微波辐射降解水中高浓度有机物的H2O2综合反应体系研究

以1．0g苯酚溶于1000mL无酚水中作为高浓度的有机物模拟水样组成反应模型,在微波辐射下研究了H2O2综合反应体系H2O2／TiO2;H2O2／Fe^2＋;H2O2／活性炭;H2O2,Fe^2＋／活性炭对水中高浓度苯酚的降解作用,实验测量了H2O2在不同体系中的分解速率,并测量苯酚在这些体系中的分解速率和有机物耗氧量（CODCr）去除率,实验表明H2O2所在体系的分解速率和苯酚的分解速率依次为H2O2,Fe^2＋／活性炭〉H2O2／Fe^2＋〉H2O2／活性炭〉H2O2／TiO2,而体系H2O2／活性炭由于活性炭在微波辐射下有较强的氧化协同作用,该体系对有机物COD呈现出很高的去除率。     

一类特殊的算术级数存在性

已有结论表明:素数集中存在任意长的算术级数.且对任意正整数k,任何具有正密度的素数子集都含一k项算术级数.考虑4h 1型素数(h为正整数),显然可得结论:一定存在k项算术级数, 其中每项都能表成 m2 n2的形式(m,n为整数). 当k=4时,有无穷多组这种类型的4 项算术级数(n-1)2 (n-8)2,(n-7)2 (n 4)2,(n 7)2 (n-4)2,(n 1)2 (n 8)2.注意到82 12=72 42,为了回答:是否存在互异正整数a,b,c,d满足a2 b2=c2 d2,使得对任何正整数n,8个数(n a)2 (n b)2,(n a)2 (n-b)2,(n-a)2 (n b)2,(n-a)2 (n-b)2, (n c)2 (n d)2, (n c)2 (n-d)2, (n-c)2 (n d)2,(n-c)2 (n-d)2中总存在5项算术级数这一问题,本文采用组合方法,证明了不存在这样的正整数a,b,c,d.同时提出了3个猜想.     

飞秒激光场中1,2-二溴-1,1-二氯乙烷分子解离电离和解离双电离的理论研究

文章首先使用基于密度泛函理论的B3LYP方法,在6-31+G(d,p)水平上对1,2-二溴-1,1-二氯乙烷分子进行了结构特性研究,而后用从头算中的CIS方法研究了C2H2Br2Cl2+1和C2H2Br2Cl2+2的低激发态.研究结果表明,C2H2Br2Cl2+1在激发态解离的碎片为CBrCl2+1和CH2Br+1,C2H2Br2Cl2+2在激发态解离的碎片为C2H2BrCl2+1和Br+1.     

金属离子对鲍鱼碱性磷酸酶活力的影响

碱性磷酸酶(ALP,EC3.1.3.1)是一种金属酶,其结构的维持和酶活性的表现均需金属离子.本文研究了几种金属离子分别对鲍鱼ALP活力的影响.结果表明,Li ,Na 和K 等正一价碱金属离子对酶活力没有任何效应;碱土金属离子Mg2 ,Ca2 和Ba2 对酶有激活作用,其激活程度依次为:Mg2 >Ca2 >Ba2 ,而且Mg2 在5.0mmol/L时可以使酶活力提高267%;在过渡金属离子中,Zn2 ,Mn2 ,Co2 和Cu2 对酶的效应不同,Zn2 、Cu2 为抑制作用,而Co2 、Mn2 表现为激活作用;重金属离子Hg2 、Pb2 、Ag 和Cd2 对酶有抑制作用,其中Hg2 的抑制效应最强,1.0mmol/LHg2 可使酶活力抑制94%.研究Mn2 和Cu2 的抑制类型表明,Mn2 为混合型激活作用,而Cu2 对酶的抑制类型为非竞争性抑制作用,其抑制常数(KI)为0.316mmol/L.     

