安徽铜陵白芒山辉石闪长岩体的成因:Sr-Nd-Pb-O同位素制约

白芒山辉石闪长岩体位于安徽铜陵狮子山矿田内,属于高钾钙碱性岩系,形成时代为燕山晚期.运用Sr、Nd、Pb和O同位素综合示踪技术,探讨了该岩体的成因.研究结果表明,白芒山辉石闪长岩锶同位素初始值(ISr)变化于0.707291~0.707315之间;εNd(t)值变化于-13.04~-14.01之间;全岩δ18O值为10.2‰~11.7‰;初始铅同位素组成(t=142.9Ma)为:(206Pb/204Pb)i=17.9790~18.3267,(207Pb/204Pb)i=15.5125~15.6578,(208Pb/204Pb)i=38.1000~38.2117.结合安徽沿江地区岩浆岩研究资料可以看出,白芒山辉石闪长岩体为壳、幔岩浆混合成因,成岩物质起源于扬子下地壳和富集岩石圈地幔的部分熔融,是富集岩石圈地幔和扬子下地壳物质混合的产物,成岩过程后期经历了上地壳物质的混染作用影响.其中富集岩石圈地幔的形成主要与俯冲洋壳与陆壳析出流体的混染与交代作用有关.     

西秦岭竹林沟新生代碱性玄武岩地球化学及其成因

目的研究出露在甘肃礼县竹林沟地区的新生代火山岩成因及其大陆动力学意义。方法运用系统的岩石学、地球化学和Sr-Nd-Pb同位素地球化学特征进行分析。结果竹林沟火山岩具有低SiO2(40.72%～42.47%)、高TiO2(3.32%～3.62%),全碱含量高(K2O+Na2O=2.59%～3.40%),以及Na2O>K2O,K2O/Na2O=0.68～0.75的特征,属于典型的碱性系列钠质苦橄玄武岩-碱玄岩类。火山岩高的Mg#值(63.0～69.8)表明其原生岩浆的属性,岩石富集轻稀土,(La/Yb)N=39.3～41.9,(Ce/Yb)N=27.8～29.8,Ba,Th,Nb,Ta等元素呈显著的富集状态,具有典型的板内火山岩特征,而K和Rb含量较低,呈相对亏损状态。岩石87Sr/86Sr(0.704 189～0.704 418),143Nd/144Nd(0.512 803～0.512 906),206Pb/204Pb(18.643 446～18.685 488),207Pb/204Pb(15.591 105～15.594 871),208Pb/204Pb(39.042 692～39.077 318)等同位素变化特征具有显著的混源属性,投影点位于EMI,EMII,BSE及PREMA等典型地幔储库的过渡部位,不同于单一地幔源局部熔融形成的玄武岩的同位素组成特征。结论结合西秦岭新生代的总体构造背景,竹林沟钠质苦橄玄武岩-碱玄岩可能起源于一个特殊的多源混合地幔的局部熔融作用。新生代期间,青藏、扬子及华北3大构造体系域在西秦岭—松潘地区的强烈汇聚拼贴作用导致的深部地幔混合和这套特殊的钠质碱性玄武岩的产出有密切的成因关系。     

江西广丰碱性橄榄玄武岩的成因:SHRIMP锆石U-Pb年龄和元素、Sr-Nd-Pb同位素制约

广丰盆地红色沉积岩系下部夹有一层玄武岩,玄武岩的锆石具有明显的环带结构,显示岩浆成因的特征;SHRIMP锆石U-Th-Pb分析结果显示:Th/U=0.28~1.28,13个分析点的206Pb/238U年龄变化为88.5~102.5 Ma,加权平均年龄为(99.0±0.7)Ma,MSWD=1.3,地质时代属晚白垩世早期。在Si O2-(K2O+Na2O)和Nb/Y-Zr/Ti O2图解上均落入碱性玄武岩范围,显示碱性系列的特征,在TFe O/Mg O-Si O2图解上显示拉斑系列的特征,属典型的碱性橄榄玄武岩。较低的Nb/Th(=2.21~4.98,平均3.43)、Ti/Yb(=3 125~5 753,平均3975),较高的Nb/U(=6.63~25.82,平均16.24)和δ18O值(=8‰~9.6‰,平均值为8.9‰),指示碱性橄榄玄武岩有地壳物质的成分。(87Sr/86Sr)i-Si O2,εNd(t)-Si O2,(87Sr/86Sr)i-10 000/Sr和εNd(t)-100/Nd图解显示,地壳物质的加入主要是源区混合的结果。在(143Nd/144Nd)i-(206Pb/204Pb)i,(87Sr/86Sr)i-(206Pb/204Pb)i和(143Nd/144Nd)i-(87Sr/86Sr)i图解上,碱性橄榄玄武岩均显示是由亏损地幔(DMM)和岩石圈富集地幔(EMⅡ)端元混合而成,且亏损地幔成分所占比例高于浙东玄武岩,与浙西玄武岩相近。     

