日地系统L2点Halo轨道自主天文导航及精度分析

针对运行于日地L₂点Halo轨道探测器,给出了质心惯性坐标系和质心旋转坐标系中的探测器运动方程,并建立了以星光角距作为观测量的导航模型,采用扩展卡尔曼滤波（EKF）算法解算探测器位置,以Cramér-Rao误差下界（CRLB）为系统可观测度的度量标准分析了不同的状态量和观测量对导航性能的影响. 通过数值仿真发现导航坐标系、主天体、导航恒星数目以及滤波器采样周期等因素对导航性能的影响较大,并依据平动点轨道运动学分析了以上因素对导航精度的影响.      

一类同余方程组解数的上界估计

 主要研究同余方程组有解时,关于m=(m₁,m₂,…,m_2r)解数的问题.通过引入初等的方法,得到当r=4时,该同余方程组关于m解数的上界估计.     

倾斜式双滚子包络环面蜗杆传动几何特性分析

为消除环面蜗杆传动齿侧间隙,提出倾斜式双滚子包络环面蜗杆传动,采取双排滚子错位布置,且滚子轴线与蜗轮径向倾斜一定角度. 阐述了倾斜式双滚子包络环面蜗杆传动的工作原理,依据空间齿轮啮合理论和微分几何理论,采用运动学法建立了蜗杆副的静态坐标系及活动坐标系,推导了该新型环面蜗杆齿面方程,并导出了该传动的蜗杆轴向截面齿廓方程、法向截面齿廓方程、一界函数、螺旋升角等几何特性相关的方程及计算公式,分析了滚柱半径R、滚柱偏距c₂、倾斜角γ等啮合参数对蜗杆几何特性的影响. 结果表明:该新型传动蜗杆喉部齿廓非常接近直线,蜗杆不会发生根切和齿顶变尖现象. 要使该传动保持良好的几何特性,R不宜超过12 mm,c₂在5~9 mm之间,γ在18°~25°之间.      

SmCo5型中熵、高熵金属间化合物的结构与磁性

以SmCo₅为原型,设计了3种中熵金属间化合物(Sm_1/3Ce_1/3Pr_1/3)Co₅、(Sm_1/3Ce_1/3Nd_1/3)Co₅、(Sm_1/3Pr_1/3Nd_1/3)Co₅和1种高熵金属间化合物(Sm_1/4Ce_1/4Pr_1/4Nd_1/4)Co₅,并采用原子半径差和混合焓预测了形成单相结构的可能性. 应用真空电弧熔炼技术成功制备了4种金属间化合物. 采用X射线衍射仪(XRD)、能谱仪(EDS) 和振动样品磁强计(VSM) 表征了样品的物相、成分和磁学性能. 结果表明:4种化合物均为单相,具有六方CaCu₅结构,空间群为P6/mmm,稀土原子占据1a位置;稀土位置上的原子浓度为等原子比;化合物的室温磁化行为遵循Langevin模型,磁化强度依赖于化合物的成分;磁价模型计算证实了化合物(Sm_1/3Ce_1/3Pr_1/3)Co₅、(Sm_1/3Ce_1/3Nd_1/3)Co₅和(Sm_1/4Ce_1/4Pr_1/4Nd_1/4)Co₅中的Ce为+4价,对磁矩没有贡献.     

玻碳基Pt/C/NH4NiPO4复合电极电催化氧化乙醇

以磷酸二氢铵、氢氧化钠和四水合乙酸镍为原料,聚乙二醇-400为模板剂,应用X-射线粉末衍射法(XRD)和循环伏安法考察低温固相反应合成NH₄NiPO₄·H₂O材料的最佳反应条件,在反应时间为4 h、反应温度70 ℃、氢氧化钠用量为n_乙酸镍:n_氢氧化钠=4:1时易得到较完整晶体材料,并应用扫描电镜(SEM)、红外光谱(FT-IR)及热重差热分析(TG-DTA)对产品进行表征. 实验表明将产物应用到Pt/C电催化电极中,玻碳基Pt/C/NH₄NiPO₄复合电极的电催化乙醇性能明显比石墨基Pt/C电极、石墨基Pt/C/NH₄NiPO₄复合电极优越,氧化电流较大,氧化电位降低,且具有一定的电容量,氧化电流可瞬间增加,是电催化乙醇电极潜在的特色电极.      

