Functionalized graphene oxide based on p-phenylenediamine as spacers and nitrogen dopants for high performance supercapacitors

p-Phenylenediamine （PPD） functionalized graphene oxide （GO） materials （PPDG） were prepared through a one-step solvothermal process and their appli-cation as supercapacitors （SCs） were studied. The PPD is not only as the spacers to prevent aggregating and re-stacking of the graphene sheets in the preparing process but also as nitrogen sources to obtain the nitrogen-doped graphene. The structures of PPDG were characterized by Fourier transformed infrared spectroscopy （FT-IR）, X-ray diffraction spectroscopy （XRD）, Raman spectroscopy and X-ray photoelectron spectroscopy （XPS） and the results show that the nitrogen-doped graphene was achieved with nitrogen content as high as 10.85 at.%. The field emission scanning electron microscopy （FE-SEM） and high resolu-tion transmission electron microscopy （HR-TEM） have confirmed that the morphologies of PPDG were looselayered with less aggregation, indicating that PPD mole-cules, as spacers, effectively prevent the graphene sheets from restacking during the solvothermal reaction. The special loose textures make PPDG materials exhibit excellent electrochemical performance for symmetric SCs with superior specific capacitance （313 F/g at 0.1 A/g）, rate capability and cycling stability. The present synthesis method is convenient and may have potential applications as ultrahigh performance SCs.     

Orbit determination of Chang＇E-3 and positioning of the lander and the rover

Chang＇E-3 landed on the east of Sinus Iridum area on December 14, 2013, performing China＇s first successful soft landing on the lunar surface. We present the results on precision orbit determination and positioning of the lander and the rover. We and methods used to achieve period December 2-21, 2014. describe the data, modeling, position knowledge over the In addition to the radiometric X-band range and Doppler tracking data, delta differential one-way ranging data are also used in the calculation, which show that they strongly improve the accuracy of the orbit reconstruction. Total position overlap differences are about 20 and 30m for the 100km × 100km and 100 kmx 15 km lunar orbit, respectively, increased by ,- 50 % with respect to CE-2 and at the same level as other lunar spacecrafts of recent era such as SELENE and lunar reconnaissance orbiter （LRO）. The position error of the soft landing trajectory is less than 100 m. A kinematic statistical method is applied to determine the position of the lander and relative position of the rover with respect to the lander. The position difference of the lander is better than 50 m compared to LRO photograph result. Compared with the delta very long baseline interferometry （VLBI） group delay between the lander and the rover, the delta VLBI phase delay can improve the relative position of the rover from ～ 1,000 to ～1 m.     

饮用水中氯代乙酰胺的细胞毒性和遗传毒性

通过细胞增殖实验、单细胞凝胶电泳实验、细胞凋亡实验和细胞周期阻滞实验分别测定了3种氯代乙酰胺(CAcAms)的细胞毒性和遗传毒性,同时结合饮用水中CAcAms的实际浓度水平,分析了3种CAcAms在饮用水中的毒性风险.结果表明,一氯乙酰胺(MCAcAm)在饮用水厂中的浓度低于二氯乙酰胺(DCAcAm)和三氯乙酰胺(TCAcAm),但由于MCAcAm的毒性较大,其在饮用水厂中的毒性风险高于DCAcAm和TCAcAm.相对于氯消毒,氯胺消毒后的饮用水中CAcAms的浓度较高,从而CAcAms造成的细胞毒性和遗传毒性风险也较高.     

健坤胶囊渗漉提取工艺研究

目的:筛选健坤胶囊渗漉提取工艺条件。方法:以白头翁皂苷B4、盐酸小檗碱、蛇床子素等的转移率为评价指标,采用单因素平行设计及多因素正交设计方法逐级优化健坤胶囊提取工艺。结果:最佳渗漉工艺条件为:30倍量70%乙醇,浸渍24h,流速为0.5mL/min。结论:该提取工艺稳定、重现性好,可作为本品的提取方法。     

颖学弘敏在奉新的经历考述

颖学弘敏系青原下三十七世、曹洞宗三十世传人,是传授八大山人“正法”并与其弟子在奉新头陀寺和耕香院共处时间达15年以上的禅门大德,对八大山人的影响可谓至深至远.为了探究八大山人成长经历,文章采用考证的方法,对颖学弘敏的人生轨迹、承传关系、禅门事迹三个问题进行了全面的探讨,作出了师徒二人在奉新的头陀寺和耕香院共同生活了15年的结论,对进一步研究八大山人的成长成历、生平事迹和艺术成就有重要的参考价值.     

