烧结铁矿中FeO含量对其在富氢高炉中还原行为的影响

Japan started the national project “COURSE 50” for CO₂ reduction in the 2000s. This project aimed to establish novel technologies to reduce CO₂ emissions with partially utilization of hydrogen in blast furnace-based ironmaking by 30% by around 2030 and use it for practical applications by 2050. The idea is that instead of coke, hydrogen is used as the reducing agent, leading to lower fossil fuel consumption in the process. It has been reported that the reduction behavior of hematite, magnetite, calcium ferrite, and slag in the sinter is different, and it is also considerably influenced by the sinter morphology. This study aimed to investigate the reduction behavior of sinters in hydrogen enriched blast furnace with different mineral morphologies in CO–CO₂–H₂ mixed gas. As an experimental sample, two sinter samples with significantly different hematite and magnetite ratios were prepared to compare their reduction behaviors. The reduction of wustite to iron was carried out at 1000, 900, and 800°C in a CO–CO₂–H₂ atmosphere for the mineral morphology-controlled sinter, and the following findings were obtained. The reduction rate of smaller amount of FeO led to faster increase of the reduction rate curve at the initial stage of reduction. Macro-observations of reduced samples showed that the reaction proceeded from the outer periphery of the sample toward the inside, and a reaction interface was observed where reduced iron and wustite coexisted. Micro-observations revealed three layers, namely, wustite single phase in the center zone of the sample, iron single phase in the outer periphery zone of the sample, and iron oxide-derived wustite FeO and iron, or calcium ferrite-derived wustite 'FeO' and iron in the reaction interface zone. A two-interface unreacted core model was successfully applied for the kinetic analysis of the reduction reaction, and obtained temperature dependent expressions of the chemical reaction coefficients from each mineral phases.     

Mg和La对Ca–Ti 处理钢中夹杂物演变和组织的影响

The evolution of inclusions and the formation of acicular ferrite (AF) in Ca–Ti treated steel was systematically investigated after Mg and La addition. The inclusions in the molten steel were Ca–Al–O, Ca–Al–Mg–O, and La–Mg–Ca–Al–O after Ca, Mg, and La addition, respectively. The type of oxide inclusion in the final quenched samples was the same as that in the molten steel. However, unlike those in molten steel, the inclusions were Ca–Al–Ti–O + MnS, Ca–Mg–Al–Ti–O + MnS, and La–Ca–Mg–Al–Ti–O + MnS in Mg-free, Mg-containing, and La-containing samples, respectively. The inclusions distributed dispersedly in the La-containing sample. In addition, the average size of the inclusions in the La-containing sample was the smallest, while the number density of inclusions was the highest. The size of effective inclusions (nucleus of AF formation) was mainly in the range of 1–3 μm. In addition, the content of ferrite side plates (FSP) decreased, while the percentage of AF increased by 16.2% due to the increase in the number of effective inclusions in the La-containing sample in this study.     

摩擦焊接碳钢（EN24）和镍基高温合金（IN718）的显微组织和力学性能

Continuous-drive rotary friction welding was performed to join cylindrical specimens of carbon steel (EN24) and nickel-based superalloy (IN718), and the microstructures of three distinct weld zones—the weld interface (WI)/thermo-mechanically affected zone (TMAZ), the heat-affected zone (HAZ), and the base metal—were examined. The joint was observed to be free of defects but featured uneven flash formation. Electron backscatter diffraction (EBSD) analysis showed substantial changes in high-angle grain boundaries, low-angle grain boundaries, and twin boundaries in the TMAZ and HAZ. Moreover, significant refinement in grain size (2–5 μm) was observed at the WI/TMAZ with reference to the base metal. The possible causes of these are discussed. The microhardness profile across the welded joint shows variation in hardness. The changes in hardness are ascribed to grain refinement, phase transformation, and the dissolution of strengthening precipitates. The tensile test results reveal that a joint efficiency of 100% can be achieved using this method.     

汽车暴露面板带有表面条状缺陷的夹杂物分布特征分析:一种定量电解方法

The specific distribution characteristics of inclusions along with the sliver defect were analyzed in detail to explain the formation mechanism of the sliver defect on the automobile exposed panel surface. A quantitative electrolysis method was used to compare and evaluate the three-dimensional morphology, size, composition, quantity, and distribution of inclusions in the defect and non-defect zone of automobile exposed panel. The Al₂O₃ inclusions were observed to be aggregated or chain-like shape along with the sliver defect of about 3–10 μm. The aggregation sections of the Al₂O₃ inclusions are distributed discretely along the rolling direction, with a spacing of 3–7 mm, a length of 6–7 mm, and a width of about 3 mm. The inclusion area part is 0.04%–0.16% with an average value of 0.08%, the inclusion number density is 40 mm?2 and the inclusion average spacing is 25.13 μm. The inclusion spacing is approximately 40–160 μm, with an average value of 68.76 μm in chain-like inclusion parts. The average area fraction and number density of inclusions in the non-defect region were reduced to about 0.002% and 1–2 mm?2, respectively, with the inclusion spacing of 400 μm and the size of Al₂O₃ being 1–3 μm.     