青藏高原东北缘马泉新生代碱性玄武岩地球化学及其成因探讨

马泉新生代碱性玄武岩出露在青藏高原东北缘,岩石SiO2介于40.40%～41.84%之间,TiO2含量高(3.73%～4.57%),K2O(0.37%～3.24%)和Na2O(0.57%～2.59%)含量高且变化范围较宽,K2O/Na2O为0.46～1.92,属于典型的幔源高钛-极高钛大陆溢流碱性玄武岩类。岩石微量及稀土元素具板内火山岩特征,Th、Rb等元素呈较明显的富集状态。岩石87Sr/86Sr(0.704090～0.704668),143Nd/144Nd(0.512770～0.512869),206Pb/204Pb(18.363698～18.866220),207Pb/204Pb(15.495292～15.602144),208Pb/204Pb(38.092958～39.399417)等同位素变化特征以及岩石高Mg(Mg#=60.7～65.9),高Sm/Yb值,(Ce/Yb)N在29.37～35.82,表明马泉碱性玄武岩的岩浆源区深度较大,应来源于软流圈地幔石榴石二辉橄榄岩的局部熔融。     

藏南雪莎地区辉绿岩脉的锆石U-Pb年龄、岩石地球化学和Sr-Nd-Pb同位素

探讨特提斯喜马拉雅在早白垩世的地质构造演化历史。通过对西藏南部雪莎地区辉绿岩进行LA-ICP-MS锆石U-Pb年龄、地球化学以及Sr-Nd-Pb同位素的研究,获得成岩年龄为124.5±2.6 Ma,全岩主元素及痕量元素地球化学特征显示:它们属于低钾(拉斑)系列,SiO_2质量分数为45.55%～46.67%,具有高TFeO(平均质量分数为9.62%)、高钛(TiO_2平均质量分数为1.73%)、高磷(P_2O_5平均质量分数为0.19%)等特点;轻、重稀土元素分馏较为明显(LREE/HREE=3.54～3.67,(La/Yb)_N比值平均为3.06),具有较弱的Eu正异常(δEu=1.02～1.19),富集大离子亲石元素(LILE,如Ba、Sr、Th)和高场强元素(HFSF,如Zr、Hf),呈现典型的洋岛玄武岩(OIB)地球化学特征;Sr、Nd、Pb同位素[(~(87)Sr/~(86)Sr)_t=0.705 17～0.706 14、(~(143)Nd/~(144)Nd)_t=0.512 748～0.512 809、ε_(Nd)(t)=5.27～6.46、(~(207)Pb/~(204)Pb)_t=15.564～15.587以及(~(206)Pb/~(204)Pb)_t=18.285～18.490]显示出亏损地幔特征。结合区域地质资料,认为雪莎地区辉绿岩形成于被动大陆边缘构造环境,具有OIB型地球化学特征,可能与澳大利亚Kerguelen地幔热柱有关,属于Comei-Bunbury大火成岩省的一部分。     

