单分子层正癸酸包覆Fe_3O_4纳米粒子的研究

应用微乳液与 Fe2 + 和 Fe3 + 化学共沉淀的方法制备了正癸酸包覆的 Fe3 O4纳米粒子水基磁流体 .用光子相关光谱仪 ( PCS)、透射电镜 ( TEM)和 JDM- 3型振动样品磁强计对制得的水基磁流体进行了表征 .制备了单分子层正癸酸包覆的 Fe3 O4纳米粒子的固态样品 ,并利用 IR,TG,DTG与DSC考查了该固态样品的组成与性质 .发现用一步表面活性剂处理可以直接制得双层表面活性剂包覆的 Fe3 O4纳米粒子水基磁流体 .     

基于反滴加-共沉淀法的水基Fe3O4磁流体制备及性能表征

用化学共沉淀法制备了Fe3O4纳米微粒,并用聚乙二醇(PEG)为表面活性剂进行表面修饰,制备稳定的水基Fe3O4磁流体,考察加料方式、铁盐浓度、表面活性剂用量等条件对Fe3O4纳米微粒粒径的影响,并用红外光谱及X射线衍射表征磁性颗粒的化学成分和晶体结构.结果表明:加料方式是影响产物粒径和磁性的重要因素,反滴法制备的磁流体粒径更小,磁性更强;铁盐浓度越高,磁流体粒径越大;随PEG质量浓度增大,磁流体粒径先减小后增大;n(Fe3+)=n(Fe2+)=0.3 mol/L,c(PEG)=50 g/L为最适宜的反应条件;未经包覆的Fe3O4纳米粒子平均粒径为15 nm,PEG包覆后粒径约为20 nm,呈现出核-壳结构.     

用于水处理的磁性Fe3O4纳米微粒研究

采用化学共沉淀法和水热法制备Fe3O4纳米磁性粒子及油酸包覆Fe3O4磁流体。通过实验确定最佳反应条件;用XRD分析Fe3O4粒子的晶体结构;用TEM观察磁流体样品的微观结构;用HPLC研究纳米粒子对左旋氧氟沙星溶液模拟废水超声降解的影响。结果表明产物为反尖晶石结构立方晶系的AB2O4型化合物,平均粒径小于15 nm;磁流体基本上为规则的球形,颗粒均匀,无团聚情况;制得的磁流体样品具有较好的流动性和超顺磁性;Fe3O4纳米粒子对左旋氧氟沙星具有一定的降解性能。     

磁性Fe3O4明胶复合纳米粒子的制备与表征

用化学共沉淀法制备磁性Fe3O4纳米粒子,然后用异丙醇为凝聚剂采用单凝聚法制备磁性Fe3O4明胶复合纳米粒子。考察了明胶浓度与异丙醇的体积以及Fe3O4含量对粒径分布及性能的关系。采用透射电子显微镜和Zetasizer粒度分析仪测量磁性明胶复合纳米粒子的平均粒径,X射线衍射仪和红外光谱以及热重及差热分析进行结构和热稳定分析。结果表明磁性Fe3O4明胶复合纳米粒子中的Fe3O4纳米粒子被明胶所包覆,而且粒径很小,具有良好的热稳定性。     

四氧化三铁磁流体的制备及性能分析

采用化学共沉淀法制备了Fe3O4磁流体。以阴离子表面活性剂油酸钠对磁性颗粒进行包覆,分析了pH值、温度和Fe2+/Fe3+比例等制备条件对Fe3O4磁流体的影响。运用磁天平、粒度测试仪对磁流体的粒径和磁化率进行了测定,并用傅里叶变换红外光谱仪(FT-IR)、透射电子显微镜(TEM)和振动样品磁强计(VSM)等对磁流体进行了表征。实验和分析结果表明,所制备的磁流体具有超顺磁性,粒径约为16 nm,饱和磁化强度在73.8 emu/g以上。     

磁性壳聚糖纳米粒子的制备及表征

以市售Fe3O4粉末为原料,经化学处理制得纳米Fe3O4糊状物;向Fe3O4糊状物中加入壳聚糖,制得磁性壳聚糖纳米粒子.用透射电子显微镜观察到Fe3O4粒子呈较规则的球形,粒径为8～12 nm,分布均匀;包覆壳聚糖以后,粒子粒径增大到10～15 nm.经红外光谱检测,壳聚糖已包覆Fe3O4粒子.用紫外-可见光谱仪检测溶液吸光度的变化来研究包覆粒子的磁响应性,研究结果表明:当无外加磁场时,粒子的沉降速率很慢;当施以磁感应强度为8 mT的磁场时,粒子沉降速率快速增大;磁性壳聚糖纳米粒子具有磁性稳定和靶向性强的优点.     

超声乳化法制备纳米Fe3O4磁性颗粒及壳聚糖表面改性

采用超声乳化法制备纳米Fe3O4磁性颗粒,以壳聚糖作为表面活性剂,制备具有生物亲和性的水基Fe3O4磁流体.研究了Fe2+/Fe3+摩尔比、超声时间和表面活性剂用量对磁流体性能的影响.结果表明:当Fe2+/Fe3+摩尔比为1:1·5,滴加氨水时反应温度为70℃时,可制备理想纳米Fe3O4磁性颗粒;超声时间为7·5min左右,质量分数1%的壳聚糖溶液体积占FeO溶液总体积的50%时,有利于壳聚糖分子的包覆,使磁流体具有较高的比饱和磁化强度及稳定性.     

