Densification behavior of mechanically milled Cu–8 at% Cr alloy and its mechanical and electrical properties

Synthesis and consolidation behavior of Cu–8 at%Cr alloy powders made by mechanical alloying with elemental Cu and Cr powders,and subsequently,compressive and electrical properties of the consolidated alloys were studied.Solid solubility of Cr in Cu during milling,and subsequent phase transformations during sintering and heat treatment of sintered components were analyzed using X-ray diffraction,scanning electron microscopy and transmission electron microscopy.The milled powders were compacted applying three different pressures(200 MPa,400 MPa and 600 MPa)and sintered in H2atmosphere at 900 1C for 30 min and at 1000 1C for 1 h and 2 h.The maximum densification(92.8%)was achieved for the sample compacted at 600 MPa and sintered for 1000 1C for 2 h.Hardness and densification behavior further increased for the compacts sintered at 900 1C for 30 min after rolling and annealing process.TEM investigation of the sintered compacts revealed the bimodal distribution of Cu grains with nano-sized Cr and Cr2O3precipitation along the grain boundary as well as in grain interior.Pinning of grain boundaries by the precipitates stabilized the fine grain structure in bimodal distribution.     

Growth, structural, optical, thermal and dielectric properties of a novel semi-organic nonline ar optical crystal: Dichloro-diglycine zinc II

Dichloro-diglycine zinc II(DCDGZ II),a semi-organic nonlinear optical material has been synthesized and single crystals were grown from the aqueous solution up to dimensions 20×10×3 mm3.The title compound,DCDGZ II(C4H10Cl2N2O4Zn H2O) crystallizes into monoclinic structure with the space group of C2/c.The unit-cell parameters were found to be a=14.4191(7),b=6.9180(2),c=12.9452(6) and Z=4.In the crystal structure,DCDGZ II layer is building up alternatingly with layers of water in which the zinc ions lie on a twofold axis.Theoretical calculations for polarizability,which are useful for device fabrication were made using Clausius–Mosotti equation and Penn analysis and the results were compared.Fourier transform infrared(FTIR) spectroscopic studies were performed for the identification of the different functional groups presented in the compound.The UV–vis–NIR absorption spectrum reveals that the lower UV cut-off wavelength is 240 nm.The optical band gap of the crystal was estimated as 2.2 eV.The surface morphology,thermal behaviour,dielectric properties have been studied using SEM,TG/DTA and LCR HITESTER analyzer.The nonlinear optical property of the crystal was also confirmed using Kurtz powder technique.     

A simulation study on the thermal and wetting behavior of alkane thiol SAM on gold (111) surface

Molecular dynamics simulations have been performed to investigate the structural,thermal and wetting properties of self-assembled monolayer(SAM) of alkane thiol on gold surface.The specific heat capacity of the gold SAM surface was found to linearly increase with the temperature in the range 100–300 K.It was found to drop down at 400 K and this decrease might be attributed to the disorder of the SAM chains.Hydration of gold SAM surface for two different terminal groups,namely methyl(hydrophobic),and hydroxy(hydrophilic) was studied at room temperature.The difference in their wetting behavior and the structure of their interfacial water were examined from the estimation of the z density profile,radial distribution function,hydrogen bonds and orientation of water dipoles in the interfacial region.The present simulation results suggest that the wetting behavior of the gold SAM surface can be modified by altering the terminal functional group of the SAM chains.     

In fl uence of HEPES buffer on the local pH and formation of surface layer during in vitro degradation tests of magnesium in DMEM

The human body is a buffered environment where p H is effectively maintained. HEPES is a biological buffer often used to mimic the buffering activity of the body in in vitro studies on the degradation behavior of magnesium. However, the influence of HEPES on the degradation behavior of magnesium in the DMEM pseudo-physiological solution has not yet been determined. The research aimed at elucidating the degradation mechanisms of magnesium in DMEM with and without HEPES. The morphologies and compositions of surface layers formed during in vitro degradation tests for 15–3600 s were characterized. The effect of HEPES on the electrochemical behavior and corrosion tendency was determined by performing electrochemical tests. HEPES indeed retained the local p H, leading to intense intergranular/interparticle corrosion of magnesium made from powder and an increased degradation rate. This was attributed to an interconnected network of cracks formed at the original powder particle boundaries and grain boundaries in the surface layer, which provided pathways for the corrosive medium to interact continuously with the internal surfaces and promoted further dissolution. Surface analysis revealed significantly reduced amounts of precipitated calcium phosphates due to the buffering activity of HEPES so that magnesium became less well protected in the buffered environment.     

