探讨含过渡金属配合物的合成、晶体结构及性质

随着时代的进步和社会经济的发展,多金属氧酸盐得到了较为广泛的应用,这是因为在诸多的领域内,它所表现出来的性质都比较的优异,如催化化学、药物化学、分析化学等,受到了人们的关注和重视。在很多的文献中已经研究了含过渡金属配合物修饰的多金属氧酸盐的合成、晶体结构和性质,本文结合以往的研究结果,进行了深入的探讨。     

钻机焊接变形的控制与校正

为了有效的控制井架钢结构件的变形问题,对影响变形的各种因素进行了分析,结合多年实际工作经验,再联系国际国内相关技术资料,本文深刻阐述控制井架钢结构焊接变形的主要方法与校正方法。     

CA04顶部法兰机加工工装

CA04顶部法兰是结构模块的重要组成部分,用来支撑RV支撑。法兰结构为正八边形,其中四个面需要加工,其表面粗糙度和平面度要求高,在现场需要使用便携式机床进行加工,由于法兰整体标高较高,所以需要对机床提供有效的支撑。根据实际情况,设计一种现场钢结构支撑方案——工装架,为机床提供有效稳定的支撑,方便现场加工,使加工结果达到技术要求。本文主要内容为工装架的制造介绍。     

多糖金属配合物的研究进展

多糖金属配合物由于其结构和生物活性的特殊性已成为当今天然产物研究领域的热门课题,研究的热点主要集中在植物类多糖铁复合物和壳聚糖与钙、铁、铜、稀土元素离子形成的配合物上。该文对多糖金属复合物的制备工艺、理化性质和药理作用、工业用途等方面进行了综述。     

耦合双桩共振子MDM波导结构中光学性质的研究

采用时域有限差分方法研究了同侧和异侧耦合双桩共振子的MDM波导结构中的光学性质．发现同侧耦合双桩共振子的MDM波导中桩间距改变时对透射谱影响很大,当间距较小时,出现两个很尖锐的透射峰,当间距较大时,其中一个峰消失,另一个峰增强．异侧耦合双桩共振子的MDM波导结构中桩长度不一样时,能导致Fano共振而产生新的尖锐的峰．     

金属橡胶在巧克力奶过滤上的应用研究

金属橡胶兼有金属和橡胶的双重性质,具有一系列优良特性.运用VHX-600超景深三维显微镜和HPCA-2便携式污染度检测仪等设备,选用不同结构参数的金属橡胶,对巧克力奶进行过滤研究.通过改变材料孔隙度、丝径和成型厚度3个因素,绘制出巧克力奶过滤前后污染度等级变化折线图.最后对折线图进行横向和纵向比较,总结出材料孔隙度的降低、丝径的减小以及厚度的增大均可提高材料的过滤性能.     

动载荷作用下铁磁性试件的磁记忆效应

研究地磁场环境中钢试件在动拉伸载荷作用下表面弱磁信号的变化以及磁记忆效应.分别进行弹性范围的等幅循环正弦加载和幅值递增至强度极限的正弦加载,对试件表面弱磁场法向分量与正弦加载的循环次数、幅值之间的关系进行了分析.结果表明,弹性加载中低频载荷的循环次数对磁信号增长的影响不明显,而幅值递增加载过程中,当幅值增大至塑性加载范围时,磁信号的变化趋势与弹性加载时相反,且信号绝对值显著增加,最终磁信号的分布在发生颈缩处出现梯度很大的过零.     

全膜润滑金属成形工艺的有限元仿真分析

全膜润滑的金属成形的数值分析非常少,这主要是由于求解润滑模型的方法只适用于轴对称和平面应变情况.因此,本文中提出了全润滑膜润滑和金属成形有限元法相结合的统一方法,适用于稳态和非稳态的三维成形工艺,也适用于轴对称和平面应变情况.而一个轴对称拉深成形被用来做一个样板实验.该法大幅度增加了仿真的精度.而理论计算的润滑膜厚与实测值相一致,这也证明本文的方法优于其它方法.     

New secondary batteries and their key materials based on the concept of multi-electron reaction

Facing the significant applications in energy field, this paper introduces how to construct new high specific energy secondary batteries based on the concept multi-electron reaction and by designing multi-electron electrode materials. Recent progress on those new secondary batteries and their key materials based on the theory of multi-electron reaction are overviewed. Representative multi-electronic electrode materials, such as metal borides, metal fluorides, sulfur composite electrode materials and ferrates are briefly introduced, as well as the new secondary battery systems constructed with these materials. Thus gives the significance of the development based on multi- electron reaction mechanism of secondary batteries and their key materials for new chemical battery systems and related energy materials.     

Growth mechanism of liquid Hg/solid β-HgS metal-semiconductor heterostructures

Density functional theory （DFT） was utilized to simulate the reactions occurred in the mixture solution of cysteine and Hg（II） ions with the ratio 〈 2. Simulation result shows that Hg ions will coordinate to cysteine by the thiol groups with the form of S-Hg2 and S-Hg3; and moreover, the content of free Hg ions can only be reduced by these two forms. OH- plays an important role in the growth of β-HgS, because its nucleophilic substitution reaction supplies plenty of Hg-S-Hg radicals, which will be adsorbed onto the surface of liquid mercury ball and form the precursor of 13-HgS（111） plane. Three valent bonds adsorption of Hg-S-Hg radicals onto the surface of Hg ball has more adsorption energy （-32.768 kcal mol-1） than that of two valent bond adsorption （-20.882 kcal - mol-1）. Hg balls will stop growing after completely covered with Hg-S-Hg radicals and their size will be limited. The growth direction of β-HgS is parallel to the ＂repel- ling＂ force, that is [111] direction in β-HgS lattice. The calculated results are in good agreement with the experimental observations, demonstrating that the DFT method can be taken as a very useful tool to interpret the solution reactions that cannot be solved by conventional methods.