Mineralogical evidence for continental deep subduction

Diamond is an index mineral to prove ultrahigh pressure (UHP) metamorphic conditions because it is only stable at the pressures above 3.3 GPa. Its occurrence in eclogite-facies metamorphic rocks suggests plate subduction to depths over 120 km assuming the normal gradient of lithostatic pressure. Because UHP eclogites are the metamorphic products of basaltic rocks, the occurrence of diamond in the eclogites demonstrates a complete geodynamic cycle in that mafic crustal rocks were subducted t…     

Call in question and discussion: Are there sandwiched low-grade metamorphic slabs within UHP metamorphic rocks in the Dabieshan terrane

Some geologists reported their discovery of sandwiched low-grade metamorphic slabs within UHP metamorphic Complexes in Changpu, Yuexi County, Anhui Province. They also suggested that some coesite-bearing eclogites are igneous veins, which intruded low-grade metamorphic slabs and other related rocks. Moreover they further called in question to UHP metamorphic process and continental collision tectonism in the Dabieshan terrane. Based on our recent study, so-called low-grade metamorphic slabs are strongly deformed fabric, fine-grained and tectonic recrystallized mylonites and tectonites. Their protolith rocks are garnet-bearing orthogneiss, eclogite and marble, as well as a few amounts of strongly deformed acid and basic veins. Their metamorphic, geochemical and geochronological characteristics are also identical with UHPM rocks and regional country orthogneisses. Therefore we conclude that there are not low-grade metamorphic slabs sand wiched with UHP metamorphic rocks in the Dabieshan terrane.     

Heterogeneity of water in UHP eclogites from Bixiling in Dabieshan： Evidence fromgarnet

Garnets in ultrahigh pressure (UHP) eclogites from Bixiling in Dabieshan were investigated by Fourier transform infrared spectrometer (FTIR). The results demonstrate that all garnets contain structural water which occurs as hydroxyl (OH), with contents ranging from 164 to 2034 ppm (H2O wt.) and mostly higher than 500 ppm. Like omphacite which is another major OH-rich mineral in eclogites, garnet is an important carrier that can recycle the surface water into deep mantles. Heterogeneity of water in garnets exists not only among different samples of the same outcrop (～150 m), but also among different crystals of the same sample (～1 cm). This indicates that the mobility of fluids during UHP metamorphism is very limited (possibly on centimeter scales), and that both subduction and exhumation processes of UHP rocks are very fast.     

Evidence for UHP metamorphism of eclogites from the Altun Mountains

Ultrahigh pressure (UHP) metamorphism refers to metamorphism that has occurred at pressures for the stability of coesite. The polycrystalline quartz inclusions showing the characteristic texture within garnets of eclogites indicates the pre-existence of coesites under the peak metamorphic condition. The unusual exsolution textures in ompacites and apatites, and the pressure estimations of phengite-bearing eciogites have been taken to provide further proof of eclogite formation under the UHP conditions.Combined with the fact that coesites have been observed in country rocks of eclogites in North Qaidam Mountains, another UHP metamorphic belt cut by the large-scale strikeslip fault in the AItun-North Qaidam area of China is confirmed.``     

Breakdown of lawsonite subsequent to peak UHP metamorphism in the Dabie terrane and its implication for fluid activity

Abundant occurrences of quartz vein within eclogites in the Dabie-Sulu orogen provide us an opportunity to study metamorphic fluid flow during subduction and exhumation of continental crust. It is, however, usually short of petrological constraints on pressure and temperature of vein formation. This study focuses on kyanite-quartz veins within Iow-T/high-P eclogite in the Dabie terrane that contain unique polycrystalline aggregates, interpreted as pseudomorphs after porphyroblasts of lawsonite. Coesite pseudomorphs were found for the first time in garnet from eclogite, resulting in a revised estimate of peak P-T conditions at 670℃ and 3.3 GPa for the eclogite. This indicates a stability field at graphite/diamond transition, thus upgrading the HP unit to a UHP unit. Neither foliation texture, undulose extinction of quartz nor coesite were observed in quartz veins,although the peak P-T conditions were estimated the same as that in host eclogite in light of thermodynamic calculation based on mineral assemblage in kyanite-quartz veins.Therefore, the formation of the kyanite-quartz veins as wellas the breakdown of lawsonlte into the kyanite-quartz-zoisite assemblage took place during exhumation subsequent to the peak UHP conditions. In this regard, the continental subduction not only brought the water of water-bearing mineral such as lawsonite into the deep mantle, but also released the water from the mineral during exhumation.     

