烧结铁矿中FeO含量对其在富氢高炉中还原行为的影响

Japan started the national project “COURSE 50” for CO₂ reduction in the 2000s. This project aimed to establish novel technologies to reduce CO₂ emissions with partially utilization of hydrogen in blast furnace-based ironmaking by 30% by around 2030 and use it for practical applications by 2050. The idea is that instead of coke, hydrogen is used as the reducing agent, leading to lower fossil fuel consumption in the process. It has been reported that the reduction behavior of hematite, magnetite, calcium ferrite, and slag in the sinter is different, and it is also considerably influenced by the sinter morphology. This study aimed to investigate the reduction behavior of sinters in hydrogen enriched blast furnace with different mineral morphologies in CO–CO₂–H₂ mixed gas. As an experimental sample, two sinter samples with significantly different hematite and magnetite ratios were prepared to compare their reduction behaviors. The reduction of wustite to iron was carried out at 1000, 900, and 800°C in a CO–CO₂–H₂ atmosphere for the mineral morphology-controlled sinter, and the following findings were obtained. The reduction rate of smaller amount of FeO led to faster increase of the reduction rate curve at the initial stage of reduction. Macro-observations of reduced samples showed that the reaction proceeded from the outer periphery of the sample toward the inside, and a reaction interface was observed where reduced iron and wustite coexisted. Micro-observations revealed three layers, namely, wustite single phase in the center zone of the sample, iron single phase in the outer periphery zone of the sample, and iron oxide-derived wustite FeO and iron, or calcium ferrite-derived wustite 'FeO' and iron in the reaction interface zone. A two-interface unreacted core model was successfully applied for the kinetic analysis of the reduction reaction, and obtained temperature dependent expressions of the chemical reaction coefficients from each mineral phases.     

Mg和La对Ca–Ti 处理钢中夹杂物演变和组织的影响

The evolution of inclusions and the formation of acicular ferrite (AF) in Ca–Ti treated steel was systematically investigated after Mg and La addition. The inclusions in the molten steel were Ca–Al–O, Ca–Al–Mg–O, and La–Mg–Ca–Al–O after Ca, Mg, and La addition, respectively. The type of oxide inclusion in the final quenched samples was the same as that in the molten steel. However, unlike those in molten steel, the inclusions were Ca–Al–Ti–O + MnS, Ca–Mg–Al–Ti–O + MnS, and La–Ca–Mg–Al–Ti–O + MnS in Mg-free, Mg-containing, and La-containing samples, respectively. The inclusions distributed dispersedly in the La-containing sample. In addition, the average size of the inclusions in the La-containing sample was the smallest, while the number density of inclusions was the highest. The size of effective inclusions (nucleus of AF formation) was mainly in the range of 1–3 μm. In addition, the content of ferrite side plates (FSP) decreased, while the percentage of AF increased by 16.2% due to the increase in the number of effective inclusions in the La-containing sample in this study.     

摩擦焊接碳钢（EN24）和镍基高温合金（IN718）的显微组织和力学性能

Continuous-drive rotary friction welding was performed to join cylindrical specimens of carbon steel (EN24) and nickel-based superalloy (IN718), and the microstructures of three distinct weld zones—the weld interface (WI)/thermo-mechanically affected zone (TMAZ), the heat-affected zone (HAZ), and the base metal—were examined. The joint was observed to be free of defects but featured uneven flash formation. Electron backscatter diffraction (EBSD) analysis showed substantial changes in high-angle grain boundaries, low-angle grain boundaries, and twin boundaries in the TMAZ and HAZ. Moreover, significant refinement in grain size (2–5 μm) was observed at the WI/TMAZ with reference to the base metal. The possible causes of these are discussed. The microhardness profile across the welded joint shows variation in hardness. The changes in hardness are ascribed to grain refinement, phase transformation, and the dissolution of strengthening precipitates. The tensile test results reveal that a joint efficiency of 100% can be achieved using this method.     

汽车暴露面板带有表面条状缺陷的夹杂物分布特征分析:一种定量电解方法

The specific distribution characteristics of inclusions along with the sliver defect were analyzed in detail to explain the formation mechanism of the sliver defect on the automobile exposed panel surface. A quantitative electrolysis method was used to compare and evaluate the three-dimensional morphology, size, composition, quantity, and distribution of inclusions in the defect and non-defect zone of automobile exposed panel. The Al₂O₃ inclusions were observed to be aggregated or chain-like shape along with the sliver defect of about 3–10 μm. The aggregation sections of the Al₂O₃ inclusions are distributed discretely along the rolling direction, with a spacing of 3–7 mm, a length of 6–7 mm, and a width of about 3 mm. The inclusion area part is 0.04%–0.16% with an average value of 0.08%, the inclusion number density is 40 mm?2 and the inclusion average spacing is 25.13 μm. The inclusion spacing is approximately 40–160 μm, with an average value of 68.76 μm in chain-like inclusion parts. The average area fraction and number density of inclusions in the non-defect region were reduced to about 0.002% and 1–2 mm?2, respectively, with the inclusion spacing of 400 μm and the size of Al₂O₃ being 1–3 μm.     