水基Fe3O4磁流体的制备和磁光特性

以FeSO44@7H 2O(AR),Fe(NO3)3@9H2O(AR),NH3@H2O(AR)为原料,用水热法制备纳米Fe3O44粒子;通过选用合适的分散剂来克服磁性颗粒的沉降,采用超声波分散的方法,制备在重力场和磁场中稳定性好的磁流体.研究了影响水基FeaO4磁流体性能的主要因素,得到最佳条件Fe(NO3)3@9H2O和FeSO4@7H2O的量比为1.75,水热反应温度为160℃,反应时间为5 h,1.5 g Fe3O4分散于100 mL水中所需分散剂的用量为0.75 mL.所制备的产物经XRD和粒度仪检测,结果表明产物为单一相的Fe3O44,水基Fe3O4磁流体体系的粒径在100nm以下.     

水基Fe3O4磁流体的制备和磁光特性

以FeSO4·7H2O(AR),Fe(NO3)3·9H2O(AR),NH3·H2O(AR)为原料,用水热法制备纳米Fe3O4粒子;通过选用合适的分散剂来克服磁性颗粒的沉降,采用超声波分散的方法,制备在重力场和磁场中稳定性好的磁流体.研究了影响水基Fe3O4磁流体性能的主要因素,得到最佳条件:Fe(NO3)3·9H2O和FeSO4·7H2O的量比为1.75,水热反应温度为160℃,反应时间为5h,1.5gFe3O4分散于100mL水中所需分散剂的用量为0.75mL.所制备的产物经XRD和粒度仪检测,结果表明:产物为单一相的Fe3O4,水基Fe3O4磁流体体系的粒径在100nm以下.     

纳米Fe3O4磁流体的制备及表征

采用化学沉淀法制备纳米Fe3O4颗粒,并以聚乙二醇为改性剂,蒸馏水为载液,制备出固体质量分数为10%的纳米Fe3O4磁流体.用XRD研究Fe3O4纳米粒子的结晶情况;用FT-IR研究聚乙二醇改性前后Fe3O4粒子表面官能团的变化;用TEM研究Fe3O4颗粒的粒径大小及改性情况;用VSM研究Fe3O4粒子的磁性能.结果表明,制备的纳米Fe3O4为立方晶型,平均粒径在15 nm左右,聚乙二醇物理吸附在Fe3O4表面,Fe3O4颗粒几乎没有磁滞,具有超顺磁性.     

Characterization of Ordovician carbonate reservoirs, southeastern Saskatchewan, Canada

The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3～4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰～ -7.8‰, PDB) and matrix dolomites (-6.6‰～ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084～0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078～0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.     

A computer generator for randomly layered structures

AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…     

海南岛地体及其毗邻陆缘晚中生代—新生代古地磁研究和构造演化

本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。     

Exciton Seebeck in Molecular Systems

Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with     

Achieving Unusual States of Matter Under High Pressure

The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to     

《Chinese Science Bulletin》SUBJECT INDEX TO VOLUME 59(2014)

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An on-line scaling method for improving scalability of a database cluster

The explosive growth of the Internet and database applications has driven database to be more scalable and available, and able to support on-line scaling without interrupting service. To support more client's queries without downtime and degrading the response time, more nodes have to be scaled up while the database is running. This paper presents the overview of scalable and available database that satisfies the above characteristics. And we propose a novel on-line scaling method. Our method improves the existing on-line scaling method for fast response time and higher throughputs. Our proposed method reduces unnecessary network use, i.e. , we decrease the number of data copy by reusing the backup data. Also, our on-line scaling operation can be processed parallel by selecting adequate nodes as new node. Our performance study shows that our method results in significant reduction in data copy time.     

An improved R-tree based on childnode''s probability

R-Tree is a good structure for spatial searching. But in this indexing structure,either the sequence of nodes in the same level or sequence of traveling these nodes when queries are made is random. Since the possibility that the object appears in different MBR which have the same parents node is different, if we make the subnode who has the most possibility be traveled first, the time cost will be decreased in most of the cases. In some case, the possibility of a point belong to a rectangle will shows direct proportion with the size of the rectangle. But this conclusion is based on an assumption that the objects are symmetrically distributing in the area and this assumption is not always coming into existence. Now we found a more direct parameter to scale the possibility and made a little change on the structure of R-tree, to increase the possibility of founding the satisfying answer in the front sub trees. We names this structure probability based arranged R-tree (PBAR-tree).     

An Index mechanism for multi-scale view in spatial databases

There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.     

Integrating GIS Web services based on mediating architecture

The geographic information service is enabled by the advancements in general Web service technology and the focused efforts of the OGC in defining XML-based Web GIS service. Based on these models, this paper addresses the issue of services chaining,the process of combining or pipelining results from several interoperable GIS Web Services to create a customized solution. This paper presents a mediated chaining architecture in which a specific service takes responsibility for performing the process that describes a service chain. We designed the Spatial Information Process Language (SIPL) for dynamic modeling and describing the service chain, also a prototype of the Spatial Information Process Execution Engine (SIPEE) is implemented for executing processes written in SIPL. Discussion of measures to improve the functionality and performance of such system will be included.