Water contents and hydrogen isotopes in nominally anhydrous minerals from UHP metamorphic rocks in the Dabie-Sulu orogenic belt

A continuous flow method, by a combination of thermal conversion elemental analyzer （TC/EA） with isotope ratio mass spec- trometry （MS）, was developed to determine both H isotope composition and H2O concentration of ultrahigh-pressure （UHP） metamorphic rocks in the Dabie-Sulu orogenic belt. By using the developed step-heating technique, we have studied H2O concen- tration and H isotope composition of the different forms of water （structural OH and molecular H2O） in garnet. The quantitative measurements of HzO concentration and H isotope composition of minerals in UHP metamorphic rocks from several typical out- crops indicate that the gneisses can release more amounts of water than the eclogites during exhumation of the deeply subducted continental crust. Therefore, by decompression dehydration at the contact between eclogite and gneiss, the released water could flow from the gneiss to the eclogite and result in significant hydration of the eclogite adjacent to the gneiss. The measured maxi- mum water contents of minerals in eclogites indicate that garnet and omphacite have the maximum water solubilities of 2500 and 3500 ppm, respectively, under the peak UHP metamorphic conditions.     

Oxygen isotope compositions of eclogites in Rongcheng,Eastern China

Collected from the Rongcheng region,Shandong Province,the three types of eclogites suffering the UHP (i.e.ultra-high pressure )metamorphism have obviously different oxygen isotope compositions.The eclogites occurring in regional orthogneisses and ultramafic rocks have the oxygen isotope compositions of normal eclogites in the world,but the eclogites existing in marbles are extremely enriched in ^18 O.By applying oxygen isotope geothermometry ,for the all types of exlogites,the temperature estimates of quartz-garnet pair,in principle,indicate the formation temperatures of eclogites,so that the peak-metamorphic temperatures are estimated to be averagely little higher than 800℃ ,which are consistent with the estimates by using other geothermometers according to cation partitioning between coesisting phases ,The δ^18O values of eclogitic inclusions hosted in marbles from Yangguantun,Rongcheng region ,are far higher than the values of eclogites (including eclogitic inclusions in marbles ) from the Dabieshan and other places of the Sulu,The oxygen isotope compositions of various minerals indicate that the formation temperatures of eclogites from the Rongcheng region ,in genceral ,are higher than that from the Dabieshan and the southwestern part of the Sulu ,but the dispersive temperatures estimated by different mineral pairs probably refect that the UHP eclogites from the Rongcheng region generally suffered overprinted metamorphisms during the exhumation.     

The Dabie-Sulu UHP rocks belt: review and prospect

The new results in the studies of the Dabie-Sulu UHP rocks belt during the past 5 years were summarized and discussed. The discussion included the following key points: ( i ) UHP eclogite has two kinds of country rocks, with one being UHP eclogite facies rocks and the other non-UHP granitic gneiss. ( ii ) The FeTiO₃ in olivine indicated exsolution at depth of 300–400 km. However, the key point is to prove the peridotite in which the FeTlO₃ in olivine was found once had been subducted down that depth. ( iii ) UHP hydrous phase evidenced that fluids had taken part in the UHP metamorphism, while the meter-scale inhomogeneous distribution of O-, C-isotope indicated no fluid activity in the deep subduction environment. ( IV ) No agreement has been arrived on many problems related to the tectonic background of the UHP rocks, such as “whether or not ophiolitic rocks there exist now?”, “when did UHP metamorphism proceed?”, “what is the subdution polarity?”, etc. ( V ) How did the UHP rocks exhume from mantle depth? The future studies will focus on the following three subjects: ( i ) thermal dynamics of the UHP metamorphism, ( ii ) relationship between UHP metamorphism and collision orogeny, as well as their geodynamics, and ( iii ) interactions between crust and mantle, and between continental lithosphere and asthenosphere during the collision orogenic process, as well as their constraints to the evolution of continental lithosphere.     

