ZnO/IDT/SiO2结构声表面波传感器仿真和分析

针对现有声表面波理论模型难以分析多层结构声表面波传感器器件的缺点,利用周期性介质的矩阵本征算子模型,成功对ZnO/IDT/SiO2多层结构中IDT电极的机械特性对装置性能的影响进行了建模。基于此模型,仿真和分析了此结构装置的波传播速度、机械耦合系数等参数与波导层厚度以及电极厚度的关系。并将仿真结果得到的装置传输频率响应与试验结果进行比较,二者基本一致。     

Si/SiO_2和Si/SiN_x/SiO_2超晶格的能带结构

利用Kronig-Penney模型从理论上计算了Si/SiO2和Si/SiNx/SiO2多层膜结构中量子阱的能带结构,进一步分析了各亚层薄膜厚度对能带结构和有效质量的影响.结果发现,适当减少亚层的厚度都能使得纳米Si薄膜的带隙发生明显宽化.在Si/SiO2超晶格中,Si量子阱层带隙能量随着Si层厚度的变化符合EPL(eV)=1.6+0.7/d2关系,与我们的计算结果十分吻合.在Si/SiNx/SiO2超晶格系统中,可以通过控制各亚层厚度,尤其是Si和SiNx层厚度,均能够有效地控制发光.     

ZnO/SiO2/Si复合结构的声表面波器件特性分析

为研究ZnO/SiO2/Si复合结构声表面波器件激发瑞利波的特性,通过有限元方法对该复合结构进行三维建模仿真,得到该结构SAW器件所激励的瑞利波特性,以及其位移-频率、导纳-频率特性曲线.为验证有限元仿真结果的正确性,制备了有无反射栅结构的两组SAW器件.采用等离子体增强化学气相沉积法(PECVD)在Si衬底上制备Si...     

电子束蒸发Al2O3/SiO2复合薄膜电学性能的研究

利用离子辅助电子束蒸发技术,在玻璃基底上以交替沉积的方式制备了A12O3/SiO2叠层复合薄膜,单层介质膜膜厚分别选取54和16 nm,总厚度为560 nm.采用步进法测试得到金属电极/复合绝缘膜/金属电极(MIM)结构的I-V特性曲线,具体成分为CrCuCr/(Al2O3/SiO2)8/CrCuCr,相应的厚度为80...     

Si/Al/BN多层膜的制备及研究

本文采用磁控溅射系统制备了Si/Al/BN多层膜结构,并通过XRD,AFM,傅立叶红外光谱仪,纳米压痕仪等对Si/Al/BN多层膜结构进行了表征,表征结果表明本实验制备的Si/Al/BN多层膜基片符合高频声表面波器件基片的要求,为金刚石/IDT/BN多层膜超高频声表面波器件的制备奠定了基础.     

ZnO薄膜声表面波型SF6气体传感器的研究

提出了一种基于ZnO薄膜的声表面波型SF6气体传感器.将利用微乳液法制备的ZnO颗粒制作在声表面波器件上,形成了一种对SF6气体具有物理吸附和脱吸附作用的ZnO薄膜.应用小波函数加权的输入换能器和具有抑制体声波作用的多条耦合器到声表面波器件中,传感器的频率响应特性得到了提高.声表面波器件的双声路结构消除了因外界测量条件改变引起的测量误差,进一步提高了传感器的可靠性和准确性.实验结果表明,基于ZnO薄膜的声表面波型SF6气体传感器具有较好的重复性和较强的连续测量特性,在测量范围内对各种浓度的SF6气体具有好的响应特性,传感器在9(SF6)为0.5×10-6到20×10-6范围内的线性灵敏度大约为7.3 kHz/10-6,但对CO2、N2具有一定的交叉灵敏度.     

