Solvent effects on infrared spectra of 2—Methyl—4,5—dimethoxy—3—oxo—2H—Pyridizine：Part 2.Binary Solvent SYstems

This research on the solvent effects of 2-methyl-4,5-dimethoxy-3-oxo-2H-pyridizine(MDOP) in binary solvent systems on the infrared spectra for MDOP in n-hexane/CHCl3 mixture solvents showed that there were three forms of carbonyl stretching vibration band[v(C=O)] of MPOP as mole fraction of CHCl3 in the binary solvents changes.In pure n-hexane solvent,the v(C=O) of MODP appeared at a relatively high wavenumber.With CHCl3 added,the v(C=O) shifted to lower wavenumbers.Two new bands were observed over a certain range of mixture solvent compositions.The origin of the bands was discussed in the terms of two kinds of hydrogen bond together with their individual dependence on mixture composition.COmparisons were drawn for the solvent sensitivities of v(C=O) for propanone.     

湍流运动论中的Hilbert—Enskog—Chapman展开(Ⅲ)

Giving up the assumption of molecular chaos, we get a hierarchy of equations, instead of the Boltzmann equation, governing the motion of a dilute gas. This article is a continuation of the articles (Ⅰ) and (Ⅱ) with the same title (published in Jour. stat. plays 25(1981) 91—514, 515—567). The study of the Enskog-chapman expansion of the hierarchy is carried on here.     

Interface and Surface Properties of Nano—hydroxyapatite／Poly（1,4—Phenylene—Sulfide）—Poly（2,4—Phenylene Sulfide Acid）Copolymer Composite

The interface and surface properties of nano-hydroxyapatite(n-HA)and poly(1,4-phenylene suIfide)-poly(2,4-phenylene sulfide acid)(PPS-PPSA) copolymer composite were investigated.The results show that there are some strong interface combinations of calcium ion(Ca^2 ),carboxyl(-COO^-)and phosphate radicle ion(PO4^3-)between copolymer and n-HA in the composite.The presence of the 2,4-phenylene sulfide acid in copolymer can increase the affinity to nHA,which causes the formation of chemical bindings between the PPS-PPSA copolymer and nHA.XRD analysis and IR surface analysis indicate that n-HA is not encapsulated by copolymer but exposed on the surface of the composite,and has same structure and properties with the original n-HA.The presence of the interface chemical bindings between the PPS-PPSA copolymer and n-HA can increase the content of n-HA in composite but does not cause the decrease of the composite mechanical strength.     

A New—style Permanent—magnet Motor with Double—stator Structure

A new-style direct drive motor with double-stator structure is proposed. The structure and principle of the permanent-magnet (PM) brushless motor are discussed. On the basis of numerical calculation, the cogging torque waveforms of the prototype rrmtor when staggering two stators are analyzed. The method that can reduce torque ripple making use of the structure features of this motor is investigated. The results of numerical calculation and experiment indicate that designing motor with this kind of structure is a good seherne for increasing the power density.     

P15——a new tumor suppressor gene

In addition to the tumor suppressor genes such as Rb and p53, it has been found that some molecules of the same class named CKI (cyclin-dependent kinase inhibitor) also play an important role in the inhibition of tumorigenesis and the tumor progression. In the KIP and INK4 families of CKIs, p15 shares extensive homology with p16. Findings in many tumors and their cell lines show that the inactivation of p15 (deletion, mutation, rearrangement, etc.) is very frequent, and inactive p15 is involved in the progress of some tumors. These studies provide evidence that the p15 is a new tumor suppressor gene. Furthermore, the research on the molecular mechanism of p15 in regulation of cell proliferation shows that p15 can inhibit the growth of some kinds of tumor cells, and p15 is the mediator of TGF-β-induced cell arrest. Investigations on p15 in cell differentiation suggest that increased p15 is related to the change of malignant phenotype. These results supply clues for further interpretation about the molecular mechnism of cell cycle control and cell tumorigenesis. And they may provide theoretical and experimental basis for application of p15 to clinical therapy of tumors.     

