反胶束溶液和血红蛋白水溶液相平衡的研究

研究了十六烷基三甲基溴化铵－正庚烷反胶束溶液和牛血红蛋白水溶液的相平衡,探讨了有机相助表面活性剂种类和浓度、水相ｐＨ值、水相离子种类和强度、表面活性剂浓度的影响,适宜条件下,牛血红蛋白的萃取率可达９５％以上。对实验结果从表面活性剂极性头与蛋白质分子间的相互作用和反胶团包溶蛋白质时的空间阻碍作用上进行了解释。     

以反胶束为模板合成导电聚苯胺

选用2—乙基已基琥珀酸钠(AOT)／异辛烷、聚氧乙烯烷基苯基醚(Triton-X100或OP)／正辛醇／环己烷以及十六烷基三甲基澳化铵(CTAB)／氯仿／正辛醇三种不同类型的表面活性剂形成的反胶束体系为模板进行苯胺聚合．系统地讨论了苯胺与过硫酸铵的物质的量的比、反应时间、氧化剂滴加速率、反应温度、微水相酸浓度及表面活性剂浓度等因素对于反应表现收率及电导率的影响．     

Review on aggregation of acid extractants in solvent extraction of metal ions: remark on the general model

The aggregation behavior of various acid extractants in the solvent extraction systems of metal ions is re-examined and explained according to knowledge obtained in recent work. The conclusions are as follows. (1) Complexes formed by the extractants and metal ions can form reversed micelles in organic diluents, depending on the microstructures of the complexes. The dimers of the acid extractant cannot percolate to the metal-extractant aggregates, and the acid-salt complexes are always formed in the aggregates. The reversed micelles or the W/O microemulsions formed by different species cannot be associated with each other to form a unified aggregate. (2) In solvent extraction systems, hydration of the extractants and metal ions can be considered as the driving force of forming reversed micelles. (3) Information of the first approach to the insight of the bicontinuous microemulsion of NaDEHP shows that various components in the aqueous phase behave confined and very similar to the typical AOT/n-heptane W/O microemulsions. (4) In the extraction of lanthanide ions by the W/O microemulsion of sodium naphthenate, the saponification is a process of forming reversed micelle or W/O microemulsion, while the extraction step is a process of destroying reversed micelles or W/O microemulsion droplets.     

质心坐标系的运动学逆解

质心坐标系的运动学逆解由于其空间变换关系中的７个结构参数中有６个是常数且取值总是非常简单以及第４列元素总是包含了第３列元素而使得求解得以简化。求解过程和结果与关节坐标系完全一致。斯坦福机械手的运动学逆解证明了这一点。     

反胶束法制备免疫脂质体

报道了反胶束法制备免疫质体的方法，先将水溶性包裹物（如药物等）包入反胶束中；在油／水界面膜上修饰有抗体，使反胶束穿过界面膜自动组装成免疫脂质体，负染电镜照片显示免疫脂质体为单层，直径在５０－４００ｎｍ范围，免疫脂质体溶解实验证明羊抗人ＩｇＧ已组装在脂质体上，该方法制备过程简单，包裹率、修饰率较高。     

反相高效液相色谱法分析克拉霉素

在对实验系统和实验方法的准确性和精密度进行评价的基础上,建立了反相高效液相色谱分析克拉霉素含量的方法.色谱条件:Kromasil C18(4.6 mm×150 mm) 反相色谱柱,前接Alltech预柱;甲醇和0.05 mol/L磷酸二氢钾(体积比7∶3)的混合液作为流动相,用磷酸调节pH＝4.0,流速1.0 mL/min;检测波长210 nm.该方法简单、快速、灵敏,具有很好的稳定性和精密度.     

齐次Poisson冲击模型中元件寿命递增的条件

证明元件寿命在齐次 Poisson 冲击模型中依期望序、反向失效率序、反向平均剩余寿命序、增凹序、Laplace 变换序等增加的充分条件,是促使元件失效的随机冲击次数也依相应的随机序增加.     

Numerical Experiments and Structural Transformation of NonLinear Evolution in Illposed Systems

Numerical experiments on nonlinear equations of the 1st and 3rdorder derivatives have been carried out through structural analyses in the phase space according to the numerical instability of illposed systems, with changes of initial values and parameters, etc.. The results show that the quantitative instability in an illposed system may reveal reversed transformation in system evolution by structural representation, and confirm A·Dauglas’ theorem that “a nonlinear equation does not satisfy the existence of the initial value in a linear wellposed system”.     

东坪金矿成矿研究

近年来，一些地质工作者认为，东坪金矿是产于碱性杂岩体中的重熔岩浆期后热液矿床，属于贫硫化物破碎带钾质蚀变岩型金矿。本文从宏观和微观两方面对该矿床的赋矿岩石和赋矿构造提出新的认识，认为变形、变质和剪切是矿化的直接动力，褶皱与剪切带是该金矿的联合控矿构造。     

豫西内乡文龙庙地区秦岭群卵形褶皱构造解析

秦岭地轴东段核心部位有规律地分布着一系列卵形褶皱,本文对其中之一的文龙庙卵形褶皱进行了构造解析,该卵形褶皱是由三期褶皱叠加而成。该区变形十分复杂,总的变形体制为塑性流变、韧性剪切、似弯滑、似弯流等;叠加褶皱的形成是在东秦岭开合构造背景下长期发展之结果,既有前寒武纪的塑造作用,也有后寒武纪的再造作用。