金属玻璃(Fe_55Ni_45)_78Si_8B_14的低温结构弛豫

使用Bordoni型仪器测量了Fe—Ni基金属玻璃在结构弛豫过程中内耗和模量的变化,详细地研究了在低于500K的低温阶段模量的变化。结果表明,结构弛豫对温度的特性可划分为两个阶段:低温结构弛豫,主要由TSRO控制;高温结构弛豫,主要由TSRO和CSRO控制。低温结构弛豫的激活能约为17kJ/mol。     

线材修磨的磨削压力与砂带速度

本文根据砂带与线材间的接触状态,讨论了砂带修磨线材机理的有关问题,导出了磨削压力、砂带速度与金属去除率之间的关系.试验结果表明;磨削压力的变化对磨削过程具有极为重要的影响,增大磨削压力可大大地提高磨削生产率,降低比磨削能.     

容积—节流联合调速系统性能分析

本文以流体力学、控制理论为基础,对限压式变量泵与调速阀组成的调速系统的工作原理、静动态性能进行了较全面的理论分析,并对系统的设计、调整等问题作了有益的探讨,为容积—节流联合调速系统的推广使用提供理论基础。     

Progress in the synthesis and reactivity studies of metallabenzenes

Metallabenzenes are metallacyclohexatriene complexes that are derived by replacement of one of the CH groups in benzene with a transition-metal fragment. Their synthesis and aromatic properties have recently attracted considerable attention. This paper summarizes the progress in the synthesis, aromatic property, and reactivity studies of metallabenzenes. We will describe the synthesis and reactivity of typical metallabenzenes with various metals (e.g. osmium, iridium, and ruthenium, etc.), the synthesis and structure of a recent reported example of metallanaphthalene and several rare examples of novel and stable metallabenzynes. Finally, the possible future developments in this field have also been suggested.     

<Emphasis Type="Italic">In situ</Emphasis> synthesis of TiC reinforced Cu<Subscript>47</Subscript>Ti<Subscript>34</Subscript>Zr<Subscript>11</Subscript>Ni<Subscript>8</Subscript> bulk metallic glass composites

In situ synthesized TiC particles and β-Ti dendrites reinforced Cu47Ti34Zr11Ni8 bulk metallic glass (BMG) composite ingots were prepared by the suction casting method.The ingots with diameters from 1 up to 4mm were successfully obtained. It was shown that introducing TiC micro-sized particles into the amorphous matrix did not disturb the glass forming ability (GFA) of the matrix,while the yield strength and ductility could be well improved.The phase constitution, microstructure and elements distribution in the composites were studied by OM, XRD, SEM and EDS.It was shown that the in situ synthesized TiC particles acting as heterogeneous nucleation sites promoted the precipitation of β-Ti dendrites, resulting in the formation of the TiC particles and β-Ti dendrites co-reinforced BMG composites. The compressive tests were employed to probe the yield strength and ductility of BMG composites.     

Study on the distribution of active centers in novel low Ti-loading MgCl2-supported Ziegler-Natta catalyst

Novel MgCl2-supported Ziegler-Natta (Z-N) catalysts prepared using a new one-pot ball milling method can effectively control the amounts of Ti-loading in the catalysts. Complex GPC data on polypropylene synthesized by these novel catalysts were analyzed using the method of fitting the molecular weight distribution (MWD) curves with a multiple Flory-Schulz function. It was found that multiple active centers exist in these novel catalysts. Detailed study of the effects of the Ti-loadings in the catalysts on the distribution of the active centers showed that the Ti-loadings in the novel MgCl2-supported Z-N catalysts might affect the proportion of each type of active centers; and might be the main factor responsible for the effect of the Ti-loadings on the microstructure, the molecular weight and molecular weight distribution width of the resultant polymer, the catalytic activity and polymerization kinetics.     

Optimization of short-pulse GPR transmit antenna

By analyzing the current distribution of Bow-Tie amerma used in short-pulse ground penetrating radar, the methods of antenna load and driving are presented in this paper to reduce strength of reflective wave both at antenna end and excitation point. The numerical simulation results show the strength oi reflective wave is smaller than -55dB comparing with the driving wave when the methods are adopted.     

聚碳酸酯在催化剂作用下的降解反应

以乙酸锂作为酯交换催化剂的代表,用红外光谱（ＩＲ）、核磁共振（ＮＭＲ）、凝胶色谱（ＧＰＣ）等分析方法研究了催化剂对聚碳酸酯（ＰＣ）相对分子质量及分子结构的影响,并用差热分析（ＤＳＣ）研究了ＰＣ在催化剂作用下的降解反应的反应动力学。结果表明,随催化剂的加入,ＰＣ发生了降解反应,相对分子质量降低,得到了带酚羟基末端基的ＰＣ分子链,其降解动力学符合一般动力学方程。     

常压等离子体渗氮应用初探

通过对现有的常规等离子体轰击渗氮技术的分析,提出了常压等离子体渗氮技术,分析了常压等离子体渗氮技术的原理和特点,并对常压等离子体渗氮技术的可行性进行了初步的实验研究,研究结果初步证明常压等离子体渗氮技术有可能成为一种前途的金属表面强化技术,论文的最后指出该技术尚待解决一些问题。     

节流调速回路的效率分析

调速回路是液压系统中的核心部分,其工作性能的好坏对整个系统起着决定性的作用,而节流调速回路在其中又获得了广泛的应用。因此,分析和研究节流调速回路的效率特性,为节流调速回路及有关液压元件的合理选择、设计、调试和应用,为提高节流调速回路的效率提供有效的方法,具有重要的技术经济意义。节流调速系统的效率可以表示为：刁一pl·刁2·刁3”河电式中V——节流调速系统的总效率VI——驱动液压泵的电动机效率只——液压泵的效率p3——节流调速回路的效率g4——执行元件（液压缸或液压马达）的效率由上式可知,要提高调速系统效…