Partial melting of deeply subducted continental crust and the formation of quartzofeldspathic polyphase inclusions in the Sulu UHP eclogites

Two types of quartzofeldspathic inclusions hosted by omphacite and garnet were identified in the Sulu UHP eclogites. The first consists of albite, quartz, and various amounts of K-feldspar. In contrast, the second consists predominantly of K-feldspar and quartz without any albite. The presence of quartzofeldspathic inclusions within the UHP mafic eclogites indicates that partial melting occurred in deeply subducted continental crust via mica dehydration melting reactions at an early stage of rapid exhumation. Such a melting event generated hydrous Na-K-Al-Si melts. These melts infiltrated into the mafic eclogite and were captured by recrystallizing garnet or omphacite, which together followed by dehydration and crystallization to form feldspar-bearing polyphase inclusions. Formation of silicate melts within the deeply subducted continental slab not only provides an excellent medium to transport both mobile （LILE） and immobile （HFSE） elements over a large distance, but also induces effective changes in the physical properties of the UHP slab. This process could be a major factor that enhances rapid exhumation of a deeply subducted continental slab.     

A huge oceanic-type UHP metamorphic belt in southwestern Tianshan, China: Peak metamorphic age and P-T path

Recent progress in the study of the UHP metamorphic belt in southwestern Tianshan, China, is summarized in this paper. This about 80-kin-long and over 10-km-wide UHP belt has been recognized by the discovery of coesite, coesite pseudomorphs and other UHP minerals. It is the largest oceanic-type UHP metamorphic belt reported so far. It has formed due to northward subduc- tion of the Tianshan Paleo-Ocean. U-Pb dating of metamorphic rims of zircons from a coesite-bearing garnet-phengite schist yields a peak UHP metamorphic ages of 320±3.7 Ma. Combined with ages of 233-226 Ma obtained from rims of zircons from retrograded eclogites, a long retrograde metamorphic evolution （〉70 Ma） has been revealed. According to phase equilibria mod- eling, the P-T paths of both coesite-bearing eclogites and garnet-phengite schists are characterized by thermal relaxation, i.e., the metamorphic temperature peak lags behind the pressure peak, indicating that the UHP rocks experienced slow and long heating and decompression during exhumation in the subduction channel. On the basis of the field observation that a small amount of eclogite lenses is wrapped in large volumes of metapelites, and the similar P-T paths of both rock types, we propose that the ex- humation of the UHP eclogites from southwestern Tianshan, China, may have resulted from the exhumation of large volumes of low-density metapelites, which carried the denser eclogites to the Earth＇s surface.     

Extreme crustal oxygen isotope signatures preserved in coesite in diamond

The anomalously high and low oxygen isotope values observed in eclogite xenoliths from the upper mantle beneath cratons have been interpreted as indicating that the parent rock of the eclogites experienced alteration on the ancient sea floor. Recognition of this genetic lineage has provided the foundation for a model of the evolution of the continents whereby imbricated slabs of oceanic lithosphere underpin and promote stabilization of early cratons. Early crustal growth is thought to have been enhanced by the addition of slab-derived magmas, leaving an eclogite residuum in the upper mantle beneath the cratons. But the oxygen isotope anomalies observed in eclogite xenoliths are small relative to those in altered ocean-floor basalt and intermediate-stage subduction-zone eclogites, and this has hindered acceptance of the hypothesis that the eclogite xenoliths represent subducted and metamorphosed ocean-floor basalts. We present here the oxygen isotope composition of eclogitic mineral inclusions, analysed in situ in diamonds using an ion microprobe/secondary ion mass spectrometer. The oxygen isotope values of coesite (a polymorph of SiO2) inclusions are substantially higher than previously reported for xenoliths from the subcratonic mantle, but are typical of subduction-zone meta-basalts, and accordingly provide strong support for the link between altered ocean-floor basalts and mantle eclogite xenoliths.     