完全三部图的线图所生成的二元码

给出了三部图Kn1,n2,n3(n1n2n3)线图生成的二元码,当n1+n2+n3为奇数时,C为[n1n2+n2n3+n1n3,n1+n2+n3-1,n1+n2]2;当n1+n2+n3为偶数时,C为[n1n2+n2n3+n1n3,n1+n2+n3-2,2(n1+n2)]2,其中n3≥n2+2,或者C为[n1n2+n2n3+n1n3,n1+n2+n3-1,2n1+n2+n3-2]2,其中n3n2+2.     

四元体系MgCl2-MgSO4-CO(NH2)2-H2O在25 ℃时的等温溶度

测定了四元体系MgCl2-MgSO4-CO(NH2)2-H2O(不含硫酸盐脱水区)在25℃时的等温溶度及相应饱和溶液的密度值和折射率.绘制了该体系的溶度图和性质图.四元体系做出了8支共饱线,3个四元无变点.溶度图有6个单饱和区,分别对应CO(NH2)2,MgSO4*CO(NH2)2*2H2O,MgCl2*4CO(NH2)2*2H2O,MgCl2*CO(NH2)2*4H2O,MgCl2*6H2O和MgSO4*xH2O(x=4,5,6,7).     

新型高温超导候选材料Sr2CuO2Fe2As2的设计及物性研究

基于现有铜氧化物和铁基两类高温超导体的特性,设计了同时包含CuO2层和Fe2As2层的新材料Sr2CuO2Fe2As2,采用一性原理方法对其进行了稳定性分析,并计算了母体材料及掺杂后的电子能带结构.结果表明,该物质在能量上处于有利地位,具有良好的稳定性.其电子结构与铁基超导体较为相似,表现出弱金属性,其导电性主要集中在Fe2As2层.空穴掺杂时,CuO2和Fe2As2层层间关联得到削弱,材料的导电性仍由Fe2As2层主导;而在电子掺杂中,不仅Fe2As2层的导电性出现增强,CuO2层的导电能力也大幅度提高.结果表明,所设计的Sr2CuO2Fe2As2的电子结构与两类高温超导体具有相似性,可能成为超导候选母体材料,并具有实验研究和理论分析价值.     

Sr2Mn2CuAs2O2的第一性原理计算研究

基于第一性原理计算,研究了3种不同结构的同组分物质Sr2Mn2CuAs2O2的电子能带结构及物质总能量,并探讨了Sr2Mn2CuAs2O2可能的最稳定结构.结果表明,3种不同结构的Sr2Mn2CuAs2O2材料均表现出金属性,且主要是具有Mn原子的层状结构起导电作用.其中同时含有CuO2层面与Mn2As2四面体层,并具...     

纳米MnO2的制备与应用研究

采用KMnO4氧化还原和废旧电池回收2种方法合成出纳米MnO2粉体, 用显微图像仪和红外研究了MnO2粉体特性,结果显示2种方法合成的纳米MnO2平均粒径都在100～120 nm,有较好的分散性.对H2O2的分解的定量实验,发现2种方法合成的纳米MnO2对H2O2分解的催化活性均高于普通分析纯MnO2.     

ZrO2粒径对ZrO2/ZrW2O8复合材料性能的影响

分别采用Nano-ZrO2和Commercial-ZrO2制备ZrO2/ZrW2O8复合材料,并对所得复合材料的微观结构、烧结质量及其热膨胀性能进行了研究.结果表明,当ZrO2和ZrW2O8的质量比为2∶ 1时,ZrO2/ZrW2O8复合材料的热膨胀系数极低,接近于零.然而Commercial-ZrO2/ZrW2O8复合材料存在致密度不高,气孔率大的缺点.Nano-ZrO2的采用,可以降低基体的烧结温度,改善复合材料的烧结质量,Nano-ZrO2/ZrW2O8复合材料的相对密度达到94%,比Commercial-ZrO2/ZrW2O8的相对密度75%有明显提高.     

