新疆吐哈盆地南北缘石碳纪火山岩铂族元素配分及其指示意义

古俯冲带背景下的残余地幔岩的PGEs配分以Pd,Pt明显亏损和Ir,Ru相对富集为特征,而部分熔融产物的玄武岩和基性岩脉则呈现相反的Ir,Ru明显亏损和Pd,Pt相对富集特征。俯冲带中流体的参与一方面增加了部分融程度,有利于Pd,Pt从原始地幔进入熔融相;另一方面,流体的作用使得Pd,Pt相对于Ir,Ru迁移活动性效率提高,造成地幔岩中w(Pd)/w(Ir)和w(Pt)/w(Ir）比例很低。新疆吐鲁番－－哈密盆地南缘觉罗塔格和北缘博格达两个石炭纪火岩带中的玄武岩和基性岩带中的基性岩明显不同,据此可以认为两个岩浆带并不具备古板块俯冲带的构造背景。     

琼中古-中元古代变质基性火山岩地球化学特征

琼中斜长角闪(片麻)岩为变质的古-中元古代基性火山岩,属于高铝和低钛的高钾钙碱性玄武岩系.其LILE和LREE明显富集,HFSE相对亏损,具有典型岛弧玄武岩特征.微量元素、Sm-Nd同位素组成还揭示其岩浆源区偏离原始地幔,但未受成熟地壳物质的明显污染,是消减带上部地幔楔与俯冲洋壳析出的流体二元混合物部分熔融的产物.古-中元古宙时期,海南地块可能经历了由拉张到挤压的地球动力学转变,早期拉张阶段形成琼西洋脊型和过渡型拉斑玄武岩,中晚期强烈俯冲作用形成琼中岛弧高钾钙碱性玄武岩,该俯冲期与华南统一地块古-中元古宙板块俯冲时期相对应.     

北祁连直河蛇绿岩的地质和地球化学特征

直河蛇绿岩是在北祁连造山带中新发现的,该蛇绿岩由地幔橄榄岩、辉长辉绿岩、玄武岩、硅质岩等组成,以构造岩片为接触关系.蛇绿岩中岩石地球化学特征表明,该蛇绿岩具有大洋拉斑玄武岩的特征,同时具有某些岛弧特征,基性岩类的REE球粒陨石标准化配分模式为平坦型和LREE亏损型,超基性岩为亏损地幔源和富集地幔物质加入的混合成因,稀土分配型式不同于典型洋脊玄武岩,源区为亏损地幔和富集地幔的混合源.北祁连自寒武纪末大陆裂解,完成大陆裂陷向洋盆的转化,至奥陶纪形成沟弧盆体系.直河蛇绿岩属于弧后盆地扩张环境的产物.     

超镁铁岩中铂族元素的行为和规律

在总结前人工作的基础上,论述了PGE在超镁铁岩中的分布范围以及在部分熔融、结晶分异和蚀变作用过程中的行为规律。在部分熔融和结晶分异过程中,Ir组PGE(Os,Ir,Ru)表现为相容性,除寄存于硫化物外,还可寄存于难熔相中如橄榄岩,铬铁岩等;Pt组PGE(Rh,Pt,Pd)表现为不相容性,主要寄存于硫化物相中,且优先进入熔体中。在蚀变作用过程中,PGE的行为主要受其溶解度的控制。     

甘肃白银厂矿田早中寒武世酸性火山岩成因及源区特征的地球化学制约

从白银厂矿田早中寒武世酸性火山岩的地球化学研究入手，对其成因和源区特征进行了比较深入的探讨，认为本区酸性火山岩的源岩应是玄武岩和含水辉长质岩石的部分熔融形成的安山岩，源岩安山岩部分熔融形成该区流纹岩，而英安岩主要由流纹岩浆或与玄武岩浆混合或发生不明显的分离结晶形成．早-中寒武世，该区酸性火山岩的成岩环境为火山弧环境，当洋壳俯冲进入深处时，由于俯冲板片的脱水导致上地幔楔部分熔融形成源岩玄武岩，同时富水的流体萃取洋壳中的大离子亲石元素、轻稀土元素向上进入楔形地幔，使地幔橄榄岩富集大离子亲石元素．地幔中流体的增加导致下地壳中辉长质岩石的部分熔融形成了该区流纹岩的源岩--安山岩．熔融地幔底辟上升，由于高热流而引起下地壳局部熔融和混染，使该区酸性火山岩又具有陆壳混染的特征．     