1,4,7-三氮杂环壬烷合钴与牛血清白蛋白的相互作用

利用荧光光谱法研究了1,4,7-三氮杂环壬烷合钴(Ⅱ)与牛血清白蛋白的相互作用,实验结果表明1,4,7-三氮杂环壬烷合钴(Ⅱ)对牛血清白蛋白的荧光猝灭是静态猝灭,并得出在水溶液和胶束溶液中1,4,7-三氮杂环壬烷合钴(Ⅱ)与牛血清白蛋白作用的结合点位数、结合常数和热力学参数,△H0,△S0,其分子间的作用力主要表现为疏水作用力.     

小清河滞洪区洪水演进数学模型的研究

随着我国经济的发展,蓄滞洪区的开发和建设越来越受到人们的关注,对滞洪区进行洪水演进数值模拟研究非常必要.本文采用有限体积法建立了二维洪水演进数学模型,并对洪水演进的水量平衡计算模式进行改进,提出单元水量出流修正法,消除了有限体积法单元体内出现负水深,产生虚假流动的现象.将该研究成果应用于小清河滞洪区洪水演进的数值模拟,采用实测资料,对小清河滞洪区50年一遇洪水演进进行验证和模拟,从而得到泛区内洪水形势及淹没情况,为滞洪区分洪调度提供理论指导.     

准噶尔盆地北缘山前带湿地扇沉积特征及控藏作用

综合野外露头、岩心、钻测井以及分析测试资料等,对准噶尔盆地北缘哈拉阿拉特山山前带侏罗系八道湾组开展了系统的沉积相研究。结果表明:八道湾组一段沉积时期,受构造背景、古物源、古气候的综合影响,哈山南缘山前带发育一套典型的湿地扇沉积,可识别出扇根、扇中、扇缘三种亚相,扇中可进一步分为辫状水道和泥炭沼泽两类微相;在明确了相类型及其展布特征的基础上,建立研究区湿地扇沉积相模式,其在岩性特征、沉积序列、平面规模、微相组合等方面均与洪积扇有明显区别;山前带湿地扇沉积区具有良好的勘探潜力,有利的微相、岩石相以及原始沉积组构共同控制着油藏分布,其中扇中辫状水道砂砾岩相和粗砂岩相为原油富集的有利储集相带。     

加肋凹型锥-环-柱结合壳稳定性几何修正方法

针对加肋凹型锥-环-柱结合壳这一新型连接结构,分析了初始几何缺陷的形态及其可能出现的位置,并运用有限元仿真技术,得到影响最大的初始几何缺陷形态组合以研究壳板稳定性几何修正方法.通过单因素数值试验,分析了各结构参数对几何修正系数Cg的影响.并提出了Cg的计算方法.结论如下:(1)距环壳临近一档圆锥壳的Cg与各结构参数的关系同普通圆锥壳的Cg有差异;(2)经算例检验,提出的Cg计算方法精度较高,可在工程计算中应用.     

矩形截面半潜式平台浪流耦合作用涡激运动响应二维数值模拟

通过计算流体力学(CFD)数值模拟,针对一型采用矩形截面立柱设计的深吃水半潜式生产平台,研究其在波浪和流共同作用时的涡激运动响应.选取典型135°来流方向,以正弦振荡流模拟波浪,考虑不同KC数、不同相对流数下波浪与同向均匀流耦合作用.研究表明,较之于仅有均匀流作用,均匀流和正弦振荡流耦合作用时,矩形截面立柱的半潜式平台运动响应明显增大.振荡流耦合作用影响显著.