Coesite in eclogite from the North Qaidam Mountains and its implications

Coesite provides direct evidence for ultrahigh pressure metamorphism. Although coesite has been found as inclusions in zircon in paragneiss of the north Qaidam Mountains, it has never been identified in eclogite. In this contribution, based on petrographic observations and in situ Raman microprobe spectroscopy, coesite was identified as inclusions in garnet of eclogite from the Aercituoshan, Dulan UHP metamorphic unit, north Qaidam Mountains. Coesite is partly replaced by quartz, showing a pali-sade texture. This is the first report on coesite in eclogite from the north Qaidam Mountains, and is also supported by garnet-omphacite-phengite geothermobarometry (2.7―3.25 GPa, 670―730℃). Coesite and its pseudomorphs have not been found in eclogites and associated rocks of other units of the north Qaidam Mountains. Further studies are required to confirm if all metamorphic units in the north Qaidam Mountains underwent the ultrahigh-pressure metamorphism.     

Whole-rock Ar-Ar dating for low-grade metavolcanics within the Dabie orogen and its geological significance

Greenschist-facies metasedimentary and metaigne- ous rocks are frequently found to occur continuously along convergent plate margins where high pressure (HP) or ultrahigh pressure (UHP) metamorphic rocks also crop out[1-7]. Geological investigations of co…     

Growth of early continental crust controlled by melting of amphibolite in subduction zones

It is thought that the first continental crust formed by melting of either eclogite or amphibolite, either at subduction zones or on the underside of thick oceanic crust. However, the observed compositions of early crustal rocks and experimental studies have been unable to distinguish between these possibilities. Here we show a clear contrast in trace-element ratios of melts derived from amphibolites and those from eclogites. Partial melting of low-magnesium amphibolite can explain the low niobium/tantalum and high zirconium/samarium ratios in melts, as required for the early continental crust, whereas the melting of eclogite cannot. This indicates that the earliest continental crust formed by melting of amphibolites in subduction-zone environments and not by the melting of eclogite or magnesium-rich amphibolites in the lower part of thick oceanic crust. Moreover, the low niobium/tantalum ratio seen in subduction-zone igneous rocks of all ages is evidence that the melting of rutile-eclogite has never been a volumetrically important process.     

Isotope composition of helium in eclogite from the Dabie Mountains, central China and its geological significance

Isotopic geochemical characteristics of helium in garnet and omphacite of eclogite in the Dabie Mountains are discussed. Concentrations of 3He and 4He in garnet and omphacite are 3.9×10 -14- 24.0×10 -14 and 0.48×10 -7-9.42×10 -7cm+3·g -1, respectively. Values of 3He/ 4He have a range of (1.19-4.63)×10 -7. Helium in the eclogite is derived from both mantle and crust. Isotopic geochemical data of helium indicate that eclogite in the Dabie Mountains might be formed in depleted mantle and the age of the cologite would be Indo-China epoch.     

Some new ideas about the deep subduction of continental crust

The discovery of coesite in metasedimentary rocks not only implies that the materials of continental crust with low density could subduct down to mantle depth, but also initiates a series of studies on continent-deep-sub-duction. Could continental crust be subducted down to the depth of more than 300 km? Water played a role in ultra-high-pressure (UHP) metamorphism although limited. Was the fluid really limited within meter-scale, as the authors suggested, at mantle depth? Erosion and extension could remove the overburden of the UHP rocks, while squeezing and buoyancy could lift up the UHP rocks through the overburden. What, however, is the main process and mechanism with which the UHP rocks have exhumed from mantle depth? All progress of these studies will eventually form and complete a new paradigm of geodynamics.     