Real—time Animation Technique for a Kind of Non—rigid Objects

A real-time animation technique for a kind of non-rigid objects,flexible and thin objects,is proposed,which can update with statility the state of n mass points of the mass-spring(MS) model with time complexity of O(n).The new implicit numerical integration technique of the authors,which is based on a simple approximation of the linear system,has great advantages over the existing implicit integration methods.Moreover,experiment shows that the new thechnique is highly efficient in animating a kind of non-rigid objects,and suitable for the draping module of the 3D garment CAD system.     

MECHANICAL PROPERTIES OF CHLORINATED POLYPROPYLENE——POLYPYRROLE FILM

The chlorinated polypropylene (PPC1)-polypyrrole (PPy) conducting films were successfully synthesized by a novel method for the first time. The mechanical properties of PPC1-PPy conducting films were investigated by means of stress-strain test and DMA. It was shown that the rupture strength and initial modulus increase with the increase of polypyrrole content , but the elongation at rupture decrease. Besides, the glass transition temperature (Tg) is increasing to a plateau when polypyrrole content attains 6%. Moreover, a new mechanical model to describe the mechanical properties of PPC1-PPy blend system is established by changing the correction factor in Mooney model. It was found that the theoretic value of the model is well coincident with the experimental results.     

Template—free electrosynthesis of aligned poly（p—phenylene） microtubules

Poly （p-phenylene)(PPP) microtubules with diameters of 0.2-0.8μm and lengths of -10μm have been synthesized by direct oxidation of benzene in the mixed electrolyte of boron trifluoride diethyl etherate(BFEE)and trifluoroacetic acid(TFA)(BFEE:TFA=2:1,by volume),containing a certain amount dodecylbenzene-sul-fonate(SDBS)as surfactant.The microtubules were grown vertically on the working electrode surface.The tubular morphology has been confirmed by scanning and transmission electron microscopies and the chain structure of the skin of the tubules has been characterized by Raman spectros-copy.The electrode property,monomer/surfactant molar ration and the value of applied potentical have strong effects on the morphology of the microtubules.     

An Anti—multipath Frequency Hopped Communication Technique in Shallow—water Acoustic Channels

This paper introduces a frequency-hopped (FH) communication system to anti-intersymbol interferences (ISI) caused by the multipath propagation in shallow-water acoustic channels, and uses high-speed digital signal processor (DSP) and serial ADC (MAX121) chip to demodulate re-ceived signal efficiently based Fast Fourier Transform (FFT) algorithm. The field experimental results show: a data rate of 1Kbit/s with the bit error rates on the order of 10^-4 is denmnstrated at 2000 m in the shallow-water acoustic channel of Xiamen harbor, and the key techniques of the system is analyzed in the paper.     

诸广308铀矿床矿物学特征及铀的赋存状态研究

308铀矿床产于诸广花岗岩体中,铀矿物以沥青铀矿为主,其次为铀石。脉石矿物有微晶石英、绿泥石、水云母、萤石等;金属矿物有黄铁矿、方铅矿、闪锌矿、赤铁矿以及副矿物锆石、金红石、磷灰石等。沥青铀矿在矿石中呈斑点状、粒状、环状、脉状,矿石结构以粒状结构为主,矿石构造多为浸染状构造。铀主要以独立铀矿物形式存在,生长于矿物裂隙及边缘。     

从风化壳淋积型稀土矿浸取液提取稀土技术与发展

详细评述了从风化壳淋积型稀土矿浸取液提取稀土方法,包括草酸沉淀法、碳酸氢铵沉淀法、沉淀浮选法、溶剂萃取法、离子交换法、液膜分离法及微生物吸附法等。草酸沉淀法因沉淀剂有毒、成本高,已被淘汰。碳酸盐沉淀法因沉淀剂无毒、成本低,成为目前生产实际中的应用方法,但仍存在氨氮污染,面临新挑战。对于溶剂萃取法和微生物吸附法等非沉淀提取法,已成为研究热点,符合绿色化学发展趋势,有良好应用前景。     

