Co_3O_4/GO和Mn_3O_4/GO催化Oxone氧化NOx的比较研究

文章比较了Co3O4/GO及Mn3O4/GO两种催化剂催化Oxone对NOx氧化效果的影响,考察了pH、Oxone投加量及温度等因素对催化Oxone氧化NOx效果的影响。研究结果表明:在相同的试验情况下,Co3O4/GO催化Oxone氧化NOx的效果要优于Mn3O4/GO。     

等离子体法降解汽车尾气中NOx平衡计算

对汽车发动机内燃烧平衡做热力学平衡计算，得到的NOx结果与实际检测值基本一致，然后计算了等离子发生发器裂解汽汪后产生的CO和H2加入发动机后的热力学平衡，得到在发动机内燃烧温度下的NOx结果，结果表明，通过等离子体法裂解部分汽油可大幅度降低尾气中NOx的含量，当汽缸最大工作压力为40atm，工作温度为2200K，汽油与氧化比值为1：15．1时，以汽缸燃烧1摩尔汽油为基准，等离子体发生器裂解0．1摩尔汽油可使尾气中NOx含量降低到100ppm左右而CO浓度不大于100ppm，裂解0．2摩尔汽油可使尾气中NOx含量降低到45ppm以下，同时CO浓度低于65ppm。     

Integrated modeling of nitrogen oxides formation in diesel engines

To account for the effects of both chemistry and flow turbulence, the present study proposes an integrated NO sub-model that combines the extended Zel’dovich mechanism and engine CFD computations to simulate the NO histories in a diesel engine. NOx sub-model parameters and pollutant formation mechanisms can be more easily investigated by solving the NOx sub-model. The new NO formation model incorporating the effects of both chemical kinetics and turbulent mixing was applied to simulate a diesel engine with a quiescent combustion chamber, and one with a re-entrant combustion chamber; the premise of the model being the reaction rate is mainly determined by a kinetic timescale and a turbulent timescale. The results indicate that the predicted NO formulation from the new model agrees well with the measured data. As the utilization of fossil fuels continues to increase, the control of NOx emissions is a worldwide concern; and it is imperative to understand fully the NOx reaction processes in combustion systems. This technology has the potential to enhance the application of various combustion techniques used to reduce NOx emissions from practical combustion systems.     

A kinetic modeling study of pollutant formation in premixed hydrocarbon flames

A kinetic modeling of pollutant formation in hydrocarbon flames is presented through analysis of hierarchical structures. Based on the newly released GRI-Mech 3.0,it was mainly taken from Dean and Bozzelli (DB) and Wang mechanism respectively for the nitrogen chemistry, the formarion and growth of polycyclic aromatic hydrocarbons (PAH). The modeling was improved by considering C4 and Howard‘s PAH chemistry. The mechanism consists of 121 species in 731 reactions. Two premixed flame structures are predicted, and the computed results are compared with the experimental ones. It is shown that the mechanism predicts reasonably well the concentration profiles of major, key intermediate and minor species.     

超细煤粉燃烧NOx析出特性试验

对超细煤粉在一维热态煤粉炉内燃烧时煤粉粒径、炉膛温度、过量空气系数及煤种等因素对NOx释放特性的影响规律进行了试验研究．研究结果表明：超细煤粉NOx的排放浓度低于常规粒径煤粉；NOx的排放浓度，随过量空气系数的增加而明显增加；煤种不同，NOx排放规律不同，煤粉超细化后，龙口褐煤的排放量明显减少，晋城无烟煤则变化不大；NOx的排放浓度随温度的升高而升高。     

自蓄热烧嘴的研制与实验研究

简述了自蓄热烧嘴系统的设计与研制过程，并利用该装置系统进行了实验室的实验研究。研究结果表明：该装置系统既能高效回收烟气余热，又能大大幅度降低NOx的排放；而且其设计原理合理，结构简单，具有进一步进行工业试验的价值。     

天然气再燃降低NOx的化学动力学及影响因素分析

对天然气再燃降低NOx(氮氧化物)的化学动力学及其主要影响因素进行了分析,描述了再燃区温度、停留时间、过量空气系数以及混合状况对降低NOx排放的影响,并对天然气再燃在我国电力行业的应用前景进行了预测。     

燃煤锅炉高效低NOx运行策略的实验研究

燃煤电站锅炉高效低污染燃烧对于节约能源和环境保护都有重要意义。借助正交实验获取数据,基于人工神经网络建立反映锅炉效率和排放特性的模型。通过引入成本系数,将NOx排放特性和反映锅炉效率的特征量统一起来。应用基于实数编码的遗传算法对锅炉高效低NOx运行进行寻优。理论分析和实验结果表明:该方法可获得锅炉的最佳运行参数,典型工况下NOx排放降低50m g.m-3,锅炉效率提高0.4%,为锅炉的经济与环保运行提供了可靠决策依据。     

基于一种新型喷油系统的船用柴油机NO x 排放试验研究

为了探索采用改进的机械式喷油系统以较低的成本使大功率船用柴油机的NOx排放满足IMO TierⅡ法规的可能性,在一台6PC2-6/2L型柴油机上开展台架试验,验证了自行研发的新型喷油系统,即交叉喷孔油嘴和调压孔式喷油泵,对于降低船用柴油机NOx排放的效果.试验结果表明：交叉喷孔油嘴所产生的扇形喷雾在柴油机气缸的空间分布范围广,混合气更为稀薄,有利于抑制燃烧温度,从而降低NOx排放;将新型喷油系统应用于该柴油机使NOx排放率降低14.3%,同时制动油耗率降低1.5%.新型供油系统进一步优化有望使该柴油机的NOx排放满足IMO TierⅡ排放法规.     

Ag/Al2O3催化二甲醚选择性还原NOx的试验研究

为了拓展二甲醚（DME）在低温条件下选择性催化还原NOx的效果,采用浸渍法制备了Ag/γ-Al₂O₃催化剂,试验研究了反应温度、Ag/γ-Al₂O₃质量分数、氧含量、NOx源、DME/NO摩尔比对NOx转化率的影响.结果表明,Ag/γ-Al₂O₃催化剂在低温条件下具有良好的脱氮性能,在200 °C时就显示较高的活性,随着温度的升高,NOx转化率先增大后减小;Ag/γ-Al₂O₃的催化活性随氧含量的增加先增大后减小,氧含量约为8%时催化效果最佳;最佳Ag质量分数约为3%;DME/NO最佳摩尔比为2;催化活性基本不受NOx源的影响.