山东东部中生代中基性火山岩的地球化学特征及成因探讨

本文对山东东部中生代中一基性火山岩的岩石化学、微量元素、稀土元素及铅同位素特征作了系统研究．该区中生代火山岩主要为玄武岩、粗面玄武岩、玄武质粗面安山岩、安山岩和粗面安山岩．玄武岩属钙碱性系列的拉斑玄武岩,微量元素特征显示大离子亲石元素和高场强元素均稍富集;稀土配分模式略呈右倾型,轻、重稀土之间的分馏不明显,基本无Eu异常;铅同位素组成显示玄武岩形成于原始地幔．粗面玄武岩和安山岩类属钙碱一弱碱性系列,微量元素特征显示大离子亲石元素富集,高场强元素含量低;稀土配分模式呈右倾型,轻、重稀土之间的分馏明显,基本无Eu异常;铅同位素组成显示粗面玄武岩形成于亏损地幔,安山岩类形成于富集地幔,具EMI属性．这些特征表明,山东东部中生代火山岩的岩浆来源于不同的源区．形成于早白垩世的安山岩类,产于活动大陆边缘拉张动力背景下,是由富集型地幔部分熔融形成的岩浆直接喷发形成;形成于晚白垩世的粗面玄武岩,也产于活动大陆边缘拉张动力背景下,随着弧后扩张引起拉伸作用,岩石圈伸展,从地幔来源的玄武质岩浆在上升过程中受到了陆壳物质的混染,之后沿着大断裂喷出地表形成本区显示亏损地幔来源特征的粗面玄武岩;形成于晚白垩世的玄武岩产于大陆板内拉张环境,是由原始地幔部分熔融而成的岩浆直接喷发形成．     

中祁连西段玄武玢岩地球化学特征及其构造意义

中祁连西段玄武玢岩呈浅层侵入于青白口系含磁铁矿的凝灰质板岩和早古生代蛇绿岩套中的玄武岩,后者辉长岩LA-ICP-MS锆石U-Pb年龄为471.6±3.7、469.3±2.8 Ma,结合蛇绿岩构造侵位时代及区域地质背景,推测玄武玢岩应形成于早古生代晚期.玄武玢岩w(SiO_2)=48.85%~53.22%,低Al,高Ti、TFe_2O_3,w(MgO)=4.80%~9.10%,w(Na_2O)/w(K_2O)3.8,为富钠贫钾,富集Nb、Ta、Th、U、LREE,亏损Rb、Ba、Sr、K、P,而Mg、Cr、Ni质量分数变化大.轻稀土略微富集,LREE/HREE为1.12~1.24,(w(La)/w(Yb))_N=2.19~2.87,轻微负Eu异常,δδEu=0.69~0.87.研究表明玄武玢岩兼有火山弧和板内岩浆作用的特征,应源于初始的埃达克岩熔体交代的地幔发生部分熔融形成的玄武岩浆,并经历了早期橄榄石的分离结晶作用,形成于北祁连古大洋向南俯冲闭合-碰撞之后的陆缘弧后裂谷环境.     

西藏班戈县蓬错地区富铌玄武岩地球化学特征及地质意义

系统的岩石化学与地球化学研究表明西藏蓬错地区存在富铌玄武岩。SiO_2含量为45.84%~55.88%,TiO_2含量为1.05%~3.25%,与加拿大Superior省太古代Wawa绿岩带的富铌玄武岩相当。Na_2O含量为0.92%~5.10%,P_2O_5含量为0.23%~1.19%,与新生代富铌玄武岩相同。稀土分布模式为无明显铕异常或弱负铕异常的右倾曲线,轻重稀土分馏较强烈。虽然铌含量很高,但Th与轻稀土元素的强烈富集,在微量元素蛛网图中铌依然显示亏损,高场强元素Ta、Ti也呈弱负异常。微量元素地球化学特征显示,蓬错富铌玄武岩形成于班公湖—怒江结合带中段的洋内弧,是adakite熔体交代的地幔楔橄榄岩部分熔融的产物,其源区处于石榴石—尖晶石稳定域,作用深度60~100 km。蓬错富铌玄武岩的发现和厘定,表明班公湖—怒江带中段在中—晚侏罗世经历了洋内俯冲消减过程,揭示了自北向南的洋内俯冲极性,也暗示了班公湖—怒江结合带多次俯冲改造的复杂性。     

房山岩体的岩浆来源、形成机制及动力学意义

房山岩体是华北东部典型的燕山期中酸性侵入杂岩体,其地球化学特征为富Si、Na、Al、Sr,亏损高场强元素(Nb、Ta),轻重稀土分异强烈,Sr-Nd同位素具有类似EMI型富集地幔的特点,表明其岩浆来自于加厚下地壳的部分熔融,并且中生代华北东部下地壳已经被早先的富集岩石圈地幔置换.不同基性程度岩浆的不完全混合是形成微粒闪长质包体的原因.侵入杂岩的角闪石压力计显示下地壳部分熔融形成的中酸性岩浆先后在19~8 km里的深度范围内结晶就位.古太平洋板块在地幔过渡带深度于早白垩世水平俯冲至太行山一线,洋壳脱水导致上覆地幔部分熔融,后者成为加热下地壳部分熔融的热源.     

