西昆仑赞坎铁矿区英安班岩锆石U-Pb年代学研究

西昆仑赞坎英安斑岩的锆石LA-ICPMS年龄和LA-MC-ICPMS Hf同位素分析结果表明,两个样品均获得了较为一致的主体年龄,分别为533±10 Ma及527.4±9.0 Ma,都归为古生代,而不是前人所归为的前寒武纪布伦阔勒群.选用其中一个样品进行,锆石Hf同位素组成实验,其赞坎英安斑岩εHf（t）值为-3.31~-9.02,平均为-5.40,具有明显的不均一性,Hf平均地壳模式年龄为TDMC=1.70~2.06 Ga（去除其中两个U-Pb年龄异常高值）,峰值在1.7~1.8 Ga左右,与锆石形成年龄533 Ma相差甚远,说明这类锆石的母岩中主体是再造的古老地壳,同时也可能混合幔源,对应着1.7~2.0 Ga地壳再造.     

德兴张家畈金矿远景区花岗闪长斑岩年代学、Lu-Hf同位素及成矿指示意义

德兴矿集区是我国重要的Cu-Au-Mo-Pb-Zn-Ag矿产资源产地,张家畈金矿远景区位于德兴斑岩铜矿田的北西部.选取张家畈成矿远景区深部的矿化花岗闪长斑岩作为研究对象,对其进行了系统的LA-ICP-MS锆石U-Pb年代学和锆石Lu-Hf同位素分析.张家畈花岗闪长斑岩两件样品中锆石14个分析点~(206)Pb/~(238)U的加权平均年龄为171±1Ma(MSWD=0.54).张家畈花岗闪长斑岩锆石Lu-Hf同位素结果为:ε_(Hf)(t)为+5.2~+6.3,两阶段模式年龄为813Ma~883Ma.该岩体的原始岩浆来源于新元古代下地壳物质的部分熔融,并在形成过程中可能加入了地幔组分.中侏罗世,伊泽纳崎板块向华南板块北西向俯冲,在华南内陆产生了一系列伸展型岩浆作用,指示了局部拉伸的环境,因此,张家畈花岗闪长斑岩形成于陆内拉伸的构造背景.张家畈矿化花岗闪长斑岩的成岩时代及Hf同位素特征均与德兴斑岩铜矿田的成矿花岗闪长斑岩相似,且张家畈成矿远景区内自然金与黄铜矿伴生,因此,其深部可能具有斑岩型矿化.     

云南普朗超大型斑岩铜矿特征及成矿模型

普朗斑岩铜矿床位于义敦岛弧带南端,是中国目前可以确定的印支期斑岩铜矿床的典型代表.矿床产于由石英闪长玢岩、石英二长斑岩小岩株组成的复式岩体中,通过野外观察和典型地质体的辉钼矿Re-Os年龄、黑云母Ar/Ar年龄和K-Ar年龄测定,确定成矿年龄为(213±3.8)～(216.0±1) Ma,为晚三叠世诺利期,表明普朗斑岩铜矿床的成矿作用在印支期完成.含矿岩体蚀变分带明显,由中心向外发育强硅化带(局部)→钾长石、黑云母化带→石英、绢云母化带→青磐岩化带(局部发育伊利石-碳酸岩化带).工业矿体主要产于石英二长斑岩中的钾长石、黑云母化带和石英、绢云母化带.矿床具有斑岩铜矿中下部细粒状浸染、中上部细网脉状浸染和顶部围岩中产出大脉状矿体的"三层楼"模式.其斑岩体、元素组合及矿化特征与蒙古的欧玉·陶勒盖斑岩铜矿可以对比,资源潜力巨大.     

内蒙古大苏计斑岩型钼矿赋矿岩体的锆石U-Pb年龄与地球化学特征研究

为研究内蒙古大苏计斑岩型钼矿床赋矿岩体的形成年龄、地球化学特征及构造背景, 对3种岩体(石英斑岩、花岗斑岩和正长花岗岩)的样品进行锆石U-Pb定年和主量元素、微量元素分析。结果显示, 石英斑岩、正长花岗岩和花岗斑岩分别形成于231, 227和225 Ma, 为印支期产物。3种岩体属于高钾钙碱性−钾玄质系列, 为高分异的I型花岗岩。岩石组合特征与区域地质背景揭示, 大苏计地区在印支期处于伸展环境, 软流圈上涌导致不同深度的地壳发生部分熔融作用, 产生与大苏计斑岩型钼矿成矿相关的母岩浆。这些母岩浆向上运移过程中萃取前中生代形成的矿源层中的成矿元素, 并在结晶分异过程中不断地富集钼元素, 当岩浆挥发分达到过饱和时发生流体相与熔体相的分离, 钼进入流体相。岩浆热液沿裂隙充填, 在演化过程中发生沸腾作用, 导致大量钼和石英沉淀, 形成大苏计钼矿床。     

