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1.
使用不同配比的4-(甲基丙烯酸)-2,2,6,6-四甲基哌啶醇酯和苯乙烯,改变引发剂AIBN的用量,合成了一系列具有不同单体配比和相对分子质量的TMPM和共聚物(PDS),研究了它们对聚丙烯耐γ辐射性能的影响。当TMPM和St的质量比为2:1 ̄1:2,引发剂的用量占单体总质量的0.5% ̄1%时,合成的PDS作为光稳定剂添加到聚丙烯中后,聚丙烯的耐辐射性能最好。  相似文献   

2.
苯乙烯(ST)、丙烯酸丁酯(BA)在无乳化剂条件下,加入少量的阳离子单体N,N二甲基N丁基N甲基丙烯酰氧乙基溴化铵(DBMEA),在引发剂偶氮二异丁基脒盐酸盐(AIBA)作用下,合成了一系列粒子分散均一、表面干净的功能型阳离子共聚物乳液.深入考察了引发剂浓度、共聚单体浓度、离子强度、ST/BA主单体配比对粒径(DW)、粒子数目(NP)及表面电荷密度的影响,结果表明:可以通过以上各因素来控制胶乳粒子的粒径、粒子数目和粒子表面电荷密度,通过DSC分析了胶膜的结构性能.  相似文献   

3.
以天然胶乳为种子乳液,苯乙烯(St),甲基丙烯酸甲酯(MMA),丙烯腈(AN),丙烯酸异冰片酯(IBA)等单体或它们的共混物为互穿单体,油酸为稳定剂,二乙烯苯为交联剂,叔丁基过氧化氢/四乙烯五胺为氧化还原引发体系,采用种子乳液聚合法制备出乳胶粒外壳呈硬聚合物梯度分布的复合乳液,经絮凝干燥得固体聚合物。考察了互穿单体的种类和用量,交联剂用量及溶胀时间等对材料力学的影响。结果表明,溶胀时间对聚合物力学  相似文献   

4.
研究了二乙基羟胺(DEHA)、二异丙基羟胺(DIPHA)和吗啉羟胺(MPHA)对偶氮二异丁腈(AIBN)引发的苯乙烯(M1)-甲基丙烯酸甲酯(M2)在60℃共聚合的行为.结果表明,3种羟胺对St-MMA共聚合表现出不同的阻聚功效,它们的阻聚活性次序为DEHA>DIPHA>MPHA.同时观察到St-MMA共聚合竞聚率发生变化,随着所用羟胺的浓度加大,St-MMA交替共聚合倾向增大.此外还讨论了聚合温度对诱导期、共聚合速率和共聚物组成的影响.  相似文献   

5.
研究了苯乙烯、丙烯酸丁酯和羧基单体(甲基丙烯酸和衣康酸)无皂乳液聚合,考察了引发剂(K2S2O8)浓度、电解质(NaCl)浓度和甲基丙烯酸与衣康酸配比改变对乳胶粒径和表面羧基含量的影响。实验结果表明:引发剂浓度是影响粒径大小的重要因素;当n(甲基丙烯酸):n(衣康酸)=1:1时,乳胶粒表面羧基含量最高。采用无皂乳液聚合,可制得表面羧基含量高、粒径较大且具有单分散的St-BA-MAA-IA乳液。  相似文献   

6.
以明胶为分散剂,N,N’-亚甲基双丙烯酰胺(双AM)为交联剂,进行了甲基丙烯酸甲酯(MMA)和丙烯酸甲酯(MA)的悬浮交联共聚合反应,研究了分散剂、引发剂、交联剂用量搅拌转速水油比及单体配比对聚合物粒径分布的影响.  相似文献   

