烧结铁矿中FeO含量对其在富氢高炉中还原行为的影响

Japan started the national project “COURSE 50” for CO₂ reduction in the 2000s. This project aimed to establish novel technologies to reduce CO₂ emissions with partially utilization of hydrogen in blast furnace-based ironmaking by 30% by around 2030 and use it for practical applications by 2050. The idea is that instead of coke, hydrogen is used as the reducing agent, leading to lower fossil fuel consumption in the process. It has been reported that the reduction behavior of hematite, magnetite, calcium ferrite, and slag in the sinter is different, and it is also considerably influenced by the sinter morphology. This study aimed to investigate the reduction behavior of sinters in hydrogen enriched blast furnace with different mineral morphologies in CO–CO₂–H₂ mixed gas. As an experimental sample, two sinter samples with significantly different hematite and magnetite ratios were prepared to compare their reduction behaviors. The reduction of wustite to iron was carried out at 1000, 900, and 800°C in a CO–CO₂–H₂ atmosphere for the mineral morphology-controlled sinter, and the following findings were obtained. The reduction rate of smaller amount of FeO led to faster increase of the reduction rate curve at the initial stage of reduction. Macro-observations of reduced samples showed that the reaction proceeded from the outer periphery of the sample toward the inside, and a reaction interface was observed where reduced iron and wustite coexisted. Micro-observations revealed three layers, namely, wustite single phase in the center zone of the sample, iron single phase in the outer periphery zone of the sample, and iron oxide-derived wustite FeO and iron, or calcium ferrite-derived wustite 'FeO' and iron in the reaction interface zone. A two-interface unreacted core model was successfully applied for the kinetic analysis of the reduction reaction, and obtained temperature dependent expressions of the chemical reaction coefficients from each mineral phases.     

Mg和La对Ca–Ti 处理钢中夹杂物演变和组织的影响

The evolution of inclusions and the formation of acicular ferrite (AF) in Ca–Ti treated steel was systematically investigated after Mg and La addition. The inclusions in the molten steel were Ca–Al–O, Ca–Al–Mg–O, and La–Mg–Ca–Al–O after Ca, Mg, and La addition, respectively. The type of oxide inclusion in the final quenched samples was the same as that in the molten steel. However, unlike those in molten steel, the inclusions were Ca–Al–Ti–O + MnS, Ca–Mg–Al–Ti–O + MnS, and La–Ca–Mg–Al–Ti–O + MnS in Mg-free, Mg-containing, and La-containing samples, respectively. The inclusions distributed dispersedly in the La-containing sample. In addition, the average size of the inclusions in the La-containing sample was the smallest, while the number density of inclusions was the highest. The size of effective inclusions (nucleus of AF formation) was mainly in the range of 1–3 μm. In addition, the content of ferrite side plates (FSP) decreased, while the percentage of AF increased by 16.2% due to the increase in the number of effective inclusions in the La-containing sample in this study.     

摩擦焊接碳钢（EN24）和镍基高温合金（IN718）的显微组织和力学性能

Continuous-drive rotary friction welding was performed to join cylindrical specimens of carbon steel (EN24) and nickel-based superalloy (IN718), and the microstructures of three distinct weld zones—the weld interface (WI)/thermo-mechanically affected zone (TMAZ), the heat-affected zone (HAZ), and the base metal—were examined. The joint was observed to be free of defects but featured uneven flash formation. Electron backscatter diffraction (EBSD) analysis showed substantial changes in high-angle grain boundaries, low-angle grain boundaries, and twin boundaries in the TMAZ and HAZ. Moreover, significant refinement in grain size (2–5 μm) was observed at the WI/TMAZ with reference to the base metal. The possible causes of these are discussed. The microhardness profile across the welded joint shows variation in hardness. The changes in hardness are ascribed to grain refinement, phase transformation, and the dissolution of strengthening precipitates. The tensile test results reveal that a joint efficiency of 100% can be achieved using this method.     