青藏高原东北缘白河碱性玄武岩地球化学及其源区性质探讨

运用地球化学及Sr-Nd-Pb同位素特征进行分析,研究出露在青藏高原东北缘甘肃礼县境内的白河碱性玄武岩的地球化学特征及其地质意义。研究后可知,白河玄武岩具有低Si O2(38.94%~40.57%),极高Ti O2(4.66%~4.97%),高的K2O(1.46%~2.02%)和Na2O(2.08%~3.23%)含量,以及高Mg#(0.74~0.76)值等特征,具有富集地幔初始岩浆的性质,为典型的幔源钠质碱性玄武岩。微量和稀土元素具板内火山岩特征:Th,Rb,Sr,REE等大离子亲石元素和Ta,Nb,Ti,HREE等高场强元素明显富集,NMORB标准化图解中没有Nb的负异常,轻/重稀土元素强烈分异,(Sm/Yb)N=10.53~11.20。初始87Sr/86Sr(0.703 948~0.704 294)略高于现代大洋MORB(0.702 29~0.703 34),143Nd/144Nd(0.512 782~0.512 847)则低于现代大洋MORB(0.512 99~0.513 3),具有亏损的εNd(t)值(+3.1~+4.3),指示具有亏损地幔的信息;初始206Pb/204Pb(19.016 729~19.076 653),207Pb/204Pb(15.619 237~15.623 632)和208Pb/204Pb(38.488 124~39.593 763)比值均高于现代大洋亏损地幔的组分,指示富集地幔的信息。研究后认为,白河碱性玄武质岩浆来源于多元混合地幔源区。     

冀北多本沟盆地流纹岩年代学、地球化学特征及地质意义

多本沟盆地位于华北克拉通的北缘,盆地内的流纹岩SHRIMP锆石U-Pb年龄为(156.6±1.8)Ma(MSWD=1.45),属于晚侏罗世早期。流纹岩具有较高的SiO_2,K_2O,低Al_2O_3,CaO和MgO,强烈的负Eu异常,相对富集Rb,Th,U,Pb,Zr,Hf,相对亏损Ba,Sr,P,Ti等元素,具有A型流纹岩的特征;(~(87)Sr/~(86)Sr)_i=(0.706 749~0.714 887),ε_(Nd)(t)=(-11.23~-8.09),T_(DM2)=(1 855~1 601 Ma),(~(206)Pb/~(204)Pb)_t=16.53~16.93,(~(207)Pb/~(204)Pb)_t=15.31~15.39,(~(208)Pb/~(204)Pb)_t=36.96~37.31,δ~(18)O_(V-SMOW)=5.1‰~6.0‰。根据该盆地岩石组合与地质时代以及同位素组成特征,提出多本沟盆地火山岩系应归入新民组,认为华北北缘断裂可能从该盆地的北侧通过,结合已知铀矿的地质特征,认为盆地内的铀矿勘查工作应参照红山子铀钼矿床的模式开展。     

矩阵左半张量积的(T,S,2)-逆的反序律

给出了矩阵半张量积的(T,S,2) 逆的反序律成立的充要条件。并证明了等式(A⊙B)⁺_MP=(A⁺_MN(A⊙B))⁺_NP((A⊙B)(B⁺_NPIp))⁺_MN。     

PVC碳糊修饰电极测定Pb2+

 介绍了一种用PVC碳糊电极测定Pb²⁺的方法.该法在开路电路条件,富集介质为0.1 mol/L KNO₃(pH 11.0),检测底液为0.15 mol/L HNO₃.用微分脉冲阳极溶出伏安法扫描,有一灵敏Pb氧化峰出现,峰电位为-0.496 V(vs.Ag/AgCl),溶出峰电流与Pb²⁺在1.0×10-7～2~2.0×10^-5mol/L浓度范围内成很好的线性关系,线性相关系数为0.9960,检出限为5.0×10^-8mol/L.     

The Sr, Nd isotopic composition of lamprophyres in Laowangzhai gold orefield, Yunnan Province

Lamprophyres are widely spread over the Laowangzhai gold orefield in northern Mt. Ailao structure zone, Yunnan Province. Lamprophyres in the orefield are temporally and spatially related to gold mineralization. Lamprophyres in the orefield have anomalous Sr and Nd isotopic compositions, e.g. the 87Sr/ 86Sr ratios (0.706 665-0.707 960, the 87Sr/ 86Sr ratio of sample YLW-44 is 0.709 041) are higher than the modern value of the original mantle (0.704 5), the 143Nd/ 144Nd ratios (0.512 463-0.512 551) are lower than the modern value of the original mantle (0.512 638), and the calculated values ε Sr>0 (28.1-63.7) and ε Nd<0 (-1.34--3.07). The results of investigation indicate that lamprophyres in the Laowangzhai gold orefield with anomalous Sr and Nd isotopic compositions would not be produced as a result of contamination of the primary magma with the isotopic features of MORB by the crust materials high 87Sr/ 86Sr ratios and low 143Nd/ 144Nd ratios in the processes of rising or in the magma chamber, but the result of metasomatism of source mantle.     