贵州遵义下寒武统黑色岩系中贵金属的表生活动性初探

用ICP-MS方法测定了贵州遵义中南村黑色岩系中原生富"硫钼矿\\"矿石、受风化淋滤的富"硫钼矿\\"矿石和富黄铁矿矿石及矿区矿坑水、泉井水和河沟水样品的贵金属元素.测定了3种水样的原地水温、pH值、电导率和溶氧量.矿坑水为酸性水,具高电导率和低溶氧量.原生富黄铁矿矿石铂族元素总量仅占原生富"硫钼矿\\"矿石的1/13,Ag含量占1/2强,两者Au含量基本相当.原生富"硫钼矿\\"矿石受风化淋滤后,除Au外,其他贵金属元素均有较大程度的亏损,Rh,Pd,Pt,铂族元素总量和Ag的淋出率高达66.72%～74.79%,说明在表生条件下,铂族元素和Ag都有随表生水迁移的趋势;此外,其Ag/Au,Pd/Ru,Pt/Ir,(Pt+Pd)/(Ru+Rh+Ir)等4项参数都显著减小,说明Pt,Pd相对于Ru,Rh和Ir,Ag相对于Au有更强的活动性.中南村黑色岩系中的贵金属可能是在温度低于50℃、富含SO 42- ,pH值约为2.4的"冷水"作用下活化迁移的.     

Patterns of platinum-group elements in mantle peridotite, granulite xenoliths and basalt in Hannuoba

Neutron activation analysis after preconcentration of nickel sulfide fire assay was used in measurement of Ru, Ph, Pd, Os, Ir, Pt (i.e. PGE elements) and Au concentrations for basalt, mantle and granulite xenoliths in Hannuoba. The chondrite- and primitive mantle-normalized PGE patterns generally exhibit flat (for Iherzolite), negative slope (for harzburgite), and positive slope (for basic granulite and basalt). In addition, strong Ir negative anomaly occurs in basalt and granulite xenolith, and little negative anomaly also exists in Iherzolite xenolith in Hannuoba.     

Platinum-group elements for the mantle peridotites in the Dazhuka ophiolite, Tibet, China

The total PGE amounts of mantle peridotites in the Dazhuka ophiolite, Tibet, are 28.37—50.67 ng/g, slightly higher than those of mantle peridotites in the primitive mantle, and typical ophiolites in the world, and the Alps-type mantle peridotites. The PGE distribution patterns in the Dazhuka mantle peridotites are also different from those of the mantle peridotites of partial melting relict origin. The Dazhuka mantle peridotites have relatively high total PGE amounts and are enriched in Pt, Pd, and Ru. Their PGE distribution patterns belong to the positively inclined- or swallow-type patterns. The PGE distribution patterns in the mantle peridotites of partial melting relict origin belong to the negative-slope patterns or flat patterns. This reflects the unique features of the upper mantle in this region. Relative enrichment in Pt and Pd, as well as in the incompatible elements Cu, Au, Cs, Rb, Ba, Th, U and LREE, indicates that the partial melting-derived relict mantle peridotites in the Dazhuka ophiolite had experienced intensive permeating and mixing processes of the melt and fluid both containing abundant incompatible elements.     

Platinum-group element （PGE） geochemistry of the Emeishan basalts in the Pan-Xi area, SW China

Mantle plume represents massive mantle-derived magma activity and mainly causes the generation of the magma-associated deposits. The economically impor- tant magmatic deposits include Cu-Ni-PGE, V-Ti-Fe, and chromite deposits, e.g., the Bushveld giant PGE…     

Supergene mobility of noble metal elements in black rock series

In order to discuss the supergene mobility of noble metal elements in black rock series, measurements have been conducted with ICP-MS method for the contents of Ru, Rh, Pd, Ir, Pt, Au and Ag in the primary jordisite-rich black shale ore, in the supergene leached jordisite-rich black shale ore, in the pyrite-rich black shale ore and in the water of pit, well and stream of the mining area near Zhongnan Village, Zunyi District of Guizhou Province. The temperature, pH, electric conductivity, dissolved oxygen of the water were also measured. The pit water is acidic with high electrical conductivity and low dissolved oxygen. The total content of platinum group elements in the primary pyrite-rich black shale ore is only 1/13 of that in the primary jordisite-rich black shale ore. The Ag content in the former is only a half of that in the latter while the Au contents in the two kinds of ores are almost the same. Being leached under supergene condition, the contents of most of the noble metal elements except Au in the jordisite-rich black shale ore greatly decrease; the leaching rates of Rh, Pd, Pt, the total platinum group elements and Ag reach as high as 66.72%～74.79%, revealing that under supergene condition, platinum group elements and Ag can migrate along with water; the ratios of Ag/Au, Pd/Ru, Pt/Ir and(Pt+Pd)/(Ru+Rh+Ir) are remarkably decreased, displaying that Pt and Pd relative to Ru, Rh and Ir, Ag relative to Au bear more active mobility. The noble metal elements in the black rock series near Zhongnan Village might be mobilized and migrate under the procession of "cold water" rich in [SO4]2- with pH value being about 2.4 at a temperature below 50 ℃.     

