C-S-H表面上吸附态C1-离子的分布特点

应用表面物理化学理论,分析了C-S-H在不同浓度、不同种类氯化物溶液中浸泡后ζ电位发生变化的原因,并在此基础上推测了被吸附的C1-离子在C-S-H表面上的分布状态.C1-离子似乎是C-S-H的特性吸附离子,只要C-S-H浸泡于氯化物溶液中,C1-离子将优先进入吸附层.吸附于C-S-H表面的C1-离子的总量包括吸附层中的C1-离子量和扩散层中的C1-离子量.随浸泡液中C1-离子浓度的增大,C1-离子不断进入吸附层,但吸附层的空间是有限的,吸附层中C1-离子增加的速度逐渐减慢.扩散层的C1-离子量取决于ζ电位的大小.在较高浓度的AlCl3溶液中浸泡的C-S-H对C1-离子的吸附量显著增大,由于此时双电层已显著变薄,因而不能忽略C-S-H表面长程范氏力对C1-离子的吸引作用.     

具非线性耗散项的p-方程组的整体光滑解

研究具非线性耗散项的p-方程组的初值问题.在非线性耗散项较弱的假设条件下,解除了对初值的C1-模的小性限制.即对初值的C0-模不加小性限制,而需其一阶导数的C0-模足够小.运用经典的特征线法和极值原理,分别得到解的C0-模估计和偏导数的C0-模估计.根据光滑解的局部存在性定理和先验估计的结果,利用逐步延拓法,证明初值问题的整体光滑解的唯一存在性.     

富勒烯(C60/C70)与 N,N,N′,N′-四-(对甲基苯)-4,4′-二胺-1,1′-二苯碲醚电荷转移复合物的特征

用激光光解方法研究了富勒烯(C60 / C70)与N,N,N′,N′-四-(对甲基苯)-4,4′-二胺-1,1′-二苯碲醚电荷转移复合物的特征. 通过观察在近红外区瞬间吸收带,富勒烯(C60 / C70)激发三线态,富勒烯(C60 / C70)阴离子自由基和N,N,N′,N′-四-(对甲基苯)-4,4′-二胺-1,1′-二苯碲醚阳离子自由基的出现,测定了在苯腈溶液中从N,N,N′,N′-四-(对甲基苯)-4,4′-二胺-1,1′-二苯碲醚到富勒烯(C60 / C70)激发三线态的量子转化产率和电子转移常数.     

4-Formyl-2-（2H-benzotriazol-2-yl）-phenol： an ESIPT chromophore

In the present work, excited state intramolecular proton transfer （ESIPT） emission properties of a new benzotriazole derivative 4-formyl-2-（2H-benzotriazol-2-yl）- phenol （C1） were studied. 4-Formyl-2-（2H-benzotriazol-2- yl）-methoxy-benzene （C2）, 4-formyl-2-（2H-benzotriazol-2- yl）-phenyl acetate （C3） and 4-methyl-2-（2H-benzotriazol- 2-yl）-phenol （C4） were used as the reference molecules. ^1H NMR chemical shift of hydroxy group in C1 was located at more down field than that of C4 or p-hydroxy-benzaldehyde （C5）, respectively. C1 showed two absorption bands in the range of 260-400 nm zones in various solvents, while C2 and C3 exhibited single absorption band. The equal molar mixtures of C2/C5 or C3/C5 showed single absorption band. C2 and C3 displayed single fluorescence emission band in various solvents, while C1 exhibited dual emission bands in some strong polar solvents. Furthermore, the second emission band in these strong polar solvents showed the large Stokes shift. The results show that the second emission band of C1 was produced by ESIPT. C2 and C3 could not undergo ESIPT due to no hydroxy group. The geometry optimization calculation of enol and keto forms in the ground and excited states of C1 provided tough theoretical evidences of ESIPT.     

关于最长圈交Grotschel猜想的证明

讨论了最长路的交及性质.证明了Grotschel猜想:C\-1和C\-2是k-连通图G的两个最长圈,则|V(C\-1)∩V(C\-2)|≥k;且公共点V(C\-1)∩V(C\-2)形成G的一个顶点割.     

π-代数上的模及~DM_π~C与Rat(C~*M_D~π*)范畴

引进了π-代数上的模的概念,研究了其相关性质.证明了π-余代数上余模的对偶是对偶π-代数上的模.最后在MπC Rat(C*Mπ)的基础上,证明了DMπC Rat(C*MπD*).     

4-(1,1,3,3-四甲基)-丁基-2-羟基苯甲酸表面改性纳米TiO_2的研究

4-(1,1,3,3-四甲基)-丁基-2-羟基苯甲酸(C8SA)对纳米TiO2微粒进行了表面改性.通过高分辨透射电子显微镜(HRTEM)、傅立叶红外光谱仪(FT-IR)和热分析仪(TG-DTA)等技术手段对TiO2/C8SA进行了分析表征,结果证明C8SA成功修饰在纳米TiO2表面.采用四球摩擦磨损试验机考察了TiO2/C8SA作为润滑油添加剂在液体石蜡中的减摩抗磨行为,TiO2/C8SA纳米微粒对钢-钢摩擦副表现出较好的减摩抗磨作用.     