采用超声组装与滚压工艺制备铝–碳纳米管复合材料

This study introduced a novel fabrication of aluminum–carbon nanotube (CNT) composites by employing bulk acoustic waves and accumulative roll bonding (ARB). In this method, CNT particles were aligned using ultrasonic standing wave in an aqueous media, and the arrayed particles were precipitated on the aluminum plate substrate. Then, the plates rolled on each other through the ARB process with four passes. Optical and scanning electron micrographs demonstrated the effective aligning of CNTs on the aluminum substrate with a negligible deviation of arrayed CNTs through the ARB process. The X-ray diffraction pattern of the developed composites showed no peaks for carbon and aluminum carbide. In addition, tensile tests showed that the longitudinal strength of the specimens processed with aligned CNTs was significantly greater than that of the specimens with common randomly dispersed particles. The proposed technique is beneficial for the fabrication of Al–CNT composites with directional mechanical strength.     

活化天然矿石选择性还原二氧化碳为无定形碳

Natural magnetite formed by the isomorphism substitutions of transition metals, including Fe, Ti, Co, etc., was activated by mechanical grinding followed by H₂ reduction. The temperature-programmed reduction of hydrogen (H₂-TPR) and temperature-programmed surface reaction of carbon dioxide (CO₂-TPSR) were carried out to investigate the processes of oxygen loss and CO₂ reduction. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy-dispersive X-ray spectroscopy (EDS). The results showed that the stability of spinel phases and oxygen-deficient degree significantly increased after natural magnetite was mechanically milled and reduced in H₂ atmosphere. Meanwhile, the activity and selectivity of CO₂ reduction into carbon were enhanced. The deposited carbon on the activated natural magnetite was confirmed as amorphous. The amount of carbon after CO₂ reduction at 300°C for 90 min over the activated natural magnetite was 2.87wt% higher than that over the natural magnetite.     

含钛高炉炉渣微波合成碳化钛及其介电性能测定

The preparation of functional material titanium carbide by the carbothermal reduction of Ti-bearing blast furnace slag with microwave heating is an effective method for valuable metals recovery; it can alleviate the environmental pressure caused by slag stocking. The dynamic dielectric parameters of Ti-bearing blast furnace slag/pulverized coal mixture under high-temperature heating are measured by the cylindrical resonant cavity perturbation method. Combining the transient dipole and large π bond delocalization polarization phenomena, the interaction mechanism of the microwave macroscopic non-thermal effect on the titanium carbide synthesis reaction was revealed. The material thickness range during microwave heating was optimized by the joint analysis of penetration depth and reflection loss, which is of great significance to the design of the microwave reactor for the carbothermal reduction of Ti-bearing blast furnace slag.     

汽车暴露面板带有表面条状缺陷的夹杂物分布特征分析:一种定量电解方法

The specific distribution characteristics of inclusions along with the sliver defect were analyzed in detail to explain the formation mechanism of the sliver defect on the automobile exposed panel surface. A quantitative electrolysis method was used to compare and evaluate the three-dimensional morphology, size, composition, quantity, and distribution of inclusions in the defect and non-defect zone of automobile exposed panel. The Al₂O₃ inclusions were observed to be aggregated or chain-like shape along with the sliver defect of about 3–10 μm. The aggregation sections of the Al₂O₃ inclusions are distributed discretely along the rolling direction, with a spacing of 3–7 mm, a length of 6–7 mm, and a width of about 3 mm. The inclusion area part is 0.04%–0.16% with an average value of 0.08%, the inclusion number density is 40 mm?2 and the inclusion average spacing is 25.13 μm. The inclusion spacing is approximately 40–160 μm, with an average value of 68.76 μm in chain-like inclusion parts. The average area fraction and number density of inclusions in the non-defect region were reduced to about 0.002% and 1–2 mm?2, respectively, with the inclusion spacing of 400 μm and the size of Al₂O₃ being 1–3 μm.     

在酸性溶液中加压氧化三价砷离子和二价铁离子

The co-oxidation of As(III) and Fe(II) in acidic solutions by pressured oxygen was studied under an oxygen pressure between 0.5 and 2.0 MPa at a temperature of 150°C. It was confirmed that without Fe(II) ions, As(III) ions in the solutions are virtually non-oxidizable by pressured oxygen even at a temperature as high as 200°C and an oxygen pressure up to 2.0 MPa. Fe(II) ions in the solutions did have a catalysis effect on the oxidation of As(III), possibly attributable to the production of such strong oxidants as hydroxyl free radicals (OH·) and Fe(IV) in the oxidation process of Fe(II). The effects of such factors as the initial molar ratio of Fe(II)/As(III), initial pH value of the solution, oxygen pressure, and the addition of radical scavengers on the oxidation efficiencies of As(III) and Fe(II) were studied. It was found that the oxidation of As(III) was limited in the co-oxidation process due to the accumulation of the As(III) oxidation product, As(V), in the solutions.     

