[（n-Bu）4N]2[X2Mo4O10（OCH3）2]的合成与表征

本文选用醌类配体菲醌和酚类配体1，2-二羟基萘，合成了具有相似结构、通式为[(n-Bu)4N]2[X2Mo4O10(OCH3)2](X=OC10H6O和OC14H8O)的二种四聚钼多酸配合物，进行了元素分析、核磁共振、红外光谱和热重分析等表征．并对菲醌与钼多酸配合时由醌式状态向酚式结构的还原进行了研究和探讨．     

Analysis of carbon isotopes in airborne carbonate and implications for aeolian sources

Methods were developed to determine the mass ratios of carbon isotopes in trace amounts of aerosol carbonate. A Finnigan MAT 252 mass spectrometer fitted with an on-line Kiel device was to determine the ^13C/^12C ratio in CO2 produced from the carbonate. A study using these methods was conducted to characterize the carbonate carbon isotopes in aerosol samples collected in Xi‘an on dusty and normal days during March and April 2002. Results of the study demonstrate that insights into the origin of the dust can be deduced from its isotopic composition. That is, the δ^13C ofcarbonate for dust storm samples ranged from -1.4‰ to -4.2‰, and this is consistent with sandy materials in dust source regions upwind. In contrast, for non-dusty days δ^13C ranged from -7.5% to -9.3‰, which is more similar to fine particles emitted from local surface soils. Comparisons of dust storm aerosols with surface soils from source regions and with aerosol samples collected downwind indicate that the δ^13C values did not change appreciably during longrange transport. Therefore, carbon isotopes have the potential for distinguishing among source materials, and this approach provides a powerful new tool for identifying dust provenance.     

Fe~(Ⅲ)(acac)Py_2Cl_2的合成和晶体结构

三氯化铁、乙酰丙酮(acacH)和吡啶(Py)在乙腈中反应得到标题化合物晶体。X-射线单晶衍射的研究表明,晶体属单斜晶系,空间群是P2_1/c,晶胞参数α=13.196(6)A,b=9.146(4)A,c=15.305(8)A,β=110.10(4)°,晶胞体积V=1734.6A~3,经验式量FW=384.1,分子数Z=4,吸收系数μ=15.85cm~(-1),计算的密度D_c=1.47gcm~(-3),最终偏差因子R=0.044,R_w=0.056。络合物的分子构型为变形八面体,两个氯原子处于顺式位置而两个吡啶分子处于反式位置。     

Radial acceleration estimation of multiple high maneuvering targets

The acceleration of a high maneuvering target in signal processing is helpful to enhance the performance of the tracker and facilitate the classification of targets. At present, most of the research on acceleration estimation is carried out in cases of a single target with time-frequency analysis methods such as fractional Fourier transform （FRFT）, Hough-ambiguity transform （HAT）, and Wigner-Vil e distribution （WVD）, which need to satisfy enough time duration and sampling theorem. Only one reference proposed a method of acceleration estimation for multiple targets based on modified polynomial phase transform （MPPT） in the lin-ear frequency modulation （LFM） continuous-wave （CW） radar. The method of acceleration estimation for multiple targets in the pulse Doppler （PD） radar has not been reported so far. Compressive sensing （CS） has the advantage of sampling at a low rate and short duration without sacrificing estimation performance. There-fore, this paper proposes a new method of acceleration estimation for multiple maneuvering targets with the unknown number based on CS with pulse Doppler signals. Simulation results validate the effectiveness of the proposed method under several conditions with different duration, measurement numbers, signal to noise ra-tios （SNR）, and regularization parameters, respectively. Simulation results also show that the performance of the proposed method is superior to that of FRFT and HAT in the condition of multiple targets.     

高校研究生自我批判精神的弱化及重塑

由于受市场经济冲击、高校行政权力和学术权力失调以及研究生扩招等因素的影响,高校研究生的自我批判精神日趋弱化。重塑高校研究生自我批判精神的举措包括：坚守对高深知识的探究,理性应对市场经济带来的影响;放松管制,调适行政权力和学术权力的关系;着眼长远,正确定位大学的角色;理性扩招,提高研究生的培养质量。     

研究金属材料高温动态拉伸性能新方法

采用自行设计带有小型加温装置的改进的分离式Hopkinson拉杆装置测试了金属材料在高温条件下的动态拉伸性能,并用修正的Johnson-Cook模型作为材料的本构关系,提出了一种拟合金属材料在弹性及塑性阶段应变率及温度相关的损伤模型,并拟合出参数.结果表明:改进装置能够精确控制加温速率及温度,减小杆端软化的影响,测试结果相对误差小于1.5%;金属材料304不锈钢的屈服应力及断裂应变具有明显的正应变率效应的温度软化效应,但材料弹性模量具有负应变率效应和负温度效应;在293—625K之间计算结果和试验结果吻合较好,表明可用这种方法测试及估算材料高温动态力学性能,并用于工程分析.     

新型热塑性的双酮酐型聚酰亚胺的合成与性能研究

以4,4’-对苯二甲酰二邻苯二甲酸酐(TDPA)和1,3-双(4-氨基苯氧基)苯(BAPB)为单体,采用2步溶液缩聚法,制得高相对分子质量的聚酰胺酸(PAA)溶液,经4种亚胺化工艺合成了TDPA/BAPB型聚酰亚胺(PI)树脂.通过FT-IR、WAXD、DSC、TGA、溶解性能等对PI树脂进行测试和表征.FT-IR表明4种方法均形成了酰亚胺结构,WAXD及DSC分析表明TDPA/BAPB型PI为部分结晶型结构,熔融温度(T_m)为363～370 ℃,TGA测试揭示乙酸酐/吡啶化学亚胺化PI耐热性能最佳,且较其它3种方法溶解性也更好,可溶于DMSO、NMP、间甲酚等强极性溶剂中.PAA溶液流延成膜性能良好,热亚胺化PI薄膜具有较好的力学性能,拉伸强度为118.3 MPa,弹性模量为2.5 GPa.     

在物化实验中用自编程序实现计算机数据处理

在我们所开设的物理化学实验中有许多电化学实验,用扫描恒电位仪发出信号,Ｘ－Ｙ记录仪接收信号,因为普通扫描情怀电位仪没有计算机接口,所以不能用计算机采集数据及处理。本文通过采用信号处理仪代替Ｘ－Ｙ记录仪采用数据并通过自编软件帝现数据转换,再用美国ＥＧ＆Ｇ－ＰＡＲ公司提供的电化学软件包解析数据,实现数据采集及处理的计算机化,减小了数据记录及处理的误差,求得了相应的电化学参数。     

集中式雷达网鉴别虚假航迹的假设检验方法

针对电子战飞机(ECAV)编队实施的航迹欺骗容易对雷达网产生虚假空情的问题,提出了一种集中式雷达网鉴别虚假航迹的假设检验(HT)方法。首先,根据航迹欺骗的具体实际,建立了虚假目标量测的误差模型,在此基础上,利用量测数据以及目标状态估计构造了样本的量测误差协方差阵;然后,采用统计分析的方法对误差协方差阵进行假设检验,完成单雷达对航迹真实性的判决;最终,利用M/N逻辑加强判决可靠性,突出雷达网的抗干扰优势。与目前在雷达战术或技术上广泛运用的具有较强试探性的方法相比,HT方法立足理论分析,具有更好的可靠性和可行性,其虚假航迹正确鉴别率能够达到90%以上。