Effect of Co substitution on the structural,dielectric and optical properties of KBiFe2O5

Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample.     

世界一流科技社团发展现状国际比较——基于实践动态的视角

 以世界一流科技社团2019年9月-2020年6月的新闻数据，分析总结了世界一流科技社团的实践动态及发展规律。研究发现：（1）国内科技社团强调党建引领，制度优势体现出强大的凝聚力；（2）国外科技社团更加善于聚合公共资源，并将产生的新知识转化为可供应用的产品和服务，推进科技与经济、创新链与产业链的融合；（3）国外科技社团善于通过多种形式发声，充分发挥决策者智库咨询的作用；（4）全球科技治理的实质性活动由国际化大型科技社团主导。中国科技社团需要重视决策咨询智库建设、为政府重大决策制定提供技术支撑；完善学术交流平台、创造有利于科技工作者的良好生态；为科技经济融合贡献智慧，推动互惠共享的国际科技交流合作。     

膝关节骨性关节炎步态分析特征及3D矫形鞋垫设计应用

 概述了2种步态分析实验系统、实验原理和KOA患者下肢三维步态的改变；由于下肢生物力学的复杂性和研究技术的局限性，3D矫形鞋垫设计目前仍处于初级阶段，产品的治疗效果尚无统一意见并且未大量生产使用，因此对3D矫形鞋垫在KOA中的应用原理及制作过程进行深入探讨，明确KOA患者膝关节周围动力和静力结构变化，将其应用于3D矫形鞋垫的设计和生产，为早期KOA保守治疗提供重要解决方案，既能够患者满足舒适性和功能性的双重需求，又能使制造周期和成本显著降低。     

带有加性噪声的阻尼吊桥方程随机吸引子的存在性

用算子分解技巧, 通过对方程的解进行先验估计, 给出随机动力系统的一致渐近紧性, 从而证明了随机吊桥方程在加性噪声下随机吸引子的存在性.     

基于反应位移法的某地铁车站抗震性能研究

以沈阳某地铁车站为计算模型,考虑地层与车站结构间相互作用,按照反应位移法原理计算地层相对位移、结构周围剪力和结构惯性力.结果表明,车站层间位移满足规范限值要求,抗震组合为非控制工况,结构受力合理,对类似工程有一定参考意义.     

一种应用于高含硫气井的智能取垢器系统设计

油气井生产过程中，受地质环境、生产阶段、矿物成分等多种因素综合影响，井筒上易产生垢物堵塞，影响正常生产；而解堵和工艺措施的有效性由能否精准取样井下垢物直接决定。针对高含硫气井井下垢物样本取样需要，设计研制了一套智能井下取垢系统，介绍了智能井下取垢器的体系结构及工作原理；详细论述了电路板减震结构、取垢弹爪、容垢篮装置以及扶正装置等取垢器关键机械结构及部件；阐述了基于DSP的电气定时控制系统的体系结构及控制原理，重点说明了系统PID控制算法关键参数计算过程。室内性能实验以及试验井功能试验结果表明，研制工具的耐温、承压性能以及取垢和容垢装置自动化伸缩同步联动控制功能可靠，入井和出井过程顺利，能为高含硫气井井下垢物精准化取样提供设备支撑。同时，提出的设计方法和思路对其他智能化井下工具的研发具有一定的参考意义。     

船舶浅水航行下沉量数值计算

为求解船舶航行中的下沉量,采用NURBS技术对船体进行曲面重构,并应用基于Rankine源格林函数的一阶面元法构造数学模型,然后结合两者得出船舶下沉量的计算方法.以标准船型KCS为例进行验证,计算值与实验值的最大和最小相对误差分别为-10.32％和-1.84％,与实验情况基本相符,说明该算法具有可行性.     

产后早期肛提肌裂孔扩张程度及相关因素分析

目的 分析产后早期肛提肌裂孔扩张的影响因素.方法 盆底超声测量产后早期女性肛提肌裂孔面积,其中研究组为105名肛提肌裂孔扩张者,对照组为145名肛提肌裂孔正常者,对肛提肌裂孔扩张的相关因素进行二元Logistic回归分析.结果 研究组中盆底疾病的发生率高于对照组(P＜0.05),Logistic回归分析显示第二产程时间、胎儿体重、催产素使用和盆腔器官脱垂与肛提肌裂孔扩张显著相关(P＜0.05).结论 第二产程时间延长、催产素增加和胎儿体重增加是肛提肌裂孔扩张的影响因素,对预测和精确诊断盆底疾病有临床意义.     

Dielectric relaxation and conduction mechanism in Aurivillius ceramic Bi5Ti3FeO15

For this study, we synthesized Aurivillius Bi5Ti3FeO15 ceramic using the generic solid-state reaction route and then performed room-temperature X-ray diffraction to confirm that the compound had a single phase with no impurities. The surface morphology of the prepared sample was observed to contain microstructural grains approximately 0.2–2 μm in size. The dielectric properties of the sample were determ-ined as a function of frequency in a range of approximately 100 Hz to 1 MHz at various temperatures (303 K ≤ T ≤ 773 K). Nyquist plots of the impedance data were found to exhibit a semi-circular arc in the high-temperature region, which is explained by the equivalent electrical circuit (R1C1)(R2QC2), where R1 and R2 represent the resistances associated with the grains and grain boundaries, respectively, C1 and C2 are the re-spective capacitances, and Q is the constant phase element (CPE), which accounts for non-Debye type of behavior. Our results indicate that both the resistance and capacitance of the grain boundaries are more prominent than those of the grains. The alternating current (ac) conductiv-ity data were analyzed based on the Jonscher universal power law, which indicated that the conduction process is dominated by the hopping mechanism. The calculated activation energies of the relaxation and conduction processes were very similar (0.32 to 0.53 eV), from which we conclude that the same type of charge carriers are involved in both processes.     

结合流形结构与柔性嵌入的多标签特征选择

将线性回归模型与流形结构相结合,构成了弱线性多标签特征选择的联合框架。首先,用最小二乘损失函数来学习回归系数矩阵;其次,通过标签流形结构来学习数据特征的权重矩阵;再次,用L2,1-范数来约束回归系数矩阵和特征权重矩阵,这样既能引导稀疏性,又有利于特征选择。此外,设计并证明了具有收敛性的迭代更新算法来解决上述提出的问题。最后,所提出的方法在多个经典多标签数据集上进行了验证,实验结果表明了所提算法的有效性。