在酸性溶液中加压氧化三价砷离子和二价铁离子

The co-oxidation of As(III) and Fe(II) in acidic solutions by pressured oxygen was studied under an oxygen pressure between 0.5 and 2.0 MPa at a temperature of 150°C. It was confirmed that without Fe(II) ions, As(III) ions in the solutions are virtually non-oxidizable by pressured oxygen even at a temperature as high as 200°C and an oxygen pressure up to 2.0 MPa. Fe(II) ions in the solutions did have a catalysis effect on the oxidation of As(III), possibly attributable to the production of such strong oxidants as hydroxyl free radicals (OH·) and Fe(IV) in the oxidation process of Fe(II). The effects of such factors as the initial molar ratio of Fe(II)/As(III), initial pH value of the solution, oxygen pressure, and the addition of radical scavengers on the oxidation efficiencies of As(III) and Fe(II) were studied. It was found that the oxidation of As(III) was limited in the co-oxidation process due to the accumulation of the As(III) oxidation product, As(V), in the solutions.     

人工闪锌矿氧压酸浸过程中Cu2+的催化机理研究

The potential autoclave was used to study the catalytic mechanism of Cu2+ during the oxygen pressure leaching process of artificial sphalerite. By studying the potential change of the system at different temperatures and the SEM–EDS difference of the leaching residues, it was found that in the temperature range of 363–423 K, the internal Cu2+ formed a CuS deposit on the surface of sphalerite, which hindered the leaching reaction, resulting in a zinc leaching rate of only 51.04%. When the temperature exceeds 463 K, the system potential increases steadily. The increase in temperature leads to the dissolution of the CuS, which is beneficial to the circulation catalysis of Cu2+. At this time, the leaching rate of Zn exceeds 95%. In addition, the leaching kinetics equations at 363–423 and 423–483 K were established. The activation energy of zinc leaching at 363–423 and 423–483 K is 38.66 and 36.25 kJ/mol, respectively, and the leaching process is controlled by surface chemical reactions.     

超声振动辅助钨极惰性气体焊接异种金属 316L 和 L415

Ultrasonic vibration assisted tungsten inert gas welding was applied to joining stainless steel 316L and low alloy high strength steel L415. The effect of ultrasonic vibration on the microstructure and mechanical properties of a dissimilar metal welded joint of 316L and L415 was systematically investigated. The microstructures of both heat affected zones of L415 and weld metal were substantially refined, and the clusters of δ ferrite in traditional tungsten inert gas (TIG) weld were changed to a dispersive distribution via the ultrasonic vibration. The ultrasonic vibration promoted the uniform distribution of elements and decreased the micro-segregation tendency in the weld. With the application of ultrasonic vibration, the average tensile strength and elongation of the joint was improved from 613 to 650 MPa and from 16.15% to 31.54%, respectively. The content of Σ3 grain boundaries around the fusion line zone is higher and the distribution is more uniform in the ultrasonic vibration assisted welded joint compared with the traditional one, indicating an excellent weld metal crack resistance.     

活化天然矿石选择性还原二氧化碳为无定形碳

Natural magnetite formed by the isomorphism substitutions of transition metals, including Fe, Ti, Co, etc., was activated by mechanical grinding followed by H₂ reduction. The temperature-programmed reduction of hydrogen (H₂-TPR) and temperature-programmed surface reaction of carbon dioxide (CO₂-TPSR) were carried out to investigate the processes of oxygen loss and CO₂ reduction. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS). The results showed that the stability of spinel phases and oxygen-deficient degree significantly increased after natural magnetite was mechanically milled and reduced in H₂ atmosphere. Meanwhile, the activity and selectivity of CO₂ reduction into carbon were enhanced. The deposited carbon on the activated natural magnetite was confirmed as amorphous. The amount of carbon after CO₂ reduction at 300°C for 90 min over the activated natural magnetite was 2.87wt% higher than that over the natural magnetite.     