辽东青城子矿田煌斑岩锆石U-Pb年龄及其地质意义

为了深入了解辽东青城子矿集区煌斑岩岩石成因、形成的大地构造环境和地质意义,通过单颗粒锆石LA-ICP-MS U-Pb定年系统和X射线荧光光谱仪,对青城子矿集区煌斑岩进行锆石U-Pb年代学和主量元素地球化学方面研究.结果表明,煌斑岩具有低硅、富镁铁的特点,煌斑岩侵位年龄为(226.0±1.0)M a~(227.7±1.3)M a,属于晚三叠世岩浆活动的产物.结合区域构造背景和前人研究,推测煌斑岩是扬子克拉通-华北克拉通深俯冲过程的板片断离的产物,扬子克拉通的深俯冲和陆-陆碰撞可能是华北克拉通东部在中生代破坏的主要原因.     

大平掌铜多金属矿斜长花岗斑岩中锆石标型研究

运用J.P.Pupin(1980)的锆石标型研究方法,通过对锆石晶形的鉴定和统计来探讨大平掌铜多金属矿花岗闪长斑岩成因信息.结果表明,锆石在亚碱性中温环境种形成,伴随矿化可能性较大.     

准苏吉花斑岩型钼铜矿床岩体特征及成矿机制研究

通过对辉钼矿的Re-Os及锆石U-Pb同位素年代学研究, 得到辉钼矿的Re-Os等时线年龄为297.2±4.3 Ma, 赋矿花岗斑岩的锆石U-Pb年龄为 301.1±4.0 Ma, 确定准苏吉花斑岩型钼铜(Mo-Cu)矿床的成岩成矿时代为晚石炭世至早二叠世。准苏吉花矿区不含矿花岗闪长岩的锆石U-Pb 年龄为301.2±2.2 Ma, 与花岗斑岩成岩时代一致。发育角闪石和黑云母的矿物学特征以及高Rb, Th和Ba, 低P和Ti的岩石地球化学特征表明, 花岗斑岩和花岗闪长岩同属于I型花岗岩。较低的Re含量、Mg#值、Nb/Ta值和Zr/Hf值以及低ISr值和正ε_Nd(t)值的全岩Sr-Nd同位素特征表明, 准苏吉花花岗岩的源区为新生下地壳的部分熔融, 岩浆演化过程中, 花岗斑岩和花岗闪长岩均经历较强烈的分离结晶作用, 有利于Mo进一步在残余熔体中富集。通过锆石的Ce⁴⁺/Ce³⁺值计算获得岩浆结晶分异时的氧逸度, 发现花岗斑岩岩浆的氧逸度相对较高(ΔFMQ平均值为+4.8), 花岗闪长岩岩浆氧逸度相对较低(ΔFMQ平均值为+2.2), 表明高氧逸度的岩浆更有利于Mo和Cu富集成矿。     

黑龙江金厂金矿花岗斑岩锆石地球化学、U-Pb年代学及地质意义

为确定与金厂金矿成矿有关的岩浆类型、活动时限和构造背景,采用LA-ICP-MS技术对研究区花岗斑岩开展了锆石U-Pb年龄及原位微区微量元素测定。结果表明:锆石环带发育,wTh/wU值>0.4,具有岩浆锆石特征;锆石年龄分布于220Ma和103～123Ma 2个区间,代表了2期岩浆事件;对2种锆石分别命名为捕获岩浆锆石和新生岩浆锆石;锆石的地球化学和年龄信息显示捕获岩浆锆石的原岩为早三叠世花岗岩;锆石微量元素信息暗示花岗斑岩是早三叠世花岗岩高度熔融结晶分异、侵位于浅部氧化环境而形成,这一过程导致新生岩浆锆石负Eu异常程度降低。新生锆石加权平均年龄为(113.5±3.8)Ma,与成矿年龄一致,据此认为早白垩世的岩浆事件是金厂金矿成矿事件的直接原因,成矿背景为太平洋板块俯冲后的岩石圈伸展。     