左手材料的性质及研究动态

左手材料(也被称为负折射率材料)最早由前苏联科学家Veselago在20世纪60年代从理论上提出来的,是一种具有介电常数和磁导率同时为负值的材料,它具有诸如负相位速度,负折射率,理想成像,逆Doppler频移及反常的Cerenkon辐射等多种奇异的物理现象。本文主要论述左手材料的性质并分析左手材料全新应用前景,简要介绍左手材料近年来的研究动态及发展前景。     

铌酸锂的折射率奇异

在10至150℃温度范围内用不同波长的可见光测量了铌酸锂铁电单畴单晶的折射率n_o和N_e,发现在45、75、125℃附近出现异常变化。观察了弛豫效应和热释电效应对测量结果的影响。用椭偏光测出了晶体不同方向表面层的复折射率。实验支持125℃附近的异常与表面状态有关。     

掠射法测三棱镜色散折射率

提出在分光计上采用平行光掠射法测量透明光学材料折射率的方法,论述了该方法的实验原理,给出了测量公式,并详尽介绍了该方法的实验操作方法。同目前国内外所采用光学材料折射率测量方法相比,不但具有操作方便迅速、环境条件要求低的特点,而且所得谱线锐利清晰,谱线条数多,位置稳定,实验测量精度高等优点。     

非均匀介质下的可调光流控器件及其生化应用

 探讨了非均匀介质下不同光流控器件及其生化应用。在微流控芯片上，主要从2个方面开发和实现各类具有光波导、透镜、细胞计数、化学检测等功能的新器件。首先，在液液非均匀介质下，通过调节沟道内液体流速，控制液体间的对流扩散来实现液体在微腔内的渐变折射率分布和阶跃分布，从而得到其特殊的光学特性，例如光束分离、弯曲、自聚焦等。其次，在固体非均匀介质下，利用特殊的微流结构与液体相结合，实现更加灵敏可调的新型探测手段。这些新型技术手段分别在生物传感、能源生产、细胞探测及海水检测等诸多应用中可发挥关键性作用。     

先验知识在三维折射率场重建中的应用研究

在干涉层析中，目前最大的难点仍是对非完全投影数据场的重建，非完全投影数据指观察角小于１８０°，或者折射率场中存在不透明的遮挡模型，问题的核心在于如何设计结合先验知识的可行算法，对于三维折射率场的重建，先验知识，如折射率非负，遮挡物的尺寸，几何形状，空间位置等是常用的信息。该文提出了一种有效易行的给先验知识的三维折射率场重虎法，在算法中引起属性矩阵的概念，无需对缺少的投影数据补齐，将该算法应用于高超     

高反射率的AlxGa（1-x）N/AlyGa（1-y）N布拉格反射器的特性研究

简单地介绍了布拉格反射器在发光二极管中的应用概况,并从理论上分析了通过将分布式布拉格反射器应用于紫外发光二极管中可以有效抑制内部吸收,从而获得较大输出能量的原理及方法。定量分析了决定DBR系统性能的几个主要因素之间的关系,即:A.膜层禁带宽度Eg与膜层材料中Al的质量分数之间的关系;B.室温下折射系数与Al的质量分数之间的关系;C.膜层禁带宽度Eg与温度之间的关系。     

紫外折射率精密测量

基于自准直法，利用一套高精度测量系统对ＣａＦ＿２晶体的紫外折射率进行了测量研究，并给出了较高精度的测量结果。     

光线通过轴向梯折分布玻璃板内的传播分析

本文给出了用电子探针扫描技术测量以玻璃板两大面到中心面逐渐减少(或增加)的Ag~+或Ti~+的浓度分布。着重讨论了光线通过这两种梯度折射率分布的玻璃板内的轴向传播,并与线性梯度折射率分布的玻璃板轴向传播作了比较。     

透明球体的偏向角研究

从理论上推出了透明球体的偏向角，用计算机绘出了不同拆射率球体、不同入射角情况下的偏向角，并指出了其应用前景．