He and Ar isotopes in mantle megacryst minerals from Nushan and Yingfengling in Southeast China

He and Ar isotopic compositions of megacrystal minerals from mantle xenoliths were measured by the technique of vacuum crushing extraction. The used samples were clinopyroxene, garnet and ilmenite in Cenozoic alkaline basalts, which were from Nushan in Anhui Province and Ying-fengling in Guangdong Province, respectively, and represented materials from the upper mantle in the continental margin of SE China. The results show ^3He/^4He ratios of 7.99 Ra to 8.58 Ra, consistent with the characteristic ratios of the MORB-type mantle. ^40Ar／^39Ar ratios vary from 313 to 909, suggesting a binary mixing between the MORB-type mantle and air argons. This may reflect the incorporation of the air argon absorbed in oceanic sediments into the mantle beneath the continental margin by subduction of oceanic plate. This study presents the first report that ilmenite megacrysts contain abundant fluid inclusions and noble gases in the mantle xenoliths.     

Old EMI-type enriched mantle under the middle North China Craton as indicated by Sr and Nd isotopes of mantle xenoliths from Yangyuan, Hebei Province

Recent studies indicate that the Mesozoic litho- spheric thinning in North China was diachronous with that in west to the Taihangshan gravity lineament being later than in the eastern part of the North China Cra- ton[1―3]. During the Cenozoic, lithospher…     

Fluid/melt inclusions in Cenozoic mantle xenoliths from Linqu,Shandong Province,eastern China: Implications for asthenosphere-lithosphere interactions

Fluid and melt inclusions in mantle xenoliths are thought as direct samples to study mantle liquids. Here we apply Raman mi- crospectroscopy and microthermometry to fluid/melt inclusions in lherzolite xenoliths in Qiaoshan basalts, a Miocene volcano in Linqu, Shandong Province, eastern China. These inclusions include (1) early CO2 fluid inclusions, (2) early carbonate melt inclu-sions, (3) late CO2 fluid inclusions, and (4) late silicate melt inclusions. Among the early CO2 fluid inclusions, most consist of...     

Mineralogy of the mid-ocean-ridge basalt source from neodymium isotopic composition of abyssal peridotites

Inferring the melting process at mid-ocean ridges, and the physical conditions under which melting takes place, usually relies on the assumption of compositional similarity between all mid-ocean-ridge basalt sources. Models of mantle melting therefore tend to be restricted to those that consider the presence of only one lithology in the mantle, peridotite. Evidence from xenoliths and peridotite massifs show that after peridotite, pyroxenite and eclogite are the most abundant rock types in the mantle. But at mid-ocean ridges, where most of the melting takes place, and in ophiolites, pyroxenite is rarely found. Here we present neodymium isotopic compositions of abyssal peridotites to investigate whether peridotite can indeed be the sole source for mid-ocean-ridge basalts. By comparing the isotopic compositions of basalts and peridotites at two segments of the southwest Indian ridge, we show that a component other than peridotite is required to explain the low end of the (143)Nd/(144)Nd variations of the basalts. This component is likely to have a lower melting temperature than peridotite, such as pyroxenite or eclogite, which could explain why it is not observed at mid-ocean ridges.     

Elastic wave velocity in rocks from Dabieshan and its constraints for lithospheric composition and crust-mantle recycling

P-and S-wave velocities in eclogites and granulites from the Dabie ultrahigh pressures (UHP) meta morphic belt, China, were measured at room temperature under the hydrostatic pressures up to 1.0 GPa. The ultrahigh pressure eclogites had the highest densities (3.3 ～ 3.6 g.cm-3) , high velocities and the lowest anisotropy (1.4%c ～ 2.6 % ) . The lowest densities (2.8 ～ 3.1 g. cm-3 ) and the highest Poisson' s ratios (0.28 ～ 0.29) were found in gran ulites, whereas the strongest anisotropies (6. 1 % ～8.4% ) were found in the high-pressure (HP) eclogites. Compari son of the velocities in rocks with that observed in the deep seismic sounding profile crossing Dabieshan suggests that e clogites might exist in the lower crust of Dabieshan, but the quantity might be small. The upper mantle has very similar velocities as the UHP eclogites and serpentinizated/water-bearing dunite. The formation of eclogite represents the crust mantle recycling processes. Crustal material is delaminated and sinks into the mantle by way of eclogite, whereas only a small part of the eclogite could return to the crust.     

