纳米电化学与生物传感器的研究进展

纳米材料的介入为传感器的发展提供了无穷的想象空间,由于其量子尺寸效应和表面效应,可把传感器的性能提高到新水平,使其不仅体积小,而且速度快、精度高、可靠性好,还能实现多功能化和选择检测．目前,纳米材料传感器已成为一个研究亮点,备受瞩目．该文主要就金利通课题组近年来在纳米电化学与生物传感器方面开展的工作进行介绍并对该领域的发展作一展望．     

化学镀镍液中的各组分对次磷酸钠浓度测定的影响

本文主要探讨了化学镀镍液中影响次磷酸钠浓度测定准确度的因素，并相应地提出了行之有效的解决方法。     

硅酸盐中Si—O~(br)键与Si—O~(ter)键相对强度的量子化学研究(英文)

用ab-initio法对硅氧烷及硅酸分子的研究指出,在硅酸盐中,由于电子的局域性,体系的总能量可以向结构单元或双中心分割:从而可以得到Si-O~(br)比Si-O~(ter)更稳定。用这些结果可以解释硅酸盐的许多性质。     

环醇和酯的定量结构-保留关系的研究

文中联立分子连接性指数和量子化学参数对环醇和酯的36个分子的结构与其色谱保留值的定量关系进行了研究，通过多元回归方法建立不同极性柱上定量结构-色谱保留关系(QSRR)的模型。模型的相关因子分别为0.9775 (SE-30柱 )、0.9312 (Carbowax20M柱)、0.9482 (EGSSX柱) ,相应的文献值分别为0.9518、0.5866、0.6227。由于量子化学参数能较准确的反映分子的电性相互作用，文中建立的模型比文献中仅以分子连接性指数建立的模型对极性色谱柱上非同系物的保留值的预测能力有了显著的提高。     

浅谈七年级生物教学中的理化知识分布与处理

分析初一生物教材(苏教版)中的理化知识分布特点,目的在于运用恰当的处理方法,使生物教学做到“对症下药”,提高教学效果。     

Inorganic chemical composition and source signature of PM2.5 in Beijing during ACE-Asia period

Aerosol samples for PM2.5 were collected in Beijing for 38 consecutive days from March to April 2001 using an IMPROVE Sampler. Concentrations of 20 elements in PM2.5 were determined using a PIXE method. Results show that the average mineral dust concentration of PM2.5 was 14.6 Ilg/m3 during the observation period. On the sand-dust event days of March 21 and April 10, dust PM2.5 mass concentrations were 62.4 and 54.1 μg/m^3, respectively.These demonstrate that fine particle pollution by dust event in Beijing was very severe. The enrichment factors of S and Cu reached minimums on the dusty days and were high on the non-dusty days. It is considered that enrichment factors of elements in PM2.5, which are associated with human activities, can probably provide an effective method to distinguish local sources from external sources of dust. Factor analysis on the chemical composition in PM2.5 shows that sources of crustal matters, anthropogenic emission, and oil combustion contributed to PM2.5 levels in air in the springtime of 2001 in Beijing.     

活性炭纤维的表面功能设计和控制(Ⅰ)

文章系统阐述了活性炭纤维 (ACF)表面功能的设计和控制方法 ,介绍了ACF的比表面积、孔径分布、表面化学结构与吸附对象的关系;从ACF表面物理、化学结构的可设计化入手 ,全面阐述了ACF物理结构的设计和控制方法及表面化学的改性方法;并介绍了其应用效果     

Structural and Chemical Diversity of TI-Based Cuprate Superconductors

The first TI一based euprate supereonduetor,TI一Ba-Cu一(),was diseovered by 2.2.Sheng and A.M.Hermann仁1〕. TI beeomes supereondueting at 2.38 K.NumerousTI eompounds and alloys are supereondueting.TIMo6Ses has the highest transition temperature of1 2.2 K among all non一euprate Tl eontaining alloyand eompound supereonduetors.Before thediseovery of the euprate supereonduetors,some TIeontaining oxide supereonduetors were found,among whieh TI。.3W()3 has the highest transitiontemPerature,2.14 K. Sinee the diseovery of TI euPratesuPereonduetors,two distinet families have beenidentified.Soon after the diseovery of TI一Ba一Cu-(),supereonduetivity was eonfirmed in TI一Ba一Ca-Cu一()samples.The ehemieal eompositions anderystal struetures of those eompounds were workedout as T12BaZCu()6,T12BaZCaCuZ()。,andT12BaZCaZCu3OI。[2〕.This 15 the first family of TIeuPrate supereonduetors,whieh features two TIatoms in eaeh ehemieal formula.     

H6M4(N2H2)3(M=Al,Ga)簇合物的结构、红外光谱和热力学性质研究

采用自洽场方法(HF)和密度泛函(DFT)的B3LYP方法，在6-31G^*水平下，研究了H6M4(N2H2)3(a—M＝Al，b—M＝Ga)簇合物的几何构型、电子结构、红外光谱及热力学性质．结果表明：N—N键比肼中N—N键长，有进一步裂解的趋势．振动频率计算表明：铝、镓的肼簇合物为基态稳定结构．     

大学预科化学课程教学探讨

本针对大学预科班学生的特点，从大学预科化学课程的基本目的和要求出发，讨论大学预科化学课程教学中应注意的问题．