在酸性溶液中加压氧化三价砷离子和二价铁离子

The co-oxidation of As(III) and Fe(II) in acidic solutions by pressured oxygen was studied under an oxygen pressure between 0.5 and 2.0 MPa at a temperature of 150°C. It was confirmed that without Fe(II) ions, As(III) ions in the solutions are virtually non-oxidizable by pressured oxygen even at a temperature as high as 200°C and an oxygen pressure up to 2.0 MPa. Fe(II) ions in the solutions did have a catalysis effect on the oxidation of As(III), possibly attributable to the production of such strong oxidants as hydroxyl free radicals (OH·) and Fe(IV) in the oxidation process of Fe(II). The effects of such factors as the initial molar ratio of Fe(II)/As(III), initial pH value of the solution, oxygen pressure, and the addition of radical scavengers on the oxidation efficiencies of As(III) and Fe(II) were studied. It was found that the oxidation of As(III) was limited in the co-oxidation process due to the accumulation of the As(III) oxidation product, As(V), in the solutions.     

活化天然矿石选择性还原二氧化碳为无定形碳

Natural magnetite formed by the isomorphism substitutions of transition metals, including Fe, Ti, Co, etc., was activated by mechanical grinding followed by H₂ reduction. The temperature-programmed reduction of hydrogen (H₂-TPR) and temperature-programmed surface reaction of carbon dioxide (CO₂-TPSR) were carried out to investigate the processes of oxygen loss and CO₂ reduction. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS). The results showed that the stability of spinel phases and oxygen-deficient degree significantly increased after natural magnetite was mechanically milled and reduced in H₂ atmosphere. Meanwhile, the activity and selectivity of CO₂ reduction into carbon were enhanced. The deposited carbon on the activated natural magnetite was confirmed as amorphous. The amount of carbon after CO₂ reduction at 300°C for 90 min over the activated natural magnetite was 2.87wt% higher than that over the natural magnetite.     

含钛高炉炉渣微波合成碳化钛及其介电性能测定

The preparation of functional material titanium carbide by the carbothermal reduction of Ti-bearing blast furnace slag with microwave heating is an effective method for valuable metals recovery; it can alleviate the environmental pressure caused by slag stocking. The dynamic dielectric parameters of Ti-bearing blast furnace slag/pulverized coal mixture under high-temperature heating are measured by the cylindrical resonant cavity perturbation method. Combining the transient dipole and large π bond delocalization polarization phenomena, the interaction mechanism of the microwave macroscopic non-thermal effect on the titanium carbide synthesis reaction was revealed. The material thickness range during microwave heating was optimized by the joint analysis of penetration depth and reflection loss, which is of great significance to the design of the microwave reactor for the carbothermal reduction of Ti-bearing blast furnace slag.     

采用超声组装与滚压工艺制备铝–碳纳米管复合材料

This study introduced a novel fabrication of aluminum–carbon nanotube (CNT) composites by employing bulk acoustic waves and accumulative roll bonding (ARB). In this method, CNT particles were aligned using ultrasonic standing wave in an aqueous media, and the arrayed particles were precipitated on the aluminum plate substrate. Then, the plates rolled on each other through the ARB process with four passes. Optical and scanning electron micrographs demonstrated the effective aligning of CNTs on the aluminum substrate with a negligible deviation of arrayed CNTs through the ARB process. The X-ray diffraction pattern of the developed composites showed no peaks for carbon and aluminum carbide. In addition, tensile tests showed that the longitudinal strength of the specimens processed with aligned CNTs was significantly greater than that of the specimens with common randomly dispersed particles. The proposed technique is beneficial for the fabrication of Al–CNT composites with directional mechanical strength.     

河南镇平祁子塘金矿金的存在状态研究

本文阐明了河南镇平县祁子塘金矿的物质组成、金的富集规律和存在状态、金矿物颗粒的形态和粒度特征,并介绍了适合于该矿石的金的存在状态考查方法。     

枞阳井边金矿金的赋存状态研究

井边金矿位于下扬子台坳、长江褶皱断裂隆起带中段。金矿体赋存于三叠系中统铜头尖组中 ,矿体形态呈不规则脉状。矿石类型主要有以含金褐铁矿为主的氧化矿石和以含金黄铁矿为主的原生矿石两大类。通过矿相鉴定 ,单矿物含金分析、物相分析、多点分析及电子探针分析等 ,查明了载金矿物系列特征的金的赋存状态。金矿物以自然金为主 ,其次为银金矿。金的粒度较细 ,主要为中细粒显微金。金的嵌布类型有包体金、晶隙金及裂隙金 ,金的成色较高 ,平均为 91 0 .4。金主要呈矿物态存在。     