青海沱沱河地区侵入岩体锆石U-Pb定年及其地质意义

青海沱沱河地区1∶5万(I45E009024、I45E010024、I46E009001、I46E010001)四幅区域地质调查发现,区内侵入岩发育差,岩性主要为花岗闪长斑岩,为该区域内首次发现的侵入岩体。通过对该花岗闪长斑岩进行LA-CIPMS锆石U-Pb同位素年龄测定,14个锆石测点中10个测点的测定值位于207Pb/235U-206Pb/238U一致线上,其206Pb/238U年龄在36~42 Ma之间,加权平均年龄为38.58±0.87 Ma,该年龄基本代表了花岗闪长斑岩的形成时间。从区域地质条件分析,将该岩体的形成时代确定为始新世。     

湖南宁乡钾镁煌斑岩及相关岩石重砂锆石地球化学特征、U-Pb年龄及其地质意义

 对湖南宁乡等地多个含有金刚石的钾镁煌斑岩及相关岩石的重砂矿物进行了分离,利用电子探针、阴极发光图像及LA-ICPMS等对其中的锆石进行了主微量元素成分、内部结构及U-Pb同位素年龄的分析。结果表明,不同地点钾镁煌斑岩重砂锆石的地球化学特征具有一定相似性;与钾镁煌斑岩有关锆石的U-Pb年龄显示研究区的岩浆活动具有多期次的特点,其中宁乡Ⅰ号及Ⅲ号岩管钾镁煌斑岩4颗重砂锆石的²⁰⁶Pb/²³⁸U加权平均年龄为(101.6 ± 5.1)Ma,显示出较为年轻的特点,但石门上五通地区白垩系红层中也发现具有²⁰⁷Pb/ ²⁰⁶Pb 谐和年龄为(2 008±29)Ma古老岩浆结晶锆石的存在,证实该地和金刚石有关火山物质的来源具有复杂性。     

藏北羌塘南缘早白垩世青草山强过铝质S型花岗岩的成因: 来自地球化学和锆石U-Pb年代学的约束

藏北羌塘南缘扎普?多不杂岩浆弧内的青草山花岗岩体由花岗斑岩和石英二长斑岩组成, 目前缺乏地球化学和年代学数据来约束其成因和形成时代。用 LA-ICP-MS 方法测得石英二长斑岩锆石 206Pb/238U 年龄加权平均值为122±1 Ma (MSWD=3.9), 花岗斑岩的锆石SHRIMP U-Pb 年龄为114.6±1.2 Ma (MSWD=1.1), 表明岩体形成于早白垩世。岩体含白云母、堇青石, 无角闪石, 具有富铝(A1₂O₃ 含量: 14.81%~15.86%)、贫钙(CaO 含量: 1.10%~2.44%)、总碱含量高(K₂O+Na₂O 含量: 6.86%~8.80%)的特征, 铝饱和指数 A/CNK 为1.06~1.20, 在 CIPW 标准矿物计算中出现刚玉分子(1.20%~2.86%), 未出现透辉石, 表明该岩体为一套强过铝质亚碱性 S 型花岗岩。(La/Yb)N=3.24~16.20, LREE/HREE=4.37~12.4, 在配分曲线上显示左高右低的特征, 富集Rb, Th, U, K, La, Ce 等大离子亲石元素, 亏损Ta, Nb, P, Ti, Y 等高场强元素, 具有较典型的岛弧岩浆岩地球化学特征。研究结果揭示, 青草山花岗岩为班公湖?怒江洋壳北向俯冲背景下, 上地壳杂砂岩质成分发生部分熔融作用的产物。     

SHRIMP zircon U-Pb dating for subduction-related granitic rocks in the northern part of east Junggar, Xinjiang

A great deal of studies have recently devoted to the Central Asian orogenic belt (CAOB). Some of the studies have proposed that CAOB is a tectonic frame ofcomplex mosaic fragments, link of multiple suture zone and mountain-basin coupling, and has undergon…     