ICP—AES在贵金属取代的钨杂多化合物元素分析中的应用

用电感耦合等离子体原子发射光谱法（ＩＣＰ－ＡＥＳ）测定贵金属取代的钨杂多化合物中的Ｓｉ，Ｐ，Ｗ，Ｒｕ，Ｉｒ，Ｐｄ，Ｐｔ７种元素，获得了满意的结果，方法满足杂多化合物元素组分分析的要求。     

Re-Os isotopic evidence for long-lived heterogeneity and equilibration processes in the Earth's upper mantle

The geochemical composition of the Earth's upper mantle is thought to reflect 4.5 billion years of melt extraction, as well as the recycling of crustal materials. The fractionation of rhenium and osmium during partial melting in the upper mantle makes the Re-Os isotopic system well suited for tracing the extraction of melt and recycling of the resulting mid-ocean-ridge basalt. Here we report osmium isotope compositions of more than 700 osmium-rich platinum-group element alloys derived from the upper mantle. The osmium isotopic data form a wide, essentially gaussian distribution, demonstrating that, with respect to Re-Os isotope systematics, the upper mantle is extremely heterogeneous. As depleted and enriched domains can apparently remain unequilibrated on a timescale of billions of years, effective equilibration seems to require high degrees of partial melting, such as occur under mid-ocean ridges or in back-arc settings, where percolating melts enhance the mobility of both osmium and rhenium. We infer that the gaussian shape of the osmium isotope distribution is the signature of a random mixing process between depleted and enriched domains, resulting from a 'plum pudding' distribution in the upper mantle, rather than from individual melt depletion events.     

Mantle metasomatism by P- and F-rich melt/fluids: evidence from phosphate glass in spinel lherzolite xenolith in Keluo, Heilongjiang Province

Spinel lherzolite xenoliths were found in phonolitic alkaline basalt in the Keluo area, Heilongjiang Province. Detailed electron-microprobe study revealed abundant phosphates and associated metasomatic minerals between primary phases in xenolith. The phosphates are considered special residual phases (coagulation) of P- and F-rich mantle melt/fluid, most of which were identified as glass phases based on Raman spectroscopic analyses. Such melt/fluid also further metasomatized primary minerals, thus leading to formation of reaction rims successively composed of Cr-spinel symplectitic zone and olivine diopside zone. Therefore, the P- and F-rich melt/fluid played an important role in the upper-mantle metasomatism in the Keluo area. It is suggested that this kind of metasomstism may occur in some other places of eastern China. The present results may also have significance in study-ing types of metasomatic melt/fluid and its evolution in the lithospheric mantle beneath eastern China.     

Mantle metasomatism by P- and F-rich melt/fluids： evidence from phosphate glass in spinel Iherzolite xenolith in Keluo, Heilonsjiang Province

Spinel Iherzolite xenoliths were found in phonoliUc alkaline basalt in the Keluo area, Heilongjiang Province. Detailed electron-microprobe study revealed abundant phosphates and associated metasomatic minerals between primary phases in xenolith. The phosphates are considered special residual phases （coagulation） of P- and F-rich mantle melt/fluid, most of which were identified as glass phases based on Raman spectroscopic analyses. Such melt/fluid also further metasomatized primary minerals, thus leading to formation of reaction rims successively composed of Cr-spinel symplecUUc zone and olivine ＋ diopside zone. Therefore, the P- and F-rich melt/fluid played an important role in the upper-mantle metasomatism in the Keluo area. It is suggested that this kind of metasomstism may occur in some other places of eastern China. The present results may also have significance in studying types of metasomatic melt/fluid and its evolution in the lithospheric mantle beneath eastern China.     

Simultaneous Removal of Soot and NOx over Precious Metal Catalysts O2-Rich Atmospheres and in the Presence of H2O and SO2

The activities of ZrO_2-supported precious metal catalysts for simultaneous removal of soot and NO_x in the presence of rich O_2and H_2O as well as SO_2 have been studied by keeping loose contact between catalyst and soot.The results show that only Ru,Ir and Rh have catalytic activity for simultaneous removal of soot and NO_x and the order of catalytic activity is Ru Ir Rh.Pt has the catalytic activity only for the removal of soot,and Ag,Pd,and Au have hardly any catalytic activities for the removal of soot and NO_x.The relationships between catalytic activity of precious metal catalysts and various reaction conditions were discussed.