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1.
报导用连续变化度法在非水溶剂DMF溶液中测定一种瓣合成的配体,N,N’-bis(8-quinolyl)malonamide和4种过渡金属离子Cu^2+、Zn^2+、Co^2+、Ci^2+所形成配合物的稳定常数,按共对数值的大小排列有如下顺序:Cu^2+(5.62)〉Zn^2+(4.03)〉Ni^2+(3.82)〉Co^2+(3.79),配合物的配位比为1:1。实验表明,它们的稳定性较之在水体系中,  相似文献   

2.
采用PH滴 定法研究风化某FA和发酵法FA与金属离子的络合能力,给出相的PH滴定曲线,获得了7种金属离子与两种不同来源FA络合倾向的大小顺序,即:Mg^2+〈Co^2+〈Ni^2+〈Zn^2+〈Cu^2+〈Al^3+〈Fe^3+。  相似文献   

3.
本文用pH电位滴定法研究了腺苷三磷酸ATP与8种稀土金属离子La^3+、Pr^3+、Sm^3+、Nd^3+、Gd^3+、Ho^3+、Er^3+、Yb^3+和55种过渡金属离子Mn^2+、Co^2+、Ni^2+、Zn^2+、Cu^2+形成的配合物的稳定性顺序。  相似文献   

4.
金属离子与伴刀豆球蛋白A刺激细胞作用的关系研究   总被引:1,自引:0,他引:1  
采用^3H-TDR掺入法,研究了过渡金属离子Cd^2+、Ni^2+、Cu^2+和Zn^2+取代Con-A中Mn^2+之后,对人淋巴细胞刺激分裂作用影响。研究结果表明,不同的金属离子取代后的Con-A刺激活性都明显提高。  相似文献   

5.
合成了一类新型吡啶衍生物配体,其组成和结构经MS,IR,1HMR及元素分析确证.研究了它们与金属离子(Cu2+,Ni2+,Zn2+)及CTAB形成金属胶束对PNPP水解的催化性能.结果表明,这些金属胶束对PNPP水解有显著的催化作用,金属离子在金属胶束中的活性大小依次为Cu2+,Ni2+和Zn2+.  相似文献   

6.
报导用连续变化光度法在非水溶剂DMF溶液中测定一种新合成的配体,N,N′-bis(8-quinolyl)malonamide和4种过渡金属离子Cu2+、Zn2+、Co2+、Ni2+所形成配合物的稳定常数。按其对数值的大小排列有如下顺序:Cu2+(5.62)>Zn2+(4.03)>Ni2+(3.82)>Co2+(3.79),配合物的配位比为11.实验表明,它们的稳定性较之在水体系中、类似的酰胺配合物的稳定性要大得多  相似文献   

7.
采用TG、DSC和XRD等手段研究了多酸层柱双氢氧化物Ms2Al-XW11Z(M=Co^2+,Ni^2+;X=Si^4+,Ge^4+,B^3+;Z=Cu^2+,Ni^2+,Co^2+)在空气气氛中的热解过程,得到了Co2Al-XW11Z系列化合物的三步热分解机理和热稳定性序列,而对于Ni2Al-XW11Z系列化合物,则表现出不同的热解过程。  相似文献   

8.
重金属离子对扁玉螺细胞色素氧化酶的影响研究   总被引:1,自引:0,他引:1  
测定子扁玉螺肝脏中细胞色素氧化酶活力,其最适温度为44℃,最适PH值7.0研究了Fe^3+,Cu^2+,Zn^2+三种重金属离子在离体条件下对该酶的影响,结果显示:低浓度的Fe^3+Cu^2+对其具有激活作用,高浓度的Fe^3+,Cu^2+及低浓度的Zn^2+对其具有显著的抑制作用。  相似文献   

9.
金属离子和脲对背角无齿蚌碱性磷酸酶的影响   总被引:9,自引:3,他引:9  
研究了多种金属离子对背角无齿蚌碱性磷酸酶(AKP)活性的影响,结果表明:Na^+,K^+和Li^+等一价金属离子没有影响:Mg^2+,Ca^2+,Ba^2+,Ni^2+,Mn^2+和Co^2+有激活作用;而Cu^2+,Zn^2+,Hg^2+,Cd^2+及Ag^+有抑制作用,脲对AKP的变性失活作用,按脲浓度可为低于2mol/L和高于2mol/L两种类型,低浓度脲对背角无齿蚌AKP活性抑制的动力学表  相似文献   

10.
本文制备了乙二胺螯合滤纸,研究其对痕量Cu^2+、Cd^2+、Zn^2+、Ni^2|等金属离子的吸附性能,并应用于各类水样中痕量金属离子的测定。  相似文献   

11.
Language markedness is a common phenomenon in languages, and is reflected from hearing, vision and sense, i.e. the variation in the three aspects such as phonology, morphology and semantics. This paper focuses on the interpretation of markedness in language use following the three perspectives, i.e. pragmatic interpretation, psychological interpretation and cognitive interpretation, with an aim to define the function of markedness.  相似文献   