Oxygen isotope compositions of eclogites in Rongcheng,Eastern China

Collected from the Rongcheng region,Shandong Province,the three types of eclogites suffering the UHP (i.e.ultra-high pressure )metamorphism have obviously different oxygen isotope compositions.The eclogites occurring in regional orthogneisses and ultramafic rocks have the oxygen isotope compositions of normal eclogites in the world,but the eclogites existing in marbles are extremely enriched in ^18 O.By applying oxygen isotope geothermometry ,for the all types of exlogites,the temperature estimates of quartz-garnet pair,in principle,indicate the formation temperatures of eclogites,so that the peak-metamorphic temperatures are estimated to be averagely little higher than 800℃ ,which are consistent with the estimates by using other geothermometers according to cation partitioning between coesisting phases ,The δ^18O values of eclogitic inclusions hosted in marbles from Yangguantun,Rongcheng region ,are far higher than the values of eclogites (including eclogitic inclusions in marbles ) from the Dabieshan and other places of the Sulu,The oxygen isotope compositions of various minerals indicate that the formation temperatures of eclogites from the Rongcheng region ,in genceral ,are higher than that from the Dabieshan and the southwestern part of the Sulu ,but the dispersive temperatures estimated by different mineral pairs probably refect that the UHP eclogites from the Rongcheng region generally suffered overprinted metamorphisms during the exhumation.     

Growth of early continental crust controlled by melting of amphibolite in subduction zones

It is thought that the first continental crust formed by melting of either eclogite or amphibolite, either at subduction zones or on the underside of thick oceanic crust. However, the observed compositions of early crustal rocks and experimental studies have been unable to distinguish between these possibilities. Here we show a clear contrast in trace-element ratios of melts derived from amphibolites and those from eclogites. Partial melting of low-magnesium amphibolite can explain the low niobium/tantalum and high zirconium/samarium ratios in melts, as required for the early continental crust, whereas the melting of eclogite cannot. This indicates that the earliest continental crust formed by melting of amphibolites in subduction-zone environments and not by the melting of eclogite or magnesium-rich amphibolites in the lower part of thick oceanic crust. Moreover, the low niobium/tantalum ratio seen in subduction-zone igneous rocks of all ages is evidence that the melting of rutile-eclogite has never been a volumetrically important process.     

Contrasting origins of the upper mantle revealed by hafnium and lead isotopes from the Southeast Indian Ridge

The origin of the isotopic signature of Indian mid-ocean ridge basalts has remained enigmatic, because the geochemical composition of these basalts is consistent either with pollution from recycled, ancient altered oceanic crust and sediments, or with ancient continental crust or lithosphere. The radiogenic isotopic signature may therefore be the result of contamination of the upper mantle by plumes containing recycled altered ancient oceanic crust and sediments, detachment and dispersal of continental material into the shallow mantle during rifting and breakup of Gondwana, or contamination of the upper mantle by ancient subduction processes. The identification of a process operating on a scale large enough to affect major portions of the Indian mid-ocean ridge basalt source region has been a long-standing problem. Here we present hafnium and lead isotope data from across the Indian-Pacific mantle boundary at the Australian-Antarctic discordance region of the Southeast Indian Ridge, which demonstrate that the Pacific and Indian upper mantle basalt source domains were each affected by different mechanisms. We infer that the Indian upper-mantle isotope signature in this region is affected mainly by lower continental crust entrained during Gondwana rifting, whereas the isotope signature of the Pacific upper mantle is influenced predominantly by ocean floor subduction-related processes.     

Trace element characteristics in the diopsides of peridotite xenoliths: a laser ablation-inductively coupled plasma-mass spectrometry study

Among the various xenoliths entrained by the Cenozoic Hannuoba basalts, peridotite is the most abundant one. The trace elements of the diopsides from the peridotite xenoliths were analysed by LA-ICP-MS. The overall depletion and some heterogeneity of the continental mantle beneath northern North China Craton were indicated by the characteristics of the trace elements. The ∑REE amount in diopside correlates with the Cr/(Cr+Al) ratio of diopside which is indicative of xenolith's partial melting degree. As the peridotite hosts and pyroxenite veins show similar REE distribution patterns, the composite xenoliths are probably formed by mantle deformation, rather than by the late metasomatism of mantle fluids/melts.     

