Bioactivity analysis of the Ta (V) doped SiO2–CaO–Na2O–P2O5 ceramics prepared by solid state sintering method

The main objective of the study was to control the degradation rate of material at a higher degradation rate improving the chemical stability of the material. Ta is known to have good chemical resistance, biocompatibility and show no adverse biological response. In the present study, SiO2–Na2O–CaO–P2O5 bioceramics with different Ta2O5 contents was prepared by solid state sintering method at 1000 °C. The as-sintered ceramics were subjected to immersion studies in stimulated body fluid (SBF) for 21 days under static condition and characterized by XRD, FTIR, SEM, and AAS. The findings of the research indicate that the addition of Ta2O5 controlled degradability, and all samples showed sufficient bioactivity.     

放电功率对微晶硅薄膜的晶化调控及光电性质的影响

以SiCl_4和H_2为源气体、采用等离子体增强化学气相沉积(PECVD)技术在不同放电功率下沉积微晶硅薄膜,通过调节放电功率实现了微晶硅薄膜的晶化调控和光电性质的优化,并利用Langmuir探针和质谱计分别对等离子体空间的电子特性和中性基团进行在线检测,初步探讨了成膜的微观机理.     

Thermal stability and magnetic properties of Fe–Co–M–Zr–Nb–Ge–B(M=Mo,Cr) bulk metallic glasses

Fe62Co8 xMxZr6Nb4Ge1B19(M=Mo, Cr) bulk metallic glasses were synthesized in the diameter range up to 2 mm by copper mold casting,which exhibit high thermal stability and large glass-forming ability. The super-cooled liquid region diminishes by the dissolution of Mo. The addition of 2 at% Cr leads to the broading of the liquid region remarkably, resulting in the improvement of thermal stability. The crystallization takes place through a single exothermic reaction, accompanying the precipitation of more than three kinds of crystallized phases such as α-Fe,Fe2Zr and ZrB2. The Fe-based alloys show soft ferromagnetic properties. The saturation magnetization(ss) decreases with increasing Mo or Cr content while the saturated magnetostriction increases with raising Mo or Cr content. There is no evident change in the ssand coercive force(Hc)with annealing temperature below the crystallization temperature, which suggests a more relaxed atomic configuration the glasses have. The crystallization causes a substantial enhancement in both ssand Hc. Each soft magnetic property of the glasses containing Cr with higher thermal stability is superior to that of the alloys containing Mo.     

王场油田盐间层地层水结盐规律研究*

盐间泥质白云岩油藏是江汉盐湖沉积盆地非常独特的一种盐间烃源盐油气藏,其中王场油田盐间层具有典型代表性。由于地层水矿化度高,油井生产过程中产生大量的盐垢,导致维护费用大大增加,产量明显下降,酸化压裂效果变差,挤水压力高,有效期短。分析了该油田的地层水理化性能和模拟井筒条件下的井筒结盐规律。研究结果认为:结盐井地层水的的化学成份主要是NaCl,同时含有一定量的CaSO_4和MgSO_4,盐垢样主要为白云石、方解石和钙芒硝,与地层水成分是相吻合;随温度逐渐降低,地层水结盐量增加,特别是在50~70℃结盐速度最快;压力对结盐速度影响不大;低转速(10 000~30 000r/min)对结盐速度影响不大;而高转速(﹥100 000 r/min)条件下结盐速度减慢。     

索氏抽提——溶剂结晶法纯化银杏叶提取物中银杏内酯的研究

建立了基于索氏抽提和溶剂结晶法的高纯度银杏内酯混合物提取纯化工艺.利用单因素实验选定乙酸乙酯作为索氏抽提法的萃取溶剂,再组建L16（45）正交实验获得索氏抽提最佳条件：浸提时间5 min、淋洗时间10 min、热源温度170℃、液固比12.在此条件下,内酯提取率可达84%,纯度可达42%.而后通过常温粗结晶1 h,-20℃重结晶1 h的步骤,可获得纯度大于97%的银杏内酯A、B、C混合物,内酯总得率约43%.该法简单易行、成本低廉且污染小,能够满足实验室日常制备或工业化批量生产的需求.     

聚乙烯醇对聚丙烯等温结晶行为的影响

利用差示扫描量热仪(DSC)研究了聚乙烯醇(PEG)的加入对聚丙烯(PP)结晶速度的影响,并用Avrami方程分析了聚丙烯在PP/PEG共混物中的结晶动力学。结果表明,当PEG的含量较低时能增加PP的结晶速度,PEG的含量增加,PP的结晶速度有降低的趋势。等温结晶动力学参数表明,PEG的加入对PP起着异相成核作用,但同时又有溶剂化的作用,使其对PP的结晶速度的影响比较复杂。PEG加入使共混物对结晶温度的敏感性降低。     

在不同温度下退火制备多晶硅薄膜的研究

通过PECVD法,用玻璃作衬底在30℃、350℃和450℃下直接沉积非晶硅（a—Si：H）薄膜,在600℃和850℃下退火三个小时,把前后样品用拉曼光谱和XRD分析,发现二次晶化后的晶化效果比直接沉积的薄膜好,850℃下退火的薄膜比600℃下好。     

NH2CH2COOH—H3PO4—H2O体系的结晶行为及磷酸甘氨酸的晶体结构

研究了NH2CH2COOH－H3PO4－H2O体系的结晶行为，得到三个结晶相，并用X射线衍射法了磷酸甘氨酸新晶体和分子结构，晶体的空间群为P21／a;晶体学数据：a=0.9293(3)nm,b=0.788(2)mm,c=0.9623(4)nm,β=114.70(3),V=0.64078(40)nm^3,Dc=1.79g/cm^3.Z=4,F(000)=359.95(e),μ(Moka)=3.95cm^-1，并且探讨了从该体系不能得到DGP和TGP的原因。     

磁场处理对蔗糖结晶速度的影响

蔗糖是世界上产量最多的有机结晶产品之一。生产过程的蔗糖结晶速度是反映生产效率的一个重要指标，影响蔗糖结晶速度的因素很多。本文提供了应用磁场处理糖液以提高蔗糖结晶速度的一些单晶静态和群晶动态试验的研究结果及理论分析，显示了磁处理技术在强化蔗糖结晶过程上的应用前景。     

电沉积Ni-W-P非晶合金的组织结构与耐蚀性能

研究了电沉积Ni-W-P非晶合金随热处理温度升高，其结构及耐蚀性能的变化规率。结果表明，镀态Ni-W-P合金在300℃以下温度热处理后，仍为非晶态；随温度升高开始晶化，到500℃时晶化过程结束；其腐蚀速率随热处理温度的升高增大，于500℃达到最大值，而后降低。