空间环境对植物影响的研究进展

从蛋白质和基因水平分别介绍空间微重力、强电离辐射、亚磁场及空间综合因素对生物性状和遗传变异的影响,并对今后空间诱变育种的前景和存在问题加以概述。     

关于短信网关的分析论述

信息作为我们生活交流媒介的一部分,那么信息的接收和发送更值得我们深入的认识和研究.主要从短信网关的引入、短信网关的系统组成、短信网关的系统功能以及应用短信网关服务进行分析论述.     

基于Hyper-V的校内私有云构建研究

针对云计算的发展趋势,结合校园网基础设施特点,研究和分析了虚拟化技术和云计算模式,提出一种基于Hyper-V的私有云计算环境模式,并在校园网内实现了该模式的私有云构建,为云计算环境在高校的实现提供了具体方法。     

绝缘体上硅高温压力传感器研究

采用有限元分析工具ANSYS完成了一种矩形弹性膜绝缘体上硅(SOI)高温压力传感器的优化设计，制作出样品，并与相同结构、工艺的多晶硅压力传感器进行了对比测试。结果表明：1：2的膜片宽长比可以使SOI压力传感器的灵敏度达到220mV／MPa，远大于多晶硅压力传感器的灵敏度(约50mV／MPa)。此外，该传感器能够工作在200℃的高温环境中，有良好的长期稳定性，30d内的零点时间漂移为0．12％。     

基于AJAX的WebGIS应用

针对目前WebGIS中所存在的问题,介绍了AJAX方法的概念和内涵,提出了基于AJAX方法构建网络地理信息系统的思路。并以森林资源信息网络发布系统的原型开发为例,阐述了该方法的优点和一些关键技术。结果表明通过AJAX方法的使用不仅能够快速地实现森林资源信息的网络发布功能,而且能够很好地改善WebGIS应用中以地图为载体的地理信息的网络传播和显示速度,带来丰富的用户体验。     

Study on copper adsorption on olivine

The copper adsorption on olivine supplied by A/S Olivine production plant at Aheim in western Norway has been studied. The factors which affect the uptake of copper have been evaluated. The results reveal that the equilibrium PH in aqueous solution has the greatest influence on the copper adsorption thanks to the competitive adsorption between proton and copper ions, and the adsorption of copper to olivine increases rapidly with the pH increasing from 4 to 6. The initial copper concentration and olivine dose also possess significant effect on copper adsorption. The adsorption efficieny of copper increases with the increase of olivine dose or the decrease of initial copper concentration at the same pH. The ionic strength effect on the adsorption has also been investigated, but it owns little effect on the adsorption process of copper due to the formation of inner sphere surface complexation of copper on olivine. The experimental data show that olivine has a high acid buffer capacity and is an effective adsorbent for copper.     

基于SOPC的SVPWM波形研究

介绍一种采用SOPC技术设计的SVPWM波形发生器,在FPGA中嵌入了32位NiosⅡ软核系统,用以处理SVPWM波形的计算、输出与显示等功能.利用可编程逻辑器件的可在线编程特点和SOPC的技术优势,灵活、快捷地将所需功能模块完全集成在单片的FPGA上,使电路的硬件结构简单,具有较高的性价比.     

Research on Telecommunication Based on JAVA

This paper discusses how a network communication isimplemented on the basis of java language under pro-gramming interface of network operating system whichrealizes TCP/IP network protocol.The design and appli-cation of java is successfully combined with Internet.In-ternet protocols such as Telnet,FTP,WWW etc.are sup-ported by Java with network classes in which there arevarious methods.While these methods are called fiexible,a telecommunication is implemented.Furthermore,us-ing telnet protocol for the network communication is alsodiscussed in this paper.     

月季的系统分类研究

本文论述了月季的形态习性、栽培技术，重点对月季的系统分类作了进一步的探讨。     

青防肿痛外敷散局部组织药动学研究

研究外用给药制剂盐酸青藤外敷散多次给药后有效成分盐酸青藤碱在实验大鼠局部组织的药代动力学,探索其在局部给药系统中的药动学行为.对实验大鼠后足造模并贴敷给药后,测定大鼠给药足组织内盐酸青藤碱的吸收量,并用PKSolver药动学软件进行药动学参数的计算与曲线的拟合.药动学参数Lambda_z、Vz/F_obs、Tmax、Css、DF%值分别为0.14 d-1、5.64 m L/mg、2 d、0.24 mg/m L、75%.从药动学数据可知药物在局部组织中含量较高,局部患处在高质量浓度的药物作用下,可达到较好的治疗效果,且外用局部给药可减少全身用药的不良反应,耐受性良好.