Re-visiting barium isotope compositions of mid-ocean ridge basalts and the implications

Barium (Ba) isotopes can be used as potential tracers for crustal material recycling in the mantle. Determination of the Ba isotope composition of the depleted mantle is essential for such applications. However, Ba isotope data for mantle-derived basalts are still rare. In this study, we reported high-precision Ba isotope data of 30 oceanic basalts including 25 mid-ocean ridge basalts (MORBs) from geochemically and geologically diverse mid-ocean ridge segments and five back-arc basin basalts. The δ138/134Ba values of these samples varied from ?0.06‰ to +0.11‰, with no systematic cross-region variation. Together with published data, we constrained the average δ138/134Ba of global MORBs to +0.05‰±0.09‰ (2 standard deviation, n = 51). Based on depleted MORBs that have (La/Sm)_N < 0.8, low 87Sr/86Sr (< 0.70263), and low Ba/Th < 71.3, we estimated the average δ138/134Ba of the depleted MORB mantle (DMM) as + 0.05‰ ± 0.05‰ (2SD, n = 16) that is significantly lower than the DMM (≈ 0.14‰) reported previously. If a new estimation of the DMM is applied, it is unreasonable to infer that the Ba isotope signatures of the “enriched-type” MORBs (E-MORBs) could be attributed to pervasive sediment recycling in the upper mantle. We, therefore, conclude that the Ba isotope compositions of the E-MORBs could be sourced from the incorporation of subducted altered oceanic crust and/or sediments depending on the Ba isotope composition and other geochemical information of the local mantle.     

A metasomatized mantle wedge origin for low-δ 18O olivine in late Cretaceous Junan and Qingdao basalts in the Sulu orogen

The North China Block (NCB) experienced extensive lithospheric thinning and subsequent mantle accretion in the Mesozoic to Cenozoic, but their mechanism remains controversial. This paper reports in situ chemical and oxygen isotope analyses on olivine xenocrysts and porphyroclastic olivines in mantle xenoliths hosted in the late Cretaceous basalts from Junan and Qingdao, the Sulu orogen. The results show that all these olivines have low δ ¹⁸O values relative to normal mantle peridotite. The olivine xenocrysts and porphyroclastic olivines from Junan have Fo=87.5–89.8, δ ¹⁸O=4.1‰–5.2‰ with an average of 4.8‰; the porphyroclastic olivines from Qingdao also have Fo=89.0–89.9, δ ¹⁸O=4.1‰–5.2‰ with an average of 4.8‰. These peridotite xenoliths have petrological and geochemical affinities similar to newly accreted MORB-type mantle, we hence consider such low-δ ¹⁸O features in the olivines to inherit from a mantle wedge that was metasomatized by melts derived from the subducted oceanic crust, which had experienced high-temperature hydrothermal alteration to acquire the low-δ ¹⁸O signatures. Combined the existence of Cenozoic low-δ ¹⁸O basalts and garnet pyroxenite xenoliths (relicts of recycled oceanic crust) hosted in Cenozoic basalts in the NCB, the subducted oceanic crust likely played an important role in the lithospheric evolution of the NCB during the Mesozoic to Cenozoic.     

Thermodynamic evolution of lithosphere of the North China craton： Records from lower crust and upper mantle xenoliths from Hannuoba

Lithospheric thinning in East China attracts much attention of geologists. In many cases where a lithospheric thinning is inferred, the trigger for instability is a preced-ing episode of crustal thickening by the continental colli-sion[1]. Lithospheric processes (e.g. lithospheric thinning) could be recorded by the thermal history of the lower crustal and upper mantle xenoliths. Xu et al.[2] suggested that the cooling (from >1200 to 850℃) recorded by spinel harzburgite from Northeast China …     

Mantle xenoliths from Late Cretaceous basalt in eastern Shandong Province： New constraint on the timing of lithospheric thinning in eastern China

Studies of mantle xenoliths hosted in both the Cenozoic alkali basalt and the Early Paleozoic kimberlite suggest that part of the subcontinental lithosphere as thick as more than 100 km has been lost from the Early Paleozoic to Cenozoic[1—8]. Neither the scale and mechanism nor the accurate timing of the lithospheric thinning has been precisely constrained[7-12]. One of the reasons for this is that there are only a few Mesozoic basalts cropped out, especially, few containing mantle-derived …     