美洲大蠊提取物对3株人肺癌细胞的体外抑制作用

目的:观察美洲大蠊提取物(CⅡ-3)对3株人肺癌细胞的细胞毒作用,探讨CⅡ-3对人肺癌细胞的体外抗肿瘤活性.方法:采用MTT法观察CⅡ-3对3株人肺癌细胞的影响.结果:CⅡ-3对3株人肺癌细胞的生长均有一定的抑制作用,在最高浓度(300μg/ml)时抑制率几乎为100%,且存在一定的剂量依赖性和时间依赖性.结论:CⅡ-3对3株人肺癌细胞生长有抑制作用,值得进一步研究.     

关于无限C∞-字的性质

给出构造无限C∞-字在求导算子下所有周期点的方法.令Pn(D)={W∈Cω|Dn(W)=W},其中C∞表示所有无限Cω-字的集合,那么|Pn(D)|=2n.     

12C原子核α跃迁密度及p-12C非弹性散射研究

基于12C原子核的α粒子结构观点,通过拟合电子散射实验得出12C核2+和3-态α粒子跃迁密度分布,并在多重散射的K.M.T理论框架下对入射能量为600 MeV和700 MeV的p-12C非弹性散射进行研究计算.结果表明,理论计算得到的p-12C非弹性散射截面与实验数据符合得较好.12C原子核基态及2+和3-激发态的α粒子结构观点在p-12C非弹性散射领域得到了检验和支持.     

电子商务从C2C到C2B2C模式的博弈分析

在电子商务领域中,技术不是决定性因素,对交易模式的创新,也能收到良好的效益。针对C2C电子商务中的信用管理,本文提出了C2C电子商务中新的模式即C2B2C模式,从理论上推导出信用管理不完善最终会导致C2C电子商务逐渐萎缩,并促使C2B2C模式的出现。在这个模式下电子商务网站以大的买家和卖家的身份参与到交易中,同时从交易中获利。通过博弈分析可知,在该C2B2C模式下卖家会变的不再欺诈,而买家也变成信任的买家,这就从根本解决了电子商务现有信用管理的缺点。     

基于C2C电子商务的物流模式研究

C2C电子商务在中国初具规模,个人网拍业务在电子商务领域也已经是一种比较成功的商务模式,然而物流已成为制约C2C电子商务发展的瓶颈。本文从C2C电子商务如何选择物流模式的角度来研究电子商务物流,提出了C2C电子商务物流模式的构建方法。     

C2C电子商务发展及潜力

伴随着个人计算机与互联网络的迅猛发展,中国上网用户数量的快速增长和电子商务市场的不断拓宽,C2C电子商务对于大多数网民来说已不是件新鲜的事物,越来越多的人选择了这种坐在家里上上网点点鼠标就能买到自己心仪物品的方式。C2C电子商务模式主要是指网络服务提供商利用计算机和网络技术,提供有偿或无偿使用的电子商务平台和交易程序,允许交易双方(主要为个人用户)在其平台上独立开展以竞价、议价为主的在线交易模式。C2C模式已成为众多持有小资本的投资者的一种投资创业方式。而C2C作为电子商务中重要的应用模式之一,近几年来在我国得到了迅速的发展。而以淘宝、易趣为代表的C2C电子商务网站在2005年已实现了逾139.24亿元的交易额,这一数字是在2004年41.6亿交易额的基础上增长了2倍多,C2C市场发展之迅猛可见一斑。本文旨为对目前国内日趋成熟并快速成长的C2C电子商务的研究,通过分析比较C2C电子商务平台的特点、途径,探讨目前C2C电子商务中存在的问题,从而了解C2C电子商务经营方式,对该类型电子商务成功与失败因素的理解,有助于正确指导C2C平台的网上行为,寻求问题的解决方法与途径。     

Effects of zonal perturbations of sea surface temperature on tropical equilibrium states: A cloud-resolving modeling study

The effects of zonal perturbations of sea surface temperature (SST) on tropical equilibrium states are investigated based on a series of two-dimensional cloud-resolving simulations with imposed zero vertical velocity, constant zonal wind, and a zonal model domain of 768 km. Four experiments with zonal SST perturbations of wavenumbers 1 (C1), 2 (C2), 4 (C3), and 8 (C4) are compared to a control experiment with zonally uniform SST (C0). The 40-day integrations show that the temperatures reach quasi-equilibrium states with distinct differences. C1 and C2 produce warmer equilibrium states whereas C3 and C4 generate colder equilibrium states than C0 does. The heat budgets in the five experiments are analyzed. Compared to C0, less IR cooling over smaller clear-sky regions in C1 and more condensational heating in C2 are responsible for warmer equilibrium states. A reduced condensational heating leads to the cold equilibrium state in C3. The interaction between convective systems in C4 causes a decrease of condensational heating, which accounts for the cold equilibrium state.     