SiO_2/Ag/SiO_2/Au多层纳米壳中的法诺共振现象

利用等离子体杂化理论解释了SiO2/Ag/SiO2/Au多层纳米壳的法诺共振现象,并利用有限元方法系统地研究了其消光特性。结果表明:具有对称性的多层纳米壳结构可以实现法诺共振。进一步证实了SiO2/Ag/SiO2/Au多层纳米壳的法诺共振是由其内球壳和外球壳的偶极-偶极耦合杂化产生。通过选择合适的几何参数,SiO2/Ag/SiO2/Au多层纳米壳法诺共振的位置可以调谐至600~900nm。     

硅源加入方式对Fe3O4/SiO2核壳结构制备的影响及磁性能研究

表面包覆惰性层是解决四氧化三铁(Fe3O4)粒子团聚、易氧化、亲水性差等问题的一种有效方法,但惰性层的引入一般会导致包覆后样品磁性能下降,从而限制了Fe3O4的应用.以正硅酸乙酯(TEOS)和氨水为原料,制备了具有良好磁响应性的Fe3O4/SiO2核壳结构.样品的结构、形貌、尺寸和表面吸附官能团采用X-ray粉末衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)和红外光谱(FTIR)等测试手段进行了表征.研究发现,TEOS加入方式影响SiO2层生长过程,从而影响包覆的均匀程度.Fe3O4/SiO2核壳结构表现出顺磁性和良好的磁响应性(52emu/g).     

TiO2/Al2O3-Al2O3-TiO2/Al2O3绝缘结构的真空沿面闪络特性

基于变插入层介电常数的多层绝缘结构能改善电场分布、提高真空沿面闪络特性.通过真空热压烧结制备了TiO2/Al2O3-Al2O3-TiO2/Al2O3(A-B-A)3层绝缘结构,A层w(TiO2)为0.5%到20%.测量了该绝缘结构的真空沿面闪络特性,发现闪络特性随w(TiO2)的增加而提高,当w(TiO2)为20%时,其脉冲初次闪络电压较同等厚度的Al2O3陶瓷提高了63%.研究发现:A层的介电常数可由w(TiO2)调控,介电常数的增大能有效降低真空-绝缘子-阴极三结合点处的电场强度;A层表面存在的TiO2颗粒可以减小二次电子发射系数并改善表面电荷分布;TiO2的电导率虽比Al2O3高,但其仍为绝缘体,即使TiO2含量较高时也不会形成贯穿的导电通道.     

Mg-Nd-Zn-Zr镁合金表面超疏水SiO2薄膜的制备及其表征

以微弧氧化层(MAO)为预处理过渡层,正硅酸乙酯(TEOS)和甲基三乙氧基硅烷(MTES)为主要原料,采用sol-gel和浸渍-提拉相结合的方法在Mg-Nd-Zn-Zr(NZ30K)镁合金表面获得甲基(-CH3)疏水基团表面修饰的超疏水SiO2薄膜,实现了NZ30K镁合金表面的超疏水改性.同时研究了微弧氧化层的表面特征、sol-gel过程中TEOS/乙醇摩尔比(TEOS/EtOH)和MTES添加量(MTES/TEOS摩尔比)对所制备超疏水SiO2薄膜表面形貌和润湿特性的影响.结果表明:NZ30K镁合金经过微弧氧化处理后,表面呈现的微米-纳米尺度上多孔的粗糙结构,其表面体现为亲水性,但有利于提高超疏水SiO2薄膜与NZ30K基材的结合力;当TEOS/EtOH摩尔比为1/30,MTES/TEOS摩尔比为1/2时,SiO2薄膜表面的静态接触角达到151°,其表面具有超疏水特性;而进一步提高MTES/TEOS摩尔比至1时,其静态接触角有所提高,达到153°.红外光谱(FT-IR)表明NZ30K镁合金表面SiO2薄膜的超疏水特性是由于MTES的引入使得-CH3疏水官能团能够成功地嫁接到SiO2粒子的表面.     

基于AlN/LiNbO3/diamond叠层结构的声表面波传播特性

金刚石材料具有最高的声速,与压电薄膜相结合可获得高声速的声表面波器件。该文以改进的传输矩阵计算方法系统研究了12种不同边界条件下AlN/LiNbO3/diamond叠层结构的声表面波波速和耦合系数与AlN和LiNbO3厚度的关系。结果表明:AlN/LiNbO3/diamond的一阶声表面波在一定范围内可保持约9km/s的波速而不随LiNbO3和AlN的厚度而变化;其中4种结构的一阶声表面波耦合系数均可达到8%以上,且可在多种厚度组合下获得。结果显示:AlN/LiNbO3/diamond叠层结构兼具AlN/diamond结构的高声速和LiNbO3/diamond结构高耦合系数的特点,而其一阶波模的稳定波速的特点可克服现有AlN/diamond和LiNbO3/diamond结构的波速与膜厚强关联的缺点,在未来的高频率、高速率无线通信系统中具有潜在的应用价值。     