Mantle olivine xenocrysts entrained in Mesozoic basalts from the North China craton：Implication for replacement process of lithospheric mantle

Mesozoic (125 Ma) Fangcheng basalts fromShandong Province contain clearly zoned olivines that arerare in terrestrial samples and provide first evidence for thereplacement of lithospheric mantle from high-Mg peridotitesto Iow-Mg peridotites through peridotite-melt reaction.Zoned olivines have compositions in the core (Mg# = 87.2--90.7) similar to those olivines from the mantle peridotiticxenoliths entrained in Cenozoic basalts from the NorthChina craton and in the rim (Mg# = 76.8--83.9) close to oli-vine phenocrysts of the host basalts (75.7--79.0). Thesecompositional features as well as rounded crystal shapes andsmaller grain sizes (300—800 μm) demonstrate that thesezoned olivines are mantle xenocrysts, i.e. disaggregates ofmantle peridotites. Their core compositions can representthose of olivines of mantle peridotites. The zoned texture ofolivines was formed through rapid reaction between the oli-vine xenocryst and the host basalt. This olivine-basaltic meltreaction could have been ubiquitous in the Mesozoic litho-spheric mantle beneath the North China craton, i.e. an im-portant type of the replacement of lithospheric mantle. Thereaction resulted in the transformation of the Paleozoic re-fractory (high-Mg) peridotites to the late Mesozoic fertile(Iow-Mg) and radiogenic isotope-enriched peridotites, lead-ing to the loss of old lithospheric mantle.     

Recycling lower continental crust in the North China craton

Foundering of mafic lower continental crust into underlying convecting mantle has been proposed as one means to explain the unusually evolved chemical composition of Earth's continental crust, yet direct evidence of this process has been scarce. Here we report that Late Jurassic high-magnesium andesites, dacites and adakites (siliceous lavas with high strontium and low heavy-rare-earth element and yttrium contents) from the North China craton have chemical and petrographic features consistent with their origin as partial melts of eclogite that subsequently interacted with mantle peridotite. Similar features observed in adakites and some Archaean sodium-rich granitoids of the tonalite-trondhjemite-granodiorite series have been interpreted to result from interaction of slab melts with the mantle wedge. Unlike their arc-related counterparts, however, the Chinese magmas carry inherited Archaean zircons and have neodymium and strontium isotopic compositions overlapping those of eclogite xenoliths derived from the lower crust of the North China craton. Such features cannot be produced by crustal assimilation of slab melts, given the high Mg#, nickel and chromium contents of the lavas. We infer that the Chinese lavas derive from ancient mafic lower crust that foundered into the convecting mantle and subsequently melted and interacted with peridotite. We suggest that lower crustal foundering occurred within the North China craton during the Late Jurassic, and thus provides constraints on the timing of lithosphere removal beneath the North China craton.     

Trace-element of Tuoyun clinopyroxene: Implication for the deep processes of lithospheric mantle beneath the southwest Tianshan, West China

Based on the LAM-ICPMS analytic results on the trace elements of clinopyroxenes in peridotitic xenoliths occurring in early-Cretaceous basalts from western Xinjiang, the properties and the deep processes, including partial melting and mantle metasomatism, of the subcontinental lithospheric mantle beneath the Tuoyun Basin are analyzed. In the northern edge of the Tarim Basin (southwest Tianshan), the Mesozoic subcontinental lithosphere which has experienced the effect of partial melting (<10%) and intricate mantle metasomatism is characterized by Phanerozoic ‘ocean-type’ mantle. The superposed influence of SiO₂-unsaturated silicate melt and carbonate melt probably results in the metasomatic medium which resembles the hydrous silicated carbonate melt in some aspects. By comparing Tuoyun mantle with Cenozoic main mantle beneath eastern China, the properties are similar, while the former shows finer grain and higher diopside content of the peridotites and more conspicuous modal metasomatism.     