A 3D evaluation method of cutting surface topography of carbon/carbon （C/C） composite

<正> This paper aims to establish a 3D evaluation method for cutting surface topography of C/C composites.The cutting surface is measured by Talyscan 150,using 3D non-contact measurement.By evaluating2D and 3D roughness of C/C composite and Duralumin,the 2D evaluation method of the cutting surfacetopography of C/C composite loses a lot of information,and the characteristics of the surface topographyof C/C composite can be comprehensively and authentically evaluated only by the 3D evaluation method.Furthermore,3D amplitude and spatial parameters are adopted to evaluate the surface and the resultsshow that:the topography of the C/C composite is anisotropy and there are no obvious feeding texturesbut abrupt peaks and valleys on surface of the C/C composite,which indicates that the machining mechanismis different from that of the metal.In conclusion,The C/C composite surface is evaluated using a3D evaluation method,the roughness error is small,and the unique topography characteristics can be authenticallyevaluated.     

三分康托集与其两个平移交的维数(英文)

C为三分康托集,考虑何时交集C∩(C+t)∩(C+s)非空,计算出当交集非空时(t,s)的Hausdorff维数.证明了:对于平面上几乎处处的(t,s),dim_HC∩(C+t)∩(C+s)=0.利用Moran集的相关结论得到当交集非空时dim_H C∩(C+t)∩(C+s)的表达式.     

论B2C与C2C两种模式的融合和发展趋势

目前电子商务流行B2C和C2C两种模式。通过对当当网和淘宝网的分析,不难发现,B2C和C2C这两种模式各有优缺点,具有很强的互补性。从发展趋势来看,伴随而来的将是一种全新的电子商务运营模式,一个跨模式的全方位电子商务平台很快就会诞生;融合B2C和C2C,不仅可能,而且将是未来电子商务发展的必然趋势。     

银木和樟树遗传多样性与亲缘关系的RAPD分析

利用RAPD技术分析银木和樟树的遗传多样性与亲缘关系.用筛选出的12条引物从7株银木和7株樟树中共扩增得到91条DNA带,其中多态性条带48条,多态性条带比率为52.7%.根据Nei-Li方法进行的遗传相似性分析表明,银木植株间的遗传相似性系数在0.457～0.781,平均为0.564;樟树植株间的遗传相似性系数在0.646～0.862,平均为0.777;银木与樟树间的遗传相似性系数在0.318～0.531,平均为0.422.根据RAPD结果进行的聚类分析正确地将银木与樟树各聚为一类.这些数据说明银木植株间的遗传多样性大于樟树植株间的遗传多样性,银木与樟树之间的亲缘关系小于两种植物内部个体间的亲缘关系.     

Behavior of pure and modified carbon/carbon composites in atomic oxygen environment

Atomic oxygen (AO) is considered the most erosive particle to spacecraft materials in low earth orbit (LEO). Carbon fiber, carbon/carbon (C/C), and some modified C/C composites were exposed to a simulated AO environment to investigate their behaviors in LEO. Scanning electron microscopy (SEM), AO erosion rate calculation, and mechanical property testing were used to characterize the material properties. Results show that the carbon fiber and C/C specimens undergo significant degradation under the AO bombing. According to the effects of AO on C/C-SiC and CVD-SiC-coated C/C, a condensed CVD-SiC coat is a feasible approach to protect C/C composites from AO degradation.     

Simulation for the primary electronic donor of photosystem Ⅱ in vitro

Histidine coordinated to Chl a is a distinct characteristic of Chl a in vivo. By using histidine analogue of 1-methylimidazole (C4H6N2) and measuring the UV/vis absorption, CD and MCD spectra of the interaction between C4H6N2 and Chl a in CCl4, we have obtained that: (ⅰ) In pure CCl4 solvent, Chl a molecule is in five-coordinate state, and two Chl a molecules form an asymmetric compact-dimer with strong coupling interaction. We propose that the two Chl a molecules are connected by two unequally coordinated Mg-O bonds (the two oxygen atoms come from the C== O of C131 keto and C17 ester, respectively); (ⅱ) when the molar ratio of C4H6N2/Chl a is 0.5 or 1 (corresponding to 2Chl a·1C4H6N2 and 2Chl a·2C4H6N2, respectively), significant changes have been observed in the absorption, CD and MCD spectra, which indicate that the Chl a remains in dimer form, but the coupling interaction between them reduces greatly. We postulate that C4H6N2 replaces the ligation of C== O of C17 ester and C131 keto to Mg atoms sequentially. The two Chl a molecules linked by two weakly interacted Mg...O bonds form a relaxed-dimer. The structure of the model is essentially similar to that of the primary electronic donor, P680, of photosystem Ⅱ in high plants and algae.