Metamorphic solid salt (KCl-NaCl) in quartzo-feldspathic polyphase inclusions in the Sulu ultrahigh-pressure eclogite

Unusual polyphase inclusions of K-feldspar+quartz+titanite+solid salt and K-feldspar+albite+quartz+epidote with textures similar to the other K-feldspar+quartz inclusions were found in omphacite grains from the Sulu ultrahigh pressure (UHP) eclogites. One of these inclusions contain square to round solid salt inclusions of KCl-NaCl composition. Such a mineral assemblage within K-feldspar-bearing inclusions hosted by UHP metamorphic phases suggests that (1) potassium granitic melts enriched in Cl components were presented during UHP metamorphism or at the early stage of rapid exhumation of deeply subducted continental slab; (2) they were resulted from reactions between the incoming granitic melts and quartz (or coesite); and (3) solid salt inclusions of NaCl-KCl were derived from dehydration and desiccation of Cl-bearing melts. Our new observations further demonstrate that during the tectonic evolution of UHP rocks, fertile components within deeply subducted continental materials could undergo partial melting, leading to the formation of Cl-bearing potassium granitic melts and substantial migration of fluid-conservative elements (e.g. Ti, Hf) within the UHP slab.     

Discovery of Late Paleozoic retrograded eclogites from the middle part of the northern margin of North China Craton

The northern margin of the North China Craton (NCC), located between the Paleo-Asian Ocean tectonic region on the north and the NCC on the south, is a key region for studying the tectonic evolution of NCC. A Pre-cambrian retrograded eclogite (2500 Ma or 1800 Ma) was reported in Baimashi near Hengshan Mountain in the NCC, which is characterized by the vermicular symplec-tite of diopside and plagioclase with absence of ompha-cite[1,2]. In Hongqiyingzi Group from the middle part of the …     

SHRIMP U-Pb zircon ages for the UHP metamorphosed granitoid gneiss in Altyn Tagh and their geological significance

Different types of UHP metamorphic rocks havebeen recently discovered in the Altyn Tagh[1—4], the north-ern margin of Qadam Basin[5—7], the southwestern Tian-shan Mountains[8,9] and the northern Qinling Moun-tains[10,11] in Central and Western China. And these areashave attracted focus attention of geologists at home andabroad to the studying of UHP metamorphism and conti-nental deep subduction. However, as newly discoveredUHP metamorphic terranes, some questions have beenarisen abou…     

New finding of micro-diamonds in eclogites from Dabie-Sulu region in central-eastern China

Micro-diamonds were only found ten years ago in eclogite associated with marble at Xindian in the Dabie Mountains. This paper reports our new finding of micro-diamonds not only in eclogites at Maobei in the Sulu region and at Xindian and Laoyoufang in the south part of the Dabie Mountains (South Dabie), but also in eclogites at Baizhangya and Huangweihe in the northern part of the Dabie Mountains (North Dabie) that has usually been considered not to experience ultrahigh pressure metamorphism.Except the micro-diamond at Huangweihe that was found from the artificial heavy sands of zircons used for isotopic dating, the micro-diamonds from other localities were identified in thin sections of the eclogites. Besides a few interstitial grains, most of the micro-diamond grains in thin sections occur as inclusion in garnet. Three crystals of microdiamond at Maobei in the Sulu region are sized in 120, 60 and 30 lira, respectively. Crystal forms look like octahedron and the composite of octahedron and hexahedron. The largest micro-diamond crystal comes from Xindian, which is measured to be 180 lira in diameter with distinct zonal structure and inclusions. The zonal structure occurs as an inclined octahedron inside rounded by an incomplete hexagonal girdle. A smaller micro-diamond inclusion occurs inside the central octahedron, and a larger graphite inclusion is within the outer zone. The Laoyoufang micro-diamond is partially retrograded to graphite. Micro-diamond from the Baizhangya eclogite in the ultramafic rock belt of North Dabie is an aggregate of 70 lira X 90 lira in size. All the micro-diamonds are confirmed by the Raman spectrum analysis. The occurrence of the micro-diamonds from the eclogites in the ultramafic rock belt of North Dabie demonstrates that this region was also subjected to ultrahigh pressure metamorphism as well as the South Dabie did.