如何解决中短波发射机之间的电磁干扰

中短波信号发射系统是目前我国广播通讯系统中应用最为广泛的,但是中短波发射设备之间在运行过程中会产生大量的电磁干扰,这种存在于发射机之间的强高频电磁干扰会对设备的运行以及广播信号的传播造成巨大的影响,严重影响系统的正常运行。所以,为了提高广播中心的工作质量,电磁干扰问题成为了广播系统中亟待解决的问题。通过对电磁干扰的研究,可以看出中短波电磁干扰仅仅只是一种笼统的定义,其包含诸多的系统,例如控制、监视以及值班环境中的电磁干扰等。文章主要便针对中短波广播发射系统中存在的问题以及相关解决措施展开了详细的讨论。     

苏里格气田天然气处理厂外包业务管理模式探索

本文首先介绍了外包的概念,外包单位的简单介绍及目前的现状,然后从最适合的外包管理模式进行探索,推出了目前适合苏里格气田的外包管理标准和要求,最后从绩效激励方面谈了点措施和一些建议。     

不同有机负荷下餐厨垃圾厌氧消化的甲烷产率

为了实现餐厨垃圾的资源化利用,在中温35℃的条件下,采用半连续进料方式,在改变有机负荷的情况下,探讨餐厨垃圾厌氧消化过程中的产甲烷规律。结果表明:有机负荷在5、6和7 g/(L·d)的条件下,CSTR反应器可以正常运行,甲烷产率分别为0.416、0.414和0.384 L/(g·d),甲烷平均质量分数分别为57.6%、56%和52.9%。该研究说明餐厨垃圾厌氧消化产生甲烷的潜力巨大,能够实现餐厨垃圾资源化利用。     

窄带Faraday反常色散光学滤波器

研究Faraday反常色散光学滤波器,给出其理论计算过程和模拟结果.结果表明,Faraday反常色散光学滤波器有线翼和线芯透过两种工作方式,其中线翼透过单峰谱线线宽约为600MHz,透过率约为25%,线芯透过谱线线宽约为700MHz,透过率约为100%.实验结果与理论结果相符.     

基于FPSO-SA算法的威布尔分布参数估计研究

为解决威布尔分布等复杂分布模型采用常规方法很难直接进行参数估计的问题, 提出了基于模糊粒子群模拟退火算法的威布尔分布参数估计。该算法根据粒子个体纵向和横向运动特性, 引入模糊逻辑推理动态调整惯性权值因子, 提高了粒子群算法(PSO: Particle Swarm Optimization)的收敛速率; 将上述模糊粒子群算法(FPSO: Fuzzy Particle Swarm Pptimization)与模拟退火算法(SA: Simulated Annealing)结合, 以FPSO算法的速度位置更新公式作为SA算法的状态生成函数, 再运用Metropolis算法以概率接受新状态, 获得全局最优参数估计值。将基于上述智能算法的参数估计法运用到威布尔分布参数估计中, 提高了参数估计精度。实际应用表明, 该参数估计方法在复杂分布模型参数估计中具有可行性和有效性。     

Comparison of the effect of hydrogen incorporation and oxygen vacancies on the properties of anatase TiO2: electronics,optical absorption,and interaction with water

Hydrogenation has been recently developed as an approach to improve the visible-light response of titanium dioxide （TiO2）; however, the effect of hydrogenation on the electronics and optical absorption of anatase TiO2 has been widely debated. In this work, the electronic structures and optical properties of hydrogenated TiO2 and its interaction with water have been studied using the density functional theory plus Hubbard model. A comparison of the effect of hydrogenation and introduction of oxygen vacancies （OVs） to TiO2 is presented. It is found that both hydrogenation and OVs can promote the absorption of visible light and strengthen the adsorption of water. Compared with OVs, hydrogen incorporation can lead to local distortion and even amorphous structures when it is heavily doped.