Potash-rich volcanic rocks and lamprophyres in western Shandong Province: 40Ar39Ar dating and source tracing

Highly precise 40Ar39Ar dating results demonstrate that the ages of potash-rich volcanic rocks in western Shandong Province are 114.7-124.3 Ma, and that of the lamprophyres is 119.6 Ma. The potash-rich volcanic rocks have relatively high (87Sr/86Sr)i ratios ( 0.708715-0.711418)and distinctly negative εNd values ( -11.47 - -17.54), and are enriched in radiogenic lead (206Pb/204pb=17.341-17.622,207pb/204Pb=15.525-15.538, 208Pb/204pb = 37.563-37.684).Similarly, the lamprophyres also have quite low εNd values ( -11.57 - -19.64). Based on the fact that the Sr, Nd and Pb isotopic compositions of potash-rich volcanic rocks are very consistent with that of the clinopyroxene separates, and by integrating comprehensive analyses of their tectonic settings,and extensive comparisons of the Sr, Nd isotopic compositions with that of the related simultaneous rocks, it is concluded that the potash-rich volcanic rocks and lamprophyres in western Shandong Province were most possibly derived from the partial melting of enriched mantle which was caused by source contamination and metasomatism of subducted continental crustal materials.``     

山东焦家金矿田锶、铅同位素特征及其地质意义

焦家金矿田是胶西北地区重要的金矿产地，金矿类型以破碎带蚀变岩型为主，其成矿物质来源及成矿地质体尚存争议。采取了焦家金矿田深部样品，分析其同位素特征，研究成矿物质来源，探讨金矿成矿地质体。焦家金矿田金矿石黄铁矿⁸⁷Sr/⁸⁶Sr=0.711 653～0.732 45,按焦家金矿田平均成矿年龄120 Ma返算的(⁸⁷Sr/⁸⁶Sr)_i的值，其范围0.710 752～0.711 986,与郭家岭花岗岩较为接近。焦家金矿田金矿石黄铁矿²⁰⁸Pb/²⁰⁴Pb=37.683～38.103,²⁰⁷Pb/²⁰⁴Pb=15.43～15.547,²⁰⁶Pb/²⁰⁴Pb=17.04～17.44。焦家金矿田金矿体铅为地幔和下地壳的混合源。郭家岭型花岗岩与焦家金矿田金矿形成时间相近，分布空间相依，与金矿体同位素组成接近，成因上有密切联系，是金矿的成矿地质体。     

四川牦牛坪碳酸岩的同位素地球化学及其成矿动力学

世界上绝大多数与碱性岩浆岩 (包括碳酸岩 )有关的稀土矿床产于裂谷化环境中 ,但四川牦牛坪稀土矿床却形成于新生代造山过程中。牦牛坪是一个与碱性杂岩体密切有关的稀土矿床 ,矿化与岩浆碳酸岩直接有关。碳酸岩的同位素地球化学组成变化很小 ,2 0 6Pb/2 0 4Pb=1 8.1 6 2～ 1 8.1 94 ,2 0 7Pb/2 0 4Pb=1 5 .5 36～ 1 5 .5 6 7,2 0 8Pb/2 0 4Pb=38.2 83～ 38.390 ,87Sr/86Sr=0 .70 6 0 5～ 0 .70 6 91 ,1 4 3 Nd/1 4 4 Nd=0 .5 1 2 32 7～ 0 .5 1 2 4 36 ,与 EMI型地幔源区的同位素组成基本一致 ,表明牦牛坪稀土元素的成矿作用与深部动力学过程有关。在强烈的挤压造山过程中能够有 EMI型地幔物质上侵 ,表明进入新生代以来 ,龙门山造山带乃至整个青藏高原及周边地区的地球动力学背景不仅限于板块的水平挤压与俯冲 ,还应考虑到地幔物质及其活动过程的显著贡献。     