7.
醋酸乙烯酯与丙烯酸甲酯的种子乳液聚合   总被引:1,自引:0,他引:1  
以过硫酸铵(APS)为引发剂,对丙烯酸甲酯(MA)的乳液聚合进行了研究,得出在MA/H2O重量比为0.5时,60℃下合成粒径分布均匀的聚丙烯酸甲酯(PMA)种子乳液的最佳配方为:十二烷基硫酸钠(SDS)、(APS)和(NaHCO3)的浓度分别为11.6、1.72和4.69mmol/L.然后以PMA乳液为种子,以油溶性偶氮二异丁腈(AIBA)为引发剂,分别进行不溶胀与溶胀条件下醋酸乙烯酯(VA)的种子乳液聚合,并以磷钨酸为染色剂,用透射电子显微镜(TEM)对胶粒形态进行了表征  相似文献   

8.
以过硫酸铵(APS)为引发剂,对丙烯酸甲酯(MA)的乳液聚合进行了研究,得出在MA/H2O重量比为0.5时,60℃下合成粒径分布均匀的聚合烯酸甲酯(PMA)种子乳液的最佳配方为:十二烷基硫酸钠(SDS)、(APS)和(NaHCO3)的浓度分别为11.6、1.72和4.69mmol/L。然后以PMA乳液为种子,以油溶性偶氮二异丁腈(AIBA)为引发剂,分别进行不溶胀与溶胀条件下醋酸乙烯酯(VA)的种  相似文献   

9.
通过无皂乳液聚合方法制备了单分散性好的丙烯酸甲酯(MA)-二乙烯苯(DVB)交联微球。研究了引发剂、单体、交联剂的用量、温度、搅拌速率、离子强度对聚合反应速率和微球粒径的影响。得到了外形较规则、粒径为730nm左右、分布均匀的交联丙烯酸甲酯-二乙烯苯微球,其制备条件是:以双蒸馏水为反应体系,C(MA)0=0.871mol/L,C(DVB)=0.067mol/L,T=70℃,转速为300r/min,  相似文献   

10.
在无皂条件下,利用偶氮二异丁基脒盐酸盐(AIBA)作引发剂,探讨苯乙烯/丙烯酸丁酯/(二甲基丁基)甲基丙烯酰氧乙基溴化铵(St/BA/DMBMEAB)三元阳离子共聚物乳液制备的合理条件,通过电镜观察到粒子形态规则、大小均一.功能性单体DMBMEAB是以甲基丙烯酸二甲胺基乙酯和正溴丁烷为原料,选择乙腈作溶剂合成的,制取的最终产品纯度高、收率高  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

15.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

16.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

17.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

18.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

19.
Quality traits in wheat (Triticum aestirum L.) were studied by quantitative trait locus (QTL) analysis in a recombinant inbred line (RIL) population, a set of 131 lines derived from Chuan 35050 × Shannong 483 cross (ChSh). Grains from RILs were assayed for 21 quality traits related to protein and starch. A total of 35 putative QTLs for 19 traits with a single QTL explaining 7.99-40.52% of phenotypic variations were detected on 10 chromosomes, 1D, 2A, 2D, 3B, 3D, 5A, 6A, 6B, 6D, and 7B. The additive effects of 30 QTLs were positive, contributed by Chuan 35050, the remaining 5 QTLs were negative with the additive effect contributed by Shannong 483. For protein traits, 15 QTLs were obtained and most of them were located on chromosomes 1 D, 3B and 6D, while 20 QTLs for starch traits were detected and most of them were located on chromosomes 3D, 6B and 7B. Only 7 QTLs for protein and starch traits were co-located in three regions on chromosomes 1D, 2A and 2D. These protein and starch trait QTLs showed a distinct distribution pattern in certain regions and chromosomes. Twenty-two QTLs were clustered in 6 regions of 5 chromosomes. Two QTL clusters for protein traits were located on chromosomes 1D and 3B, respectively, three clusters for starch traits on chromosomes 3D, 6B and 7B, and one cluster including protein and starch traits on chromosome 1D.  相似文献   

20.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

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