具有给定共轭类长的有限群

通过有限群G的共轭类长集合cs(G)来刻画有限群A₆和S₆,得到如下结论：如果cs（G）=cs（G）={1, p³·r,p·q²·r,p³·q²,q²·r},则G=A₆;如果cs（G）={1,q·r,p³·r,q²·r,p·q²·r,p³·q·r,p⁴·q²},则G=S₆.     

基于开环双模谐振器的双频带滤波器

基于新型的带开路枝节的双模开环谐振器,设计了应用于无线局域网（WLAN）IEEE 802.11 b/a（2.4/5.2 GHz）的双频带微带滤波器.双模开环谐振器的奇模和偶模谐振频率,分别由开环结构和开路枝节负载激励产生.双频带滤波器由两个双模开环谐振器电磁混合耦合实现,具有4个传输零点.滤波器的两个通带分别由双模谐振器的基频和一次杂散频率产生.为了满足输入和输出阻抗匹配要求,并改善双频段的通带特性,采用锥形渐变线0°馈电方式.双频带滤波器的频率响应特性S₁₁和S₂₁的电磁仿真和实测结果非常吻合,两个通带均呈现很好的通带特性和隔离效果.     

基于双面平行带线的绝对带宽不变频率可调带通滤波器

提出基于双面平行带线结构的电容加载绝对带宽不变频率可调平面带通滤波器,通过选取特定的耦合区域,使谐振器之间耦合系数满足绝对带宽不变的要求. 分别设计了工作在单端信号和差模信号下的滤波器. 结果表明,对于单端信号滤波器,其3 dB绝对带宽（|S₁₁| <-3 dB）在0.97 ~1.43 GHz的中心频率调节范围内约为80±4 MHz;对于差模信号滤波器,其3 dB绝对带宽（|S_dd11| <-3 dB）约为91±3 MHz,对共模噪声的抑制低于-20 dB.      

Lp(I,E)上的最佳联合逼近

设G是Banach空间E的自反子空间,Lp(I,E)(1≤p<∞)表示定义在区间I=[0,1]上且值域为E的所有p-Bochner可积函数构成的空间. 给出Rm(m≥2)上的一个范数N(·,…,·),其中N在集合R₊m上的每一坐标是非减的,证明Lp(I,G)是Lp(I,E)上的N-联合逼近.      

一类同余方程解数的上界估计

主要研究同余方程∏ri=1(x+m_i)≡∏2r i=r+1(x+m_i)(mod p^μ)有解时, 关于m=(m₁,m₂,…,m_2r)解数的问题.通过引入p-adic指数赋值,并比较该同余方程关于未知元x各项系数的p-adic指数赋值方法,得到r=6时,该同余方程关于m解数的上界估计.     

Investigation of nanocrystalline structure in selected carbonaceous materials

The structural parameters of nine Indian coals were determined by X-ray diffraction (XRD) and Raman spectroscopy. The study revealed that the coals contain crystalline carbon of turbostratic structure with amorphous carbon. The stacking height (L_c) and interlayer spacing (d₀₀₂) of the crystallite structure of the coals ranged from 1.986 to 2.373 nm and from 0.334 to 0.340 nm, respectively. The degree of graphitization was calculated to range from 42% to 99%, thereby confirming the ordering of the carbon layers with the increase in coal rank. An exponential correlation was observed among the aromaticity (f_a), the lateral size (L_a), and the rank (I₂₀/I₂₆), suggesting that the coal crystallites are nanocrystalline in nature. A very strong correlation was observed between the structural parameters (f_a, d₀₀₂, L_c, the H/C ratio, and I₂₀/I₂₆), the volatile matter content, and the elemental carbon content, indicating the structures of coals are controlled by the degree of contact metamorphism. The Raman spectra exhibited two prominent bands: the graphitic band (G) and the first-order characteristic defect band (D). The deconvolution resulted in five peaks: G, D1, D2, D3, and D4. The intense D1 band, which appeared at ~1350 cm?1, corresponds to a lattice vibration mode with A_1g symmetry. The D2 mode, which appeared at ~1610 cm?1, arises from the structural disorder as a shoulder on the G band.     