江西乐平塔前钼(钨)矿床成岩成矿时代及意义

探讨江西省乐平市塔前钼(钨)矿床成矿岩体的形成时代。通过对塔前钼(钨)矿床进行野外地质调查和SIMS锆石U-Pb测龄,结果表明其成矿母岩为花岗闪长斑岩,其加权平均年龄为160.9±2.5 Ma(MSWD=0.69),代表矿区花岗闪长斑岩的结晶时间。这与矿区矽卡岩矿石中辉钼矿Re-Os同位素年龄(162±2 Ma)在误差范围内一致,说明此矿床形成于中侏罗世晚期。将其与钦杭成矿带东段塔前-赋春成矿带与乐华—德兴成矿带中同类矿床进行对比发现,前者成矿年龄集中于161 Ma±,控岩控矿构造皆以北东向为主;而后者成矿年龄集中于170 Ma±,控岩控矿构造以北西向为主,预示钦杭成矿带东段2个成矿阶段(170~161 Ma B.P.)区域构造应力方向可能发生了重大转变。     

Geochronolosic constraints on masmatic intrusions and mineralization of the Zhunuo porphyry copper deposit in Gansdese, Tibet

In situ zircon U-Pb ages for the recently discovered Zhunuo porphyry copper deposit in the western part of the Gangdese metallogenic belt in Tibet were determined by sensitive high-resolution ion microprobe （SHRIMP）. The ages can be divided into two separate groups, reflecting more than four major tectono-magmatic events in the area. The 62.5±2.5 Ma age of inherited zircons may be related to the volcanic eruption of the Linzizong Group formed shortly after the India-Asia continental collision. The 50.1±3.6 Ma age most likely corresponds to the time of underplating of mantle-derived mafic magma in Gangdese. The 15.6±0.6 Ma age obtained from magmatic zircons is interpreted as the age of crystallization of the Zhunuo ore-forming porphyry. Finally, a molybdenite Re-Os isochron age of 13.72±0.62 Ma is consistent with another zircon U-Pb age of 13.3±0.2 Ma, representing the time of copper mineralization. These ages, in combination with available literature data, indicate that magmatic crystallization and copper mineralization in the Gangdese metallogenic belt became gradually younger westward, and further suggest that the Zhunuo porphyry copper deposit was formed in the same tectonic stage as other porphyry copper deposits in the eastern and central Gangdese belt. This conclusion provides critical information for future exploration of porphyry copper deposits in western Gangdese.     

Indosinian isotope ages of plutons and deposits in southwestern Miaoershan-Yuechengling,northeastern Guangxi and implications on Indosinian mineralization in South China

The Miaoershan-Yuechengling complex pluton is the largest granitoid complex in the western Nanling metallogenic belt with a surface exposure of >3000 km2.The complex pluton is composed of an early stage granitoid batholith and late stage small intrusions.The early stage batholith contains mainly medium-grained porphyritic mica granite and porphyritic monzonite granite,whereas the late stage intrusions are composed of muscovite granite porphyry and muscovite monzonitic granite.There are many W-Sn-Mo-Pb-Zn-Cu ores in the contact zone between the batholith and strata,forming an ore-rich belt around the batholith.Based on zircon LA-ICP-MS U-Pb ages,the southwestern part of the early stage batholith formed at 228.7 ± 4.1 Ma(MSWD = 2.49),with slightly earlier magmatic activity at 243.0 ± 5.8 Ma(MSWD = 2.62).The Yuntoujie muscovite granite was associated with W-Mo mineralization and has a zircon LA-ICP-MS U-Pb age of 216.8 ± 4.9 Ma(MSWD = 1.44).The Re-Os isochron age of molybdenite from the Yuntoujie W-Mo ore was 216.8 ± 7.5 Ma(MSWD = 11.3).Our new isotope data suggest that the late stage intrusive stocks from the southwestern Miaoershan-Yuechengling batholith were closely associated with W-Mo mineralization from the Indosinian period.These new results together with previous isotope data,suggest that South China underwent not only the well-known Yanshanian mineralization event,but also a widespread Indosinian metallogenic event during the Mesozoic period.Therefore,South China has a greater potential for Indosinian mineralization than previously thought such that more attention should be given to the Indosinian ore prospecting in South China.     

