大水沟地区金多金属矿成矿地质背景及找矿远景分析

通过几年的野外勘查工作,大水沟矿区在找矿方面取得了较为显著的成果,矿区内圈定了2处水系沉积物综合异常,通过异常查证,目前发现了3条矿化蚀变带,圈出金矿体5条、铜矿体1条、钼矿化体1条、铅锌银矿化脉1条。其中金矿体主要赋存于蚀变的碎裂岩中,对发现的矿体沿走向进行了槽探揭露、钻探深部验证控制,矿体沿走向、倾向具一定延伸,深部品位变富,与邻近五龙沟金矿田具有相似的成矿地质背景及成矿规律,说明该矿区具有较大的找矿空间。     

三种多金属氧酸盐的制备及催化H_2O_2氧化淀粉性能比较

以磷钼钒多阴离子[PMo11VO40]4-、[PMo10V2O40]5-、[PMo9V3O40]6-为构建基元,分别和1-辛基-3-甲基咪唑阳离子通过离子交换反应制备三种多金属氧酸盐。以这三种多金属氧酸盐为氧化性催化剂,可溶性淀粉为原料,双氧水为氧化剂,应用于淀粉氧化实验并比较它们的催化氧化活性。试验结果显示,三种催化剂均具有较好的催化性能,其中用[Omim]4H[PMo10V2O40](OPMo V2)作催化剂时氧化淀粉中的羧基含量最高。     

单取代环戊二烯基金属羰基配合物的合成及晶体结构

配体C5H5R[R=CH2Ph(1),nBu(2)]分别与Fe(CO)5,Ru3(CO)12在二甲苯中加热回流,得到了3个新的双核配合物[(η5-C5H4CH2Ph)Fe(CO)(μ-CO)]2(3),[(η5-C5H4nBu)Fe(CO)(μ-CO)]2(4)和[(η5-C5H4CH2Ph)Ru(CO)(μ-CO)]2(5).通过元素分析、红外光谱、核磁共振氢谱对配合物的结构进行了表征,并用X射线单晶衍射法测定了配合物5的结构.结果表明:晶体属于单斜晶系,P21/m空间群,a=0.678 94(13)nm,b=1.225 8(2)nm,c=0.781 16(13)nm,α=90°,β=113.407(2)°,γ=90°,V=596.61(19)nm3,Dc=3.477g/cm3,μ=2.597mm-1,F(000)=620,Z=2,R1=0.022 6,wR2=0.059 5.CCDC:881473.     

逆变式高频窄脉冲微弧氧化电源的设计

为增强微弧氧化过程中电弧的可控性,从脉冲能量控制角度,设计了一种逆变式高频窄脉冲微弧氧化电源.该电源在传统的两级逆变电路结构基础上,增加了阻抗匹配电路,实现了变极性模式下回路及负载中能量的快速释放与存储.文中还详述了实现多种模式输出的协同控制策略及对应的电路工作模式,分析了电源的负载特性,并通过仿真和实验波形验证了该负载特性等效模型的有效性.实验结果表明,通过提高电源输出脉冲频率(最高20 k Hz)及减小脉冲宽度(最窄20μs),可实现对脉冲能量的精密控制和提高系统的能量利用率;高频窄脉冲处理模式获得的膜层表面孔隙率和表面粗糙度更低.     

Hydrothermal synthesis,structures and properties of metal phosphonates based on m-xylylenediphosphonic acid

In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on m-xylylenediphosphonic acids （H4L）, including [M（H2L）（bpy）] （M = Mn 1, Co 2）, [MH2L）（phen）] （M = Co 3, Cu 4）, and [Cu2（H2L）2（bpy＂）2] 5 （bpy = 2,2＇-bipyfidine, phen = 1,10-phenanthroline, bpy＂ = 4,4＇-dimethyl-2,2＇- bipyridine）. X-ray diffraction indicated that compounds 1 and 2 were isomorphic. Complexes 3 and 4 were shown to crystallize in different space groups but had similar crystallographic units. In the complexes, H4L was seen to partially deprotonate to afford H2L^2-. The H2L^2- ligands in 1-4 functioned as tetradentate ligands with each phosphonate group adopting bidentate coordination mode with two M centers to generate a 2D layer. In addition, the H2L^2- anions in 5 functioned as tfidentate ligands with one phosphonate group adopting the bidentate mode and another phosphonate group adopting the monodentate mode, thus linking three Cu atoms to provide a 1D chain. The IR and thermal stabilities of these compounds were subsequently examined.     

Progress in the research of radical anion ligands and their complexes

Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and properties of the corresponding complexes were introduced. The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.     

Progress of transition metal-catalyzed cross-coupling mediated by PyBroP

In the transition metal-catalyzed cross-coupling reactions, phenol and enol derivatives activated by phos- phorus groups are very important electrophiles. This kind of compounds has the advantages of easy preparation, great stability, and producing more benign phosphorus by-pro- ducts. The present work provides a comprehensive review of the advances made over the past several decades in this area. Cross-coupling reactions mediated by PyBroP are first surveyed, then two types of recently developed tran- sition metal-catalyzed reactions, i.e., Pd-catalyzed and Ni- catalyzed reactions, and the corresponding mechanisms are discussed. Finally, future directions are analyzed.     

金属热容量与温度关系的实验测定及理论研究

测量了铜、铁和铝在55~200℃范围内的热容量.基于爱因斯坦和德拜固体热容理论模型,利用Matlab软件对实验数据进行了模拟和处理,得到了3种金属的热容量与温度的关系曲线.结果发现,在实验误差允许范围内,实验结果与爱因斯坦理论和德拜理论都具有较好的一致性.     

负载Dawson结构磷钨酸催化剂及其在有机反应中应用研究进展

Wells－Dawson型磷钨酸（ H6 P2 W18 O62（ HP2 W）是一种具有超强酸性和显著稳定性的绿色环保型催化剂,可以代替传统催化剂HF, HCl, H2 SO4在均相和非均相中发生反应,比Keggin型磷钨酸H3 PW12 O40（ HPW）催化活性还高。综述了近几年利用不同载体制备负载Dawson型磷钨酸催化剂的方法及其在催化有机反应中的研究现状,并对新型载体金属有机骨架和负载Dawson型磷钨酸未来的发展前景进行了展望。     

不对称三相电路的分析及计算

在三相电路分析和计算中,不对称电源或负载加大了电路网络分析和计算的难度。对于电源不对称的三相电路,可以根据“对称分量法”将不对称的分量分解成对称的分量,对单相进行分析和计算;对于不对称的静负载,又可以通过直接列出节点电压方程来进行求解。这些方法广泛地应用于不对称三相电路,使得电路变得简单、容易,减少了计算量。算例演示了计算步骤和方法,验证了其有效性和正确性。