Generalized Intersection Bodies with Parameter

AIn 2005, the classical intersection bodies and L_p intersection bodies were extended. Afterwards, the concept of general L_p intersection bodies and the generalized intersection bodies was introduced. In this paper, we define the generalized bodies with parameter. Besides, we establish the extremal values for volume, Brunn-Minkowski type inequality for radial combination and L_p harmonic Blaschke combination of this notion.     

Thermodynamic characterization of two novel spin-crossover complexes

Spin-crossover complexes are of great interest to the scientists because of their potential application in molecular-based electronic devices. Some octahedral metal compounds with 3dn (4 ≤ n ≤ 7) configuration can induce a spin state conversion through a fine tuning condition (temperature, pressure, light irradiation, etc.). If the conversion occurs reversibly with a hystersis loop and color change, it will make the system possessing memory effect. The memory effect can be magnified and the …     

Spin-orbit coupling and zero-field splitting of the high-spin ferric enzyme-substrate complex: Protocatechuate 3,4-dioxygenase complexed with 3,4-dihydroxyphenylacetate

We used density functional calculations to investigate the electronic origins of the magnetic properties of the high-spin ferric enzyme-substrate complex protocatechuate 3,4-dioxygenase(3,4-PCD).The calculated g-tensors show that ligand-to-metal charge transfer transitions are from the protocatechuate(PCA) and Tyr408 orbitals to the Fe d orbitals,which lead to x-and y-polarized transitions.These polarized transitions require a spin-orbit coupling(SOC) matrix element in the z-direction,Lz(z=z’),resulting in a g z value of 2.0158,significantly deviating from 2.0023.A large zero-field splitting parameter value of+1.147cm-1 is due to △S =-1 spin-orbit mixing with the quartet states for the sextet ground state,accounting for around 73% of the SOC contribution.The SOC matrix elements indicate that the high-spin d 5 system Fe(Ⅲ),3,4-PCD-PCA is a weak spin-crossover compound with an SOC of 31.56 cm-1.     

CIE L*a*b*色空间色调角对比敏感度函数研究

为获取人眼视觉在均匀颜色空间下的空间频率响应特性并构建其模型,在CIE 1976 L* a* b*色度系统下,对色调角对比敏感度函数(S_H)进行了测试研究. 采用校准的彩色显示系统,对色调角正弦波变化的图像序列进行显示,经大量视觉观察实验,获取了人眼在12种色调角中心下的对比敏感度函数曲线. 结果表明,在不同色调角中心下,色调角对比敏感度函数存在差异,这种差异与人眼对不同色调的辨别能力紧密相关. 基于测试数据,构建了色调角对比敏感度的数学函数模型.      

白酒窖泥中乳酸菌分离鉴定及其发酵产挥发性风味物质比较

从白酒窖泥中分离得到11株乳酸菌,经16S rDNA基因序列同源性分析,鉴定为1株短乳杆菌、1株鼠李糖乳杆菌、2株干酪乳杆菌和7株铅黄肠球菌。 分析了11株菌MRS培养基发酵产乳酸性能,结果表明:乳酸产量与菌群生长呈正相关,鼠李糖乳杆菌L₉、干酪乳杆菌L₁₀与L₁₁发酵液乳酸含量较高,分别为15.74、15.58、14.74g/L。4株代表菌相同条件下发酵高粱培养液产挥发性风味组分,共有物质13种,包含了白酒中重要香气成分:乙酸、己酸、乙酸苯乙酯和苯乙醇,且乙酸、己酸相对含量较高。各菌产可挥发性组分差异明显,相对含量较高的化合物种类为:短乳杆菌L₅产烷烃类化合物(27.91%),铅黄肠球菌L₈产醇类化合物(43.14%),鼠李糖乳杆菌L₉产酯类(7.35%)、酮类(3.61%)和吡嗪类(3.3%)化合物,干酪乳杆菌L₁₁产酸类(27.98%)和芳香类(5.96%)化合物。仅有短乳杆菌L₅产四甲基吡嗪,短乳杆菌L₅和铅黄肠球菌L₈可明显产乙醇,鼠李糖乳杆菌L₉和干酪乳杆菌L₁₁产3-羟基-2-丁酮。这些物质对白酒风味和口感有重要影响。研究显示,窖泥中各种乳酸菌特征不一,对白酒酿造有不同影响。本研究旨在为进一步挖掘白酒酿造功能微生物、拓展乳酸菌的应用提供理论依据。     