12.
The Williston Basin is a significant petroleum province, containing oil production zones that include the Middle Cambrian to Lower Ordovician, Upper Ordovician, Middle Devonian, Upper Devonian and Mississippian and within the Jurassic and Cretaceous. The oils of the Williston Basin exhibit a wide range of geochemical characteristics defined as "oil families", although the geochemical signature of the Cambrian Deadwood Formation and Lower Ordovician Winnipeg reservoired oils does not match any "oil family". Despite their close stratigraphic proximity, it is evident that the oils of the Lower Palaeozoic within the Williston Basin are distinct. This suggests the presence of a new "oil family" within the Williston Basin. Diagnostic geochemical signatures occur in the gasoline range chromatograms, within saturate fraction gas chromatograms and biomarker fingerprints. However, some of the established criteria and cross-plots that are currently used to segregate oils into distinct genetic families within the basin do not always meet with success, particularly when applied to the Lower Palaeozoic oils of the Deadwood and Winnipeg Formation.  相似文献   

13.
王慧 《科技信息》2008,(10):240-240
Wuthering Heights, Emily Bronte's only novel, was published in December of 1847 under the pseudonym Ellis Bell. The book did not gain immediate success, but it is now thought one of the finest novels in the English language. Catherine is the key character of this masterpiece, because everybody and everything center on her though she had a short life. We can understand this masterpiece better if we know Catherine well.  相似文献   

14.
何延凌 《科技信息》2008,(4):258-258
Language is a means of verbal communication. People use language to communicate with each other. In the society, no two speakers are exactly alike in the way of speaking. Some differences are due to age, gender, statue and personality. Above all, gender is one of the obvious reasons. The writer of this paper tries to describe the features of women's language from these perspectives: pronunciation, intonation, diction, subjects, grammar and discourse. From the discussion of the features of women's language, more attention should be paid to language use in social context. What's more, the linguistic phenomena in a speaking community can be understood more thoroughly.  相似文献   

15.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

16.
Location based services is promising due to its novel working style and contents.A software platform is proposed to provide application programs of typical location based services and support new applications developing efficiently. The analysis shows that this scheme is easy implemented, low cost and adapt to all kinds of mobile nework system.  相似文献   

17.
以AC-13级配为基础,将橡胶颗粒代替部分集料掺入混合料中,以低温弯曲试验为评价方法对不同橡胶颗粒掺量下沥青混合料的低温抗裂性进行研究,并引入应变能密度值对混合料的低温抗裂性进行综合评价.试验结果表明:橡胶颗粒沥青混合料试件的破坏微应变均超过2 300,满足冬寒区的技术指标;无论是否掺加橡胶颗粒,随着温度的下降,沥青混合料破坏时的最大弯拉强度增大,弯拉应变降低,劲度模量增大;弯曲应变能密度在胶粒掺量为1%左右时具有较大的弯曲应变能密度值,此时橡胶颗粒沥青混合料具有较好的低温抗裂性.  相似文献   

18.
理论推导与室内实验相结合,建立了低渗透非均质砂岩油藏启动压力梯度确定方法。首先借助油藏流场与电场相似的原理,推导了非均质砂岩油藏启动压力梯度计算公式。其次基于稳定流实验方法,建立了非均质砂岩油藏启动压力梯度测试方法。结果表明:低渗透非均质砂岩油藏的启动压力梯度确定遵循两个等效原则。平面非均质油藏的启动压力梯度等于各级渗透率段的启动压力梯度关于长度的加权平均;纵向非均质油藏的启动压力梯度等于各渗透率层的启动压力梯度关于渗透率与渗流面积乘积的加权平均。研究成果可用于有效指导低渗透非均质砂岩油藏的合理井距确定,促进该类油藏的高效开发。  相似文献   

19.
As an American modern novelist who were famous in the literary world, Hemingway was not a person who always followed the trend but a sharp observer. At the same time, he was a tragedy maestro, he paid great attention on existence, fate and end-result. The dramatis personae's tragedy of his works was an extreme limit by all means tragedy on the meaning of fearless challenge that failed. The beauty of tragedy was not produced on the destruction of life, but now this kind of value was in the impact activity. They performed for the reader about the tragedy on challenging for the limit and the death.  相似文献   

20.
Quality traits in wheat (Triticum aestirum L.) were studied by quantitative trait locus (QTL) analysis in a recombinant inbred line (RIL) population, a set of 131 lines derived from Chuan 35050 × Shannong 483 cross (ChSh). Grains from RILs were assayed for 21 quality traits related to protein and starch. A total of 35 putative QTLs for 19 traits with a single QTL explaining 7.99-40.52% of phenotypic variations were detected on 10 chromosomes, 1D, 2A, 2D, 3B, 3D, 5A, 6A, 6B, 6D, and 7B. The additive effects of 30 QTLs were positive, contributed by Chuan 35050, the remaining 5 QTLs were negative with the additive effect contributed by Shannong 483. For protein traits, 15 QTLs were obtained and most of them were located on chromosomes 1 D, 3B and 6D, while 20 QTLs for starch traits were detected and most of them were located on chromosomes 3D, 6B and 7B. Only 7 QTLs for protein and starch traits were co-located in three regions on chromosomes 1D, 2A and 2D. These protein and starch trait QTLs showed a distinct distribution pattern in certain regions and chromosomes. Twenty-two QTLs were clustered in 6 regions of 5 chromosomes. Two QTL clusters for protein traits were located on chromosomes 1D and 3B, respectively, three clusters for starch traits on chromosomes 3D, 6B and 7B, and one cluster including protein and starch traits on chromosome 1D.  相似文献   

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