A hybrid hydrogel/textile composite as flame-resistant dress

Currently, the functional and cost-effective flame-resistant textiles(FRTs) are on high demand. However, such FRTs based on general polymer fabrics are always expensive, readily decompose, and their temperatures quickly rise once exposed to thermal environments. Inspired by the large specific heat of water and high decomposition temperature of inorganic substances like SiO_2, this study establishes a simple casting strategy for preparing flameresistant gel/textiles(FR-GTs). The findings showed that active diffusion of aqueous AAM/SiO_2 pre-gel solution into the textile structure enabled the formation of a tough interfacial adhesion between the hydrogel and textiles.The interfacial toughness reached ～272 J/m~2 because the PAAM/SiO_2 nanocomposite hydrogel was filled into textile to form the semi-interpenetrating structure at the interface. The presence of chemical crosslinker(PEGDA)and physical crosslinker(SiO_2) limited the volume expansion of the hydrogel upon swelling. In addition, the PAAM/SiO_2 nanocomposite hydrogel layer prevented burning in high temperature environments(over 100℃),due to the heat dissipation of water during evaporation. This simple strategy provides a guidance towards the fabrication of hybrid hydrogel/textile composites for the applications like household fire resistant materials such as flame-resistant gloves.     

基于多条耦合器声表面波器件的小波重构

提出了一种基于多条耦合器声表面波器件实现小波重构的新方案．利用基于多条耦合器声表面波器件的传递函数等于输入与输出加权换能器传递函数之积的关系，对输入、输出叉指换能器分别进行小波和重构小波加权，在单块器件上实现了小波重构功能，避免了二次插入损耗的产生．利用多条耦合器和双声路对称结构，将沿晶体表面传播的体声波进行了分离和消除，抑制了三次渡越信号，降低了接收损耗，使器件的响应特性得到了改善．实验结果表明，用新方案实现的小波重构器件比用早期方案实现的小波重构器件在插入损耗、体声波抑制、通带波纹和接收损耗方面均有明显的改善．     

Preparation and photocatalytic activity of Cu-doped TiO2/SiO2

Cu²⁺-doped nanostructured TiO₂-coated SiO₂ (TiO₂/SiO₂) particles were prepared by the layer-by-layer assembly technique and their photocatalytic property was studied. TiO₂ colloids were synthesized by the sol-gel method using TiOSO₄ as a precursor. The experimental results showed that TiO₂ nanopowders on the surface of SiO₂ particles were well distributed and compact. The amount of TiO₂ increased with the increase in coating layers. The shell structure appeared to be composed of anatase titania nanocrystals at 550°C. The 2-layer coated TiO₂ particles on the surface showed a higher degradation rate compared with all the different-layer samples. The photocatalytic activity of Cu²⁺-doped TiO₂/SiO₂ was higher than that of undoped TiO₂/SiO₂. The optimum dopant content was about 0.10wt%.     

Near 30% fractional bandwidth surface acoustic wave filters with novel electrode configuration

With the rapid progress of the wireless communication technique and the fast growing of the radio frequency (RF) markets, the development of wideband surface acoustic wave (SAW) filter is intensely pursued in RF front-end platforms. In this study, a novel configuration of SAW device was proposed in 15°YX-LiNbO₃ (300 ​nm)/SiO₂ (600 ​nm)/Si heterostructure, where the series and shunt resonator innovatively adopt Cu electrodes of different thickness to suppress the unwanted Rayleigh mode efficiently. Series and shunt resonators with clean spectrum and high electromechanical coupling coefficients over 20% were experimentally achieved under the guidance of finite element method calculation. Based on the resonator results, a ladder-type SAW filter with a very large 3-dB fractional bandwidth near 30% was successfully designed and fabricated. The minimum insertion loss of device is as small as 1.1 ​dB while the in-band fluctuation is less than 0.3 ​dB. The unprecedented wideband property of SAW device indicates that the proposed configuration is expected to become one of the solutions of wideband filter in fifth-generation mobile communication, and possess great commercial application prospects.     