The return of subducted continental crust in Samoan lavas

Substantial quantities of terrigenous sediments are known to enter the mantle at subduction zones, but little is known about their fate in the mantle. Subducted sediment may be entrained in buoyantly upwelling plumes and returned to the Earth's surface at hotspots, but the proportion of recycled sediment in the mantle is small, and clear examples of recycled sediment in hotspot lavas are rare. Here we report remarkably enriched 87Sr/86Sr and 143Nd/144Nd isotope signatures in Samoan lavas from three dredge locations on the underwater flanks of Savai'i island, Western Samoa. The submarine Savai'i lavas represent the most extreme 87Sr/86Sr isotope compositions reported for ocean island basalts to date. The data are consistent with the presence of a recycled sediment component (with a composition similar to the upper continental crust) in the Samoan mantle. Trace-element data show affinities similar to those of the upper continental crust--including exceptionally low Ce/Pb and Nb/U ratios--that complement the enriched 87Sr/86Sr and 143Nd/144Nd isotope signatures. The geochemical evidence from these Samoan lavas significantly redefines the composition of the EM2 (enriched mantle 2; ref. 9) mantle endmember, and points to the presence of an ancient recycled upper continental crust component in the Samoan mantle plume.     

Potash-rich volcanic rocks and lamprophyres in western Shandong Province: 40Ar-39Ar dating and source tracing

Highly precise ⁴⁰Ar-³⁹Ar dating results demonstrate that the ages of potash-rich volcanic rocks in western Shandong Province are 114.7–124.3 Ma, and that of the lamprophyres is 119.6 Ma. The potash-rich volcanic rocks have relatively high (⁸⁷Sr÷⁸⁶Sr)_i ratios (0.708715–0.711418) and distinctly negative ε_nd values (−11.47–−17.54), and are enriched in radiogenic lead (²⁰⁶Pb÷²⁰⁴Pb=17.341−17.622, ²⁰⁷Pb÷²⁰⁴Pb=15.525−15.538, ²⁰⁸Pb÷²⁰⁴Pb = 37.563−37.684). Similarly, the lamprophyres also have quite low ε_nd values (−11.57–−19.64). Based on the fact that the Sr, Nd and Pb isotopic compositions of potash-rich volcanic rocks are very consistent with that of the clinopyroxene separates, and by integrating comprehensive analyses of their tectonic settings, and extensive comparisons of the Sr, Nd isotopic compositions with that of the related simultaneous rocks, it is concluded that the potash-rich volcanic rocks and lamprophyres in western Shandong Province were most possibly derived from the partial melting of enriched mantle which was caused by source contamination and metasomatism of subducted continental crustal materials.     

阿尔泰地区霍热木德克花岗岩体年代学、地球化学特征及构造意义

中阿尔泰构造带出露大面积晚三叠世花岗岩,对其进行详细研究是了解阿尔泰造山带构造演化和陆壳增生过程的重要途径。本文对霍热木德克岩体进行详细的岩石学、锆石U-Pb年代学、岩石地球化学及Sr-Nd同位素研究。霍热木德克花岗岩体主要有粗粒二长花岗岩、细粒二长花岗岩和正长花岗岩。LA-ICP-MS锆石U-Pb年代学研究结果表明,其结晶年龄为(222.3±1.8)Ma(MSWD=1.6),为晚三叠世岩浆活动产物。地球化学研究表明,岩石具有高SiO_2、Al_2O_3、ALK,低TiO_2、MnO、MgO、P_2O_5的特征,轻稀土富集、轻重稀土分馏明显,具有Eu的负异常(δEu=0.37~0.50),富集大离子亲石元素、相对亏损高场强元素,显示出强过铝质S型花岗岩的特征,花岗岩具有负的εNd(t)(-3.7~-2.7)和较老的二阶段模式(T2DM)年龄(1.2~1.3Ga)。综合分析认为,霍热木德克花岗岩由富含白云母和黑云母的变泥质岩经历部分熔融形成,其源区有富钙斜长石、钛铁矿的残留,为同碰撞造山阶段挤压环境下地壳加厚而发生部分熔融的产物,形成于同碰撞构造环境。     