大功率LED恒流源调光电路设计

设计了一种以数字电位器x9312结合单片机的可调恒流电路,给出了系统组成,硬件电路设计,作品进行了测试,并将该设计主要方案用于2009年大学生电子设计竞赛设计制作,达到了要求。     

应用单片机控制的感应加热电源频率跟踪调功方式

本文主要对感应加热电源的调功方式进行了研究。由于感应加热过程中负载等效参数随温度而变化和加热工艺的需要,感应加热电源需要对负载进行功率调节。针对几种常用的功率调节方式进行比较的基础上,本文提出了一种应用单片机控制的频率跟踪调节方法。这一开发使用PWM控制器SG3525A和数字电位器X9312WP实现,控制电路简单可靠,整机效率高,大大降低能耗。     

A novel approach to design microwave medium of negative refractive index and simulation verification

In this paper, a novel approach is presented to synthesize microwave medium of negative refractive index by incorporating metallic wire array with negative effective permittivity into the host media such as ferrimagnet-YIG （yttrium iron garnet） applied by external magnetic field whose permeability is negarive. We have designed the composite medium having negative refractive index in C/X band frequencies, analyzed and simulated its electromagnetic （EM） properties by use of EM EDA package based on time-domain finite integration method. The simulation results show that： ① the effective permittivity of the designed metallic wire array is negative in the frequency range from 7.02 GHz to 9.80 GHz; ② the permeability of YIG substrate immersed into an external magnetic field is negative in the frequency range from 5.22 GHz to 8.14 GHz; ③ EM wave can pass through the composite medium synthesized by the above designed metallic wire array and YIG substrate, and ④ the negative refraction behavior occurs on the interface between the composite medium and the normal material with positive refractive index in 7.51-8.13 GHz frequency range, in which the effective permitUvity of the metallic wire array and the permeability of YIG substrate are negative simultaneously. The full wave simulation has demonstrated that the effective refractive index of the designed composite medium is indeed negative and ascertained that the proposed approach to design microwave medium with negative refractive index is viable.     

Research of technique for synthesizing carbonyl diethyl malonate

Diethyl malonate being an initial raw material,processed with chlorination-replacement-desalination-vacuum rectification,is used to produce carbonyl diethyl malonate.An experiment for optimization determines that the best reaction condition was:① reaction for 7 h at 10 ℃ with mole-ratio being 2.4︰1 between chloride and raw material(diethyl malonate);② reaction for 4.5 h at 118 ℃ with mole-ratio being 1.2︰1 between the anhydrous sodium acetate and intermediate Ⅰ.The final product carbonyl diethyl malonate recovery ratio reaches up to as high as 79.12% with a purity of 96.4%,which meets the market requirement.This synthesis technique has the advantages of simple process,moderate reaction conditions,high yield and low cost,being suitable for industrial scale production.     

An ontology reasoning architecture for data mining knowledge management

In order to realize the intelligent management of data mining （DM） domain knowledge, this paper presents an architecture for DM knowledge management based on ontology. Using ontology database, this architecture can realize intelligent knowledge retrieval and automatic accomplishment of DM tasks by means of ontology services. Its key features include：①Describing DM ontology and meta-data using ontology based on Web ontology language （OWL）.② Ontology reasoning function. Based on the existing concepts and relations, the hidden knowledge in ontology can be obtained using the reasoning engine. This paper mainly focuses on the construction of DM ontology and the reasoning of DM ontology based on OWL DL（s）.     

A new secure password authentication scheme using smart cards

Thirteen security requirements for an ideal password authentication scheme using smart cards are listed and a new smart card based password authentication scheme with identity anonymity is proposed. The new scheme can satisfy all the listed ideal security requirements and has the following merits： （1） it can resist all the attacks listed in introduction; （2） less storage memory requirement due to no verification table stored in server; （3） low computational cost due to hash functions based operations; （4） even if the smart card is lost, the new system is still secure; （5） As user identity is anonymous, this scheme is more practical. The new proposed scheme can be applied in source constraint networks.     