Geochemical characteristics and petrogenesis of Mesozoic basalts from the North China Craton： A case study in Fuxin, Liaoning Province

Occurrence of Cretaceous basalts in Fuxin County, Liaoning Province provides us an opportunity to understand Mesozoic mantle processes beneath the northern margin of the North China Craton (NNCC). Fuxin Jianguo basalts occur as volcanic channel phases with well-developed columnar jointings and contain few spinel lherzolite and pyroxenite xenoliths. They are poor in silica and rich in alkalis, Ti and Al, belonging to alkaline basalts. In trace element compositions, Jianguo basalts are moderately enriched in LREE and LILE, but not depleted in HFSE. They have low Sr and high Nd and Pb isotopic ratios. These geochemical characteristics suggest that Jianguo basalts originated from the depleted asthenosphere, representing an undifferentiated and uncontaminated primitive magma. Presence of these basalts indicates that the lithosphere beneath the region had thickness less than 65 km at the time of basalt eruption and was mainly composed of fertile pargasite-bearing spinel Iherzolite and plagioclase pyroxenite. The voluminous basaltic-andesitic magmatism during the early Jurassic-late Cretaceous time indicates that the commencement and accomplishment of lithosphere thinning in the NNCC was much earlier than that in the southern margin, since the mafic-intermediate volcanism only occurred at the Cretaceous time in the southern margin and the basalts with an asthenosphere isotopic signature at the Tertiary. This shows that highly spatial and temporal heterogeneity existed in the Mesozoic lithosphere evolution.     

The importance of water to oceanic mantle melting regimes

The formation of basaltic crust at mid-ocean ridges and ocean islands provides a window into the compositional and thermal state of the Earth's upper mantle. But the interpretation of geochemical and crustal-thickness data in terms of magma source parameters depends on our understanding of the melting, melt-extraction and differentiation processes that intervene between the magma source and the crust. Much of the quantitative theory developed to model these processes has neglected the role of water in the mantle and in magma, despite the observed presence of water in ocean-floor basalts. Here we extend two quantitative models of ridge melting, mixing and fractionation to show that the addition of water can cause an increase in total melt production and crustal thickness while causing a decrease in mean extent of melting. This may help to resolve several enigmatic observations in the major- and trace-element chemistry of both normal and hotspot-affected ridge basalts.     

蓬莱与宽甸新生代碱性玄武岩及其深源包体和巨晶矿物的稀土元素

本文应用现代仪器分析方法——质谱同位素稀释法测定了辽宁宽甸和山东蓬莱碱性玄武岩及其深源超镁铁岩包体和巨晶矿物中的稀土元素REE,测定结果用Nakamura数值进行了球粒陨石标准化计算。根据所得REE丰度和分布模式特征,推测了两地区的尖晶石二辉橄榄岩属残渣型地幔岩包体,榴辉岩属原始型地幔岩包体。两地区的镁铝榴石巨晶可能是早期液相线上的产物,后期的变质作用对整个REE没有明显的影响。富铝普通辉石巨晶则是比镁铝榴石较晚期的结晶产物。两地区的碱性玄武岩及其超镁陕岩包体和巨晶矿物在REE丰度和分布模式上十分相似,表明了两地区所处的大地地质构造以及熔融和分异作用的物理化学条件的相似性。     

Boron and oxygen isotope evidence for recycling of subducted components over the past 2.5 Gyr

Evidence for the deep recycling of surficial materials through the Earth's mantle and their antiquity has long been sought to understand the role of subducting plates and plumes in mantle convection. Radiogenic isotope evidence for such recycling remains equivocal because the age and location of parent-daughter fractionation are not known. Conversely, while stable isotopes can provide irrefutable evidence for low-temperature fractionation, their range in most unaltered oceanic basalts is limited and the age of any variation is unconstrained. Here we show that delta(18)O ratios in basalts from the Azores are often lower than in pristine mantle. This, combined with increased Nb/B ratios and a large range in delta(11)B ratios, provides compelling evidence for the recycling of materials that had undergone fractionation near the Earth's surface. Moreover, delta(11)B is negatively correlated with (187)Os/(188)Os ratios, which extend to subchondritic values, constraining the age of the high Nb/B, (11)B-enriched endmember to be more than 2.5 billion years (Gyr) old. We infer this component to be melt- and fluid-depleted lithospheric mantle from a subducted oceanic plate, whereas other Azores basalts contain a contribution from approximately 3-Gyr-old melt-enriched basalt. We conclude that both components are most probably derived from an Archaean oceanic plate that was subducted, arguably into the deep mantle, where it was stored until thermal buoyancy caused it to rise beneath the Azores islands approximately 3 Gyr later.