小秦岭金钼共生矿床地质特征及成矿规律研究

小秦岭地区是中国典型的以金矿为主的矿产地,在该地区罗山金矿发现与金矿共生的石英脉型钼矿床,对罗山金钼矿矿床地质特征和成矿规律进行研究,并对该矿床的最新研究等方面进行归纳。     

贵州灰家堡金矿田成矿与蚀变元素迁移

选择贵州省灰家堡金矿田内最为典型的水银洞矿床和太平洞矿床,研究卡林型金矿床围岩蚀变过程中元素迁移规律与方式,探讨围岩蚀变与金矿化的内在联系。典型矿床围岩→矿化围岩→矿石的岩相学特征及与其对应的Grant质量平衡方程计算结果表明,卡林型金矿各成矿阶段所对应的围岩蚀变类型与通过计算所反映的元素迁移规律相一致;地球化学热力学计算结果显示,Au主要以AuHS0络合物的形式在成矿溶液中迁移。元素迁移研究的结果证明不同成矿阶段发生的围岩蚀变促进卡林型金矿主要成矿物质发生迁移,进而沉淀富集成矿。     

胶东一个新发现金矿床--辉寨金矿床成矿特征研究

研究了胶东地区新发现的辉寨金矿床,依据围岩蚀变分带特征,成矿热液组分、成矿温度、氢氧同位素、Rb-Sr等时线数据等,该矿床为产于黄铁绢英岩中的蚀变岩型金矿床,由此扩大了该区找金前景.     

圆盘粉碎机盘形与黄金矿制备样加工的探析

对四凸瓣磨盘圆盘粉碎机在制备黄金矿样中的运动、力学和粉碎机理进行了分析,得出四凸瓣磨盘圆盘粉碎机符合对黄金矿制备样的加工均匀性要求。其粉碎机理主要是以持续的摩擦剪切和间断层压粉碎对金矿制备样进行加工,为合理选择金矿制备样设备和对磨盘的改进设计提供了依据。     

山东焦家金矿田锶、铅同位素特征及其地质意义

焦家金矿田是胶西北地区重要的金矿产地,金矿类型以破碎带蚀变岩型为主,其成矿物质来源及成矿地质体尚存争议。采取了焦家金矿田深部样品,分析其同位素特征,研究成矿物质来源,探讨金矿成矿地质体。焦家金矿田金矿石黄铁矿⁸⁷Sr/⁸⁶Sr=0.711 653～0.732 45,按焦家金矿田平均成矿年龄120 Ma返算的(⁸⁷Sr/⁸⁶Sr)_i的值,其范围0.710 752～0.711 986,与郭家岭花岗岩较为接近。焦家金矿田金矿石黄铁矿²⁰⁸Pb/²⁰⁴Pb=37.683～38.103,²⁰⁷Pb/²⁰⁴Pb=15.43～15.547,²⁰⁶Pb/²⁰⁴Pb=17.04～17.44。焦家金矿田金矿体铅为地幔和下地壳的混合源。郭家岭型花岗岩与焦家金矿田金矿形成时间相近,分布空间相依,与金矿体同位素组成接近,成因上有密切联系,是金矿的成矿地质体。     

黄金坪金矿成因矿物学研究及其找矿评价

黄金坪金矿系典型碲—金建造。该文对主要组成矿物(包括碲金银系列矿物)的成因矿物学研究,通过系统分析典型矿物的结晶形貌、微量元素、晶胞参数、热电效应、显微硬度、反射率颜色指数、红外吸收、热发光性、稀土组成等标型特征,帮助确定矿床的成因类型并预测矿床的产出规模、矿石建造与矿石质量、深部远景及外围矿化带的评价诸方面。     

陕西省汉阴县北部金矿田地质特征

陕西省汉阴县北部志留系岩金矿田是陕西省矿产资源规划优选的贵金属矿产资源主要勘查评价区带。本次主要研究工作区以汉阴县北部铁佛-汉滨区流芳金矿带为主,通过已有资料的分析研究、野外调查、总结该金矿田的地质特征,为加快该岩金矿田评价提供支持。     

贵州天柱下达金矿矿床地质特征及成矿模式探讨

本文对下达金矿的矿床地质特征进行了总结，划分了成矿期、阶段及矿物生成顺序，测定了成金阶段部分样品矿物的微量元素含量及成矿温度，并阐明了构造对含金石英脉富矿的控制作用，根据地质事实，提出了成矿模式并指明进一步的找矿方向。