Adakite-type sodium-rich rocks in Awulale Mountain of west Tianshan: Significance for the vertical growth of continental crust

The sodium-rich dacites and albite porphyries of Permian in the Awulale Mountain of west Tianshan have unique chemical and trace element signatures identical to adakite. These intermediate-acidic igneous rocks are characterized by high Na2O, Al₂O₃ and Sr contents and high Sr/Y and La/Y ratios (＞40 and ＞20, respectively), and low Y and Yb contents, and strong depletion in HREE, and positive Eu anomaly. The (^{143Nd/₁₄₄Nd)_i} is in the range from 0.51236 to 0.51248 and the e_Nd(t) is positive value (+0.79—+3.11); the (⁸⁷Sr/⁸⁶Sr)^_i is in the range from 0.7052 to 0.7054. These Nd and Sr isotopic composition features indicate that the source rocks of these adakite-type rocks are from a weakly depleted mantle, or a depleted mantle, but was contaminated by the crustal materials. These adakite-type rocks were most likely derived from the partial melting of new underplated basaltic rocks under the conditions of amphibolite to eclogite transition in the postcollisional environment of North Xinjiang during the Permian Period. They are not only the Phanerozoic juvenile crust materials, but also are probably animportant symbol of the underplating of mantle- derived basaltic magmas and the vertical growth of continental crust in the west Tianshan area during the postcollision of Late Paleozoic.     

Pb-Pb isotope dating of black shales from the Lower Cambrian Niutitang Formation, Guizhou Province, South China

Withthedevelopmentofnewanalyticaltech niquesandstate of artinstruments ,isotopetracinganddatingmethodshavemadeconsiderableprogressinrecentyears .Inparticular ,variouskindsofradio genicisotopedatingmethodshavebeenappliedsuc cessfullyinigneousrocks.However,directdatingofsedimentaryrocksremainsundevelopedandcontro versial.Inmostcases ,researchersapplyU PbandK ArorAr Armethodstodatingvolcanicashesthatareinterbeddedwithinsedimentarystratainanattempttoobtaintheageofsedimentsindirectly[1] .Howev e…     

Pb, Sr isotopes in organic matter of Lower Tertiary hydrocarbon source rocks in Liaohe Fault Depression

The Pb, Sr isotopic compositions in organic matters (kerogen and soluble organic matter) of Lower Tertiary hydrocarbon source rock in Liaohe Fault Depression is first reported. There is a great variable rang of Pb isotopic compositions in kerogen, 206Pb/204Pb = 17.488-18.656, 207Pb/204Pb= 15.388-15.692, 208Pb/204Pb = 37.656-37.484. And soluble organic matters have a very stable Pb isotopic composition, that is 206Pb/204Pb = 17.424-17.601, 207pb/204pb= 15.376-15.448, 208Pb/204Pb = 37.620-37.870. Sr isotopic composition varies in the range of 0.747 59-0.716 79 in kerogen and of 0.709 67-0.747 59 in soluble organic matters that have a great range. It is shown that mantle fluid can influence organic matters and make them form hydrothermal hydrocarbon in the geoglogic environment of rift basin.     

Late Mesozoic interaction between crust and mantle in coastal area of Zhejiang-Fujian

This paper summarizes the lithogeochemical features of composite lavas, dikes and plutons composed of early Cretaceous associated basic-acidic igneous rocks from the coastal area of Zhejiang-Fujian. On the basis of the studies on Nd, Sr, Pb isotopic signatures and geochemical characteristics of large ion lithophile elements (L1LE) , light rare earth elements (LREE) and high field strong elements ( HFSE) of these contemporary basic-acidic igneous rocks, it is considered that the source enrichment caused by the subduction of Pacific plate and contamination of crustal rocks and melts during ascending process may lead to the formation of basaltic magmas with a high LILE concentration. These late Mesozoic composite basic-acidic igneous rocks are the products of the interactions between crust and mantle in active continental margin.