TiO2/SiO2/GQDs双层增透膜的制备及其在太阳能板中的应用

采用溶胶-凝胶法制备了SiO₂ 和TiO₂ 纳米溶胶,采用水热法制备了石墨烯量子点（graphene quantum dots,GQDs）。为进一步提高光伏太阳能板的透光率,设计了一种TiO₂/SiO₂/GQDs双层增透膜结构。探究了薄膜的结构、自清洁性能和增透性能,并进一步讨论了GQDs在增透性中的作用。结果表明,SiO₂-TiO₂/TiO₂-GQDs结构的双层薄膜厚度为120 nm时,太阳能板上的光透过率由未涂敷的85%增加至95%。接触角实验和室外耐环境性能实验测试表明,复合膜层接触角为10°,并具有良好的亲水性和耐环境性能。此外,户外实验结果表明,涂覆该薄膜的太阳能电板发电效率提高6%。由此说明双层增透膜可有效地提高太阳能电池板的光能利用率和使用寿命,可高效地利用太阳能。     

Effects of boron on the microstructure and thermal properties of Cu/diamond composites prepared by pressure infiltration

Diamond reinforced copper (Cu/diamond) composites were prepared by pressure infiltration for their application in thermal management where both high thermal conductivity and low coefficient of thermal expansion (CTE) are important. They were characterized by the microstructure and thermal properties as a function of boron content, which is used for matrix-alloying to increase the interfacial bonding between the diamond and copper. The obtained composites show high thermal conductivity (>660 W/(m·K)) and low CET (<7.4×10-6 K-1) due to the formation of the B₁₃C₂ layer at the diamond-copper interface, which greatly strengthens the interfacial bonding. Thermal property measurements indicate that in the Cu-B/diamond composites, the thermal conductivity and the CTE show a different variation trend as a function of boron content, which is attributed to the thickness and distribution of the interfacial carbide layer. The CTE behavior of the present composites can be well described by Kerner’s model, especially for the composites with 0.5wt% B.     

Synthesis of γ-Fe<Subscript>2</Subscript>O<Subscript>3</Subscript>/SiO<Subscript>2</Subscript>/Au magnetic composites for immobilization of bovine serum albumin

A method for the two-step synthesis of magnetic composites with a γ-Fe₂O₃ core, silica inner layer and numerous gold nanoparticles supported on the surface of the silica (γ-Fe₂O₃/SiO₂/Au) is described. First, thiol-functionalized γ-Fe₂O₃/SiO₂ composites and gold colloids are prepared by modifying γ-Fe₂O₃/SiO₂ composites with mercaptosilane and reduction of Au³⁺ to Au⁰ with citrate, respectively. Gold nanoparticles are then assembled on the surface of the thiol-functionalized γ-Fe₂O₃/SiO₂ composites to form γFe₂O₃/SiO₂/Au composites. The structure of the composite particles is confirmed by transmission electronic microscopy and powder X-ray diffraction. Immobilization studies with bovine serum albumin (BSA) demonstrate that the γ-Fe₂O₃/SiO₂/Au composites can be used to immobilize BSA, making them useful for biomedical and biological applications.     

Morphological evolution and kinetic enhancement of Li2FexMn1-xSiO4/C cathodes for Li-ion battery

Li_2MnSiO_4-based cathode materials possess reasonable work potentials and high theoretical capacities,while the practical energy/power densities are constrained by their inferior kinetics of Li~+ diffusion.In this work,the Pmn2_1-structure Li_2Fe_xMn_(1-x)SiO_4/C materials were synthesized via a solvothermal method and evaluated as Liion cathode materials,with notable morphological evolutions and tunable crystallographic habits observed after solvothermal process.The Li_2Fe_(0.33)Mn_(0.67)SiO_4/C material delivers an initial reversible capacity of 250.2mAh g~(-1)at 0.1 C(～1.51 Li~+insertion/extraction,1 C=166 mA g~(-1)),excellent high-rate capability(52.2 mAh g~(-1)at 5 C),and good long-term cyclability(64.6%after 196 cycles at 2 C).The enhanced electrochemical properties are attributed to the boosted ion/electron transports induced by preferred morphological and structural characteristics of Li_2Fe_(0.33)Mn_(0.67)SiO_4/C.