黄沙铀矿区221铀矿床微量、稀土元素地球化学特征及其意义

221铀矿床位于黄沙铀矿区中部,其深部及外围具有一定的找矿前景。系统采集矿床坑道内矿石及围岩样品,对矿床微量元素、稀土元素地球化学特征及其与铀成矿的内在联系进行了深入探讨。研究表明,矿石与围岩中微量元素的分类明显不同,相关性上也有较大差异。与该矿床铀迁移、富集密切相关的元素有Sc、Ni、Y、Nb、Sr、Cs、Pb等高场强元素。稀土元素特征显示铀成矿物质来源具有上、下地壳混合的特点,成矿流体具有幔源性质。     

Φ1600新型高效铀水冶固定床离子交换装置概述

Φ1600新型高效铀水冶固定床离子交换装置主要用于从铀矿石的浸出液中分离提取含铀化合物.该装置主要结构——离子交换塔底部的出液结构的使用,在保证液体顺畅流过的前提下,减少了离子交换树脂的磨损,防止了树脂的泄露,确保了树脂在两个塔间的转移.经现场试验,该装置独特的工作方式有效解决了原固定床树脂板结、中毒等难题,提高了生产效率和经济效益.     

肌肉醇磷酸盐的合成研究

目的研究肌肉醇磷酸盐的合成条件。方法以N-甲基氨基乙醇和单氰胺为原料,以甲醇为溶剂,与冰醋酸反应生成肌肉醇醋酸盐,再加入磷酸反应生成肌肉醇磷酸盐。结果考察了各反应条件对其产率的影响,得到了较优合成条件,肌肉醇磷酸盐的收率可达71%。结论此工艺反应条件温和,操作安全,简便,收率高,易于工业化。     

铀对Ⅰ型低熟烃源岩生烃演化的影响

在Ⅰ型低熟烃源岩中加入砂岩型铀矿石的条件下进行生烃模拟实验,对比无铀-加铀样品生烃模拟实验产物的相关参数,探讨油气生成过程中无机铀所起的作用。结果表明:铀的存在促使长链烃类在400℃后裂解成低相对分子质量短链烃,烃类相对分子质量降低,向干气演化,CO2和H2大量生成,且铀的存在使得这一变化的温度点提前50℃;铀可以促进总油生成高峰的提前到来;350℃为铀使烯烃产量变化的转折温度点,烯烃开始向烷烃转变;铀的存在能提高模拟实验中生成的烯烃的异构化程度,并在整体上使生成的烯烃分子在晶格中排得更加紧密;加铀的烃源岩样品的生烃模拟实验产物在族组成、饱和烃气相色谱、生物标志化合物等方面表现出更加成熟的特征,铀可以使有机质的成熟度提高,有利于低熟烃源岩早期生成低熟油气,使铀的存在成为未熟-低熟油气形成的可能无机促进因素之一,这种提前生成的少量油气可以使所在储层变为亲油性,为后期大规模生成的油气运移成藏提供有利的条件,使得即使是致密的储层,也能形成大规模的工业油气藏。     

新型双极双齿配体的合成及其与铀酰离子相互作用的共振光散射

铀是重要的核燃料,也是发展核电的前提条件之一,而它具有重金属毒性和放射性,可对人类的生存和发展构成潜在的威胁.铀的检测对资源开发、健康维护和环境保护都非常重要.要高效地获得铀资源并防止铀污染,就必须开发高效无毒的铀配位剂.本文利用间苯二甲醛与吡咯发生的反应制备了一种新型的双极双齿配体isophthalaldehyde-tetrapyr-role(IPTP),并研究了其与铀酰离子进行配位作用的共振光散射光谱及机理,初步探讨了其用作铀配位剂开发分离分析新方法的可能性.     

用HEHEHP液膜法提取铀

采用乳状液膜体系对铀进行提取，该体系包括表面的性剂（双丁二烯亚胺），载体（２－乙基已基膦酸单２－乙基已基酯（ＨＥＨＥＨＰ）），溶剂（民用煤油和液石蜡）以及内相（１．４４ｍｏｌ·Ｌ－１的硫酸溶液）。研究了乳状液膜的稳定性，温度，铀浓度，硫酸根浓度，外不汀ｐＨ值及乳水比等因素对提取铀的影响。实验表明，在适宜的条件下，铀的提取率可达１００％。液膜提取铀的方法是一种高效，快速及经济的方法。