| 2(3)-四-(2-异丙基-5-甲基苯氧基)酞菁铜的合成、 光特性及电化学性质 |
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| 引用本文： | 何为,马春雨,程传辉,于书坤,范昭奇,夏道成,杜锡光,杜国同.2(3)-四-(2-异丙基-5-甲基苯氧基)酞菁铜的合成、 光特性及电化学性质[J].吉林大学学报(理学版),2008,46(4):769-773. |
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| 作者姓名： | 何为 马春雨 程传辉 于书坤 范昭奇 夏道成 杜锡光 杜国同 |
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| 作者单位： | 1. 大连理工大学 物理与光电工程学院, 辽宁 大连 116023； 2. 吉林大学 集成光电子学国家重点实验室, 长春 130012； 3. 东北师范大学 化学学院, 长春 130024 |
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| 摘 要： | 利用分步合成方法在酞菁铜外围引入4个2-异丙基-5-甲基苯氧基团, 合成一种酞菁铜, 经过表征确定了化合物结构. 分析结果表明, 此化合物在低温近红外1 180 nm左右有较强的光磷光发光, 可作为潜在的近红外发光材料. 电化学的研究结果表明, 这种化合物的电化学过程是环上氧化还原的单电子过程.
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| 关 键 词： | 酞菁铜 苯氧基 光致发光 电化学 光谱电化学 |
| 收稿时间： | 2007-07-12 |
Synthesis, Optical and Electrochemical Properties of Copper Tetra-(2-isopropyl-5-methylphenoxy) Phthalocyanine |
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| HE Wei,MA Chun-yu,CHENG Chuan-hui,YU Shu-kun,FAN Zhao-qi,XIA Dao-cheng,DU Xi-guang,DU Guo-tong.Synthesis, Optical and Electrochemical Properties of Copper Tetra-(2-isopropyl-5-methylphenoxy) Phthalocyanine[J].Journal of Jilin University: Sci Ed,2008,46(4):769-773. |
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| Authors: | HE Wei MA Chun-yu CHENG Chuan-hui YU Shu-kun FAN Zhao