滇西小龙潭矿区始新世岩浆岩的成因及其地质意义

云南省宾川县小龙潭矿区是一个大型斑岩型铜多金属矿床,铜矿体主要产于斑岩体及其外围接触带,矿化与斑岩体密切相关。对矿区主要侵入岩开展全岩地球化学、锆石LA-ICPMS U-Pb年代学和Hf同位素研究,获得含矿二长斑岩的~(206)Pb/~(238)U加权平均年龄为(35.98±0.16)Ma,属于始新世岩浆活动的产物。斑岩体SiO_2质量分数变化较大(64.81%~69.6%),高钾(4.36%~10.95%)和碱(Na_2O+K_2O8%),A/CNK为0.99~1.36,属高钾的碱性—过碱性、准铝质—过铝质斑岩;富集大离子亲石元素(K、Rb、Ba、Sr等)、亏损高场强元素(Ta、Nb、P、Ti等),富集轻稀土元素、亏损重稀土元素;虽被划入富碱侵入岩及A型花岗岩,但具C型埃达克岩地球化学特征。斑岩体锆石ε_(Hf)(t)值为-26.93~1.66,地壳模式年龄为1 009~4141 Ma,显示斑岩体来源于下地壳物质的部分熔融,并有幔源物质的加入。结合区域演化特征,认为小龙潭斑岩体形成于造山期后的拉张环境,陆陆碰撞挤压后应力松弛,岩浆沿断裂及次级断裂上侵,进而形成铜多金属矿床。     

Porphyry Cu-Mo deposits in the eastern Xing’an-Mongolian Orogenic Belt: Mineralization ages and their geodynamic implications

The eastern Xing’an-Mongolian (Xing-Meng) Orogenic Belt (XMOB) is one of the important areas of porphyry copper (Cu)-molybdenum (Mo) deposits in China. However, studies on the exact ages of mineralization and their geodynamic significance are very limited. In this study, granodioritic rocks from the Duobaoshan Cu deposit and Daheishan Mo deposit were selected to make zircon SHRIMP U-Pb analyses in order to constrain their mineralization ages. Geochronological data indicate that two episodes of mineralization took place in the Duobaoshan Cu deposits. The granodiorite related to the Duobaoshan porphyry Cu deposit was formed in the Early Paleozoic with zircon U-Pb age of 485±8 Ma, whereas the granodiorites related to the Sankuanggou skarn-type Cu deposit were emplaced in the Jurassic with zircon U-Pb ages of 176±3 and 177±3 Ma. In the Daheishan area of Jilin Province, the emplacement age of the granodiorite porphyry related to the porphyry Mo deposit was dated at 170±3 Ma, and the unmineralized monzogranite at 178±3 Ma. Therefore, two episodes of Cu-Mo mineralization were developed in the eastern XMOB, at ~485 Ma and ~175 Ma, respectively. Based on the geological history and spatial-temporal distribution of the granitoids in northeastern (NE) China, it is proposed that the Duobaoshan Cu deposit was related to the collision of the Xing’an and Erguna blocks in the Early Paleozoic, and the Sankuanggou Cu and Daheishan Mo deposits were related to subduction of the Paleo-Pacific plate during the Jurassic.     

The latest Yanshanian magmatic and metallogenic events in the middle-lower Yangtze River belt: Evidence from the Ningzhen region

The Ningzhen region in Jiangsu Province represents the easternmost magmatic region in the middle-lower Yangtze River belt.The formation of the polymetallic deposits has close genetic relationships with Early Cretaceous intermediate-acid intrusions.In this study,LA-ICP-MS zircon geochronology of two Mesozoic intermediate-acid intrusive rocks(including the Shima porphyritic granodiorite and Gaozi quartz diorite porphyry)in the Ningzhen region were systematically investigated.These new geochronological data demonstrate that the intermediate-acid magmatism in the Ningzhen region dates to approximately between 109 and101 Ma.We present new40Ar-39Ar phlogopite ages for the Cishantou skarn iron deposits that constrain the timing of the mineralisation in the Ningzhen region.The phlogopite in the Cishantou skarn deposits yielded a40Ar-39Ar plateau age of 104±1 Ma.This result coincides with the ages of the Anjishan and Tongshan Cu(Mo)deposits in the Ningzhen region.Our high-precision geochronological data together with recent high-precision geochronological studies(such as zircon LA-ICP-MS U-Pb,zircon SHRIMP U-Pb,molybdenite Re-Os and single-mineral40Ar-39Ar dates)reveal that there were four periods(152-135 Ma,135-127 Ma,127-121 Ma,109-101 Ma)of magmatism and ore formation in the middle-lower Yangtze River metallogenic belt.The Mesozoic intermediate-acid magmatism and mineralisation in the Ningzhen region belong to the latest episode in the middle-lower Yangtze River metallogenic belt.