Petty projection inequalities for the general L p -mixed projection bodies

In this paper,the definition of the general L p-mixed projection bodies is introduced,and the general L p-projection bodies given by Ludwig is a special case for the general L p-mixed projection bodies.Then the Petty projection inequality for the general L p-mixed projection bodies is shown.Moreover,the monotonicity for the general L p-mixed projection bodies is obtained.     

Spatial Heterogeneity of Vegetation in China

The spatial heterogeneity and ecological characteristics of 74 vegetation types and the lack of vegetation type within the 9.6 million km2 of Chinese territory were studied using data from the China vege- tation map. The analysis used 877 large quadrats 10 mm×10 mm (actual size 100 km×100 km), which cov- ered about 8.77 million km2. Each large-quadrat was divided into four small 5 mm×5 mm quadrats (actual size 50 km×50 km). The frequency of occurrence of all vegetation types was recorded in each small quadrat. The survey using the Shiyomi method of vegetation analysis based on the beta-binomial distribution was adopted to describe the frequency of occurrence and spatial heterogeneity for each kind of vegetation. The weighted average heterogeneity of all the vegetation types in the landscape provides a measure of the landscape level heterogeneity which describes the spatial intricacy of the existing vegetation composition. The maximum spatial vegetation heterogeneity was 0.8620 in the frigid-temperate coniferous forest of Larix (V1), which dominates cold moist northeast China. The minimum spatial heterogeneity with a low occurrence was the Caragana tibetica in the gravel desert in the western Yellow River Hetao area. The minimum occur- rence with a low spatial heterogeneity was the Monsoon rainforest on rock in Guangxi and Yunnan Provinces. The vegetation types on the Qing-Zang Plateau were found to be representative of Chinese vegeta- tion because of the very high occurrence and spatial heterogeneity of these vegetation types. The weighted average of the heterogeneity was 0.677, while the vegetation diversity index was 3.29.     

电性距离矢量预测有机污染物的生物富集因子

以电性距离矢量Mt表征165种非离子性有机物(NOC)的分子结构.利用多元回归方法建立了122种NOC的生物富集因子(lg BCF)与32个Mt的数学模型,其相关系数R为0.976.经逐步回归建立最佳四变量(M15,M17,M36,M91)模型,其R为0.960;并以Jackknife法检验,其LOO交互检验系数(q2)为0.915.这4个Mt参数揭示了影响NOC生物富集因子的主要因素,结果表明该模型具有良好的估算能力与鲁棒性.以111个NOC为训练集的生物富集模型作用于11个NOC的检验集,显示出良好的预测能力.     

LiNiPO4前驱体固相反应合成动力学及电容性能

以氢氧化锂、磷酸二氢铵和醋酸镍为原料,以聚乙二醇PEG-400为表面活性剂,采用前驱体固相活化法制备LiNiPO4纳米晶材料.固相制备过程的活化能E=81.08 kJ·mol-1,过程动力学为二维相界面扩散反应机理.前驱体生成LiNiPO4的反应符合界面反应指数成核机理,活化能E1=11.82 kJ·mol-1,指前因子lnA=13.82;LiNiPO4晶体生长过程具有较小的活化能E2=17.73 kJ·mol-1;Li3PO4转化反应和反应体系物系晶化过程符合二维相界面扩散反应机理,其是制备过程可控制的重要步骤.材料复合电极LiNiPO4+Nafion/C在0.5 mol·L-1H2SO4中具有典型的电容性能,电极比电容为214 F·g-1,经1 000次循环,电极电容量不但没有衰减反而略有增加,是潜在的电容器材料.