A geometric robust watermarking algorithm based on DWT-DCT and Zernike moments

This paper proposed a novel multibits watermarking algorithm providing robustness against geometric attacks. The robustness is achieved from three aspects： （1） Choosing the inscribed disk of the host image as the Zernike moments computation domain and the square in the disk as the watermarking embedding domain. （2） Embedding the watermark in the cascade discrete wavelet transform-discrete cosine transform （DWT-DCT） domain by modulating the specified coefficient pair in each sub block. （3） Saving two selected Zernike moments of the original watermarked image to estimate and correct the geometric attacks before watermark extraction. Experimental results show that the proposed algorithm is robust to any angle of rotation attacks and wide range of scaling attacks, and as well, a variety of other attacks such as lossy compression, common signal processing.     

Experimental study on the distribution of soil nitrate and ammonium nitrogen under controlled drainage

A field experimental project was set up to assess the effects of controlled drainage on the distribution and concentration of nitrogen in the soil at the Irrigation and Drainage Experimental Station under Four-Lake Engineering Administration of Jingzhou City, Hubei Province. Two plots drain runoff by controlled drainage system, with an area of 0.1 hm² (20 m×50 m) each. The third one with an area of 0.04 hm² (8 m×50 m) has a conventional subsurface drainage system. Under this experimental condition, the study draws the following conclusions: ① The controlled drainage system has a remarkable effect on the diminishing ratios of nitrate nitrogen between neighboring layers. It is presented that the diminishing ratio increases with the raising height of drain outlet. Controlled drainage system also reduces the transference of nitrate nitrogen in topsoil. ② Different from nitrate nitrogen, the concentration of ammonium nitrogen is stable along the longitudinal section of soil, which is little affected by the controlled drainage system. It indicates that the concentration of ammonium nitrogen decreases according to the lowering of controlling height of the drain outlet.     

An Analysis of Labor Resources "One River and Two Tributaries" Region in Tibet, China

Focusing on the region of Yarlung Zangbo River and the middle reaches of its two tributaries of Nianchu River and Lhasa River in Tibet (Herefter referred to as the “One River and Two Tributaries” region), and based on the data from China 3rd, 4th and 5th population censuses, the article has analyzed change patterns of this region's labor force, Major findings from the study are summarized as follows: ① Compared with the data from the 3rd census, labor force population in 2000 has increased significanlty. ② Children dependency coefficient has dropped, while old people dependency coefficient has changed very slightly with an increase of 0.047% only. ③ Compared 2000 with 1982, illiteracy and semi-illiteracy rate of the population above 15 years old have decreased significantly by 30. 69 percentage points, but still higher than the national average. ④ Women's illiteracy rate has dropped faster than men's, but up to 2000 it was generally quite high. The upgrading of the entire population's overall quality has a long way to go.     

Distribution Regularity of Debris Flow and Its Hazard in Upper Reaches of Yangtze River and Other Rivers of Southwestern China

In the upper reaches of Yangtze River and other rivers of southwestern China, the debris flows develop and lead to most serious disasters because of the various landforms, complex geological structures and abundant rainfall. The distribution of debris flows has regularity in the regions with different landform, geological structure, and precipitation. The regularities of distribution of debris flows are as following： （1） distributed in transition belts of different morphologic regions; （2） distributed in the area with strong stream trenching; （3） distributed along fracture zones and seismic belts： （4） distributed in the area with abundant precipitation; （5） distribution of debris flow is azonal. The activity of abundant debris flows not only brings harm to Towns, Villages and Farmlands, Main Lines of Communication, Water-Power Engineering, Stream Channels etc., but also induces strong water and soil loss. According to the present status of debris flow prevention, the problems in disasters mitigation and soil conservancy are found out, and the key works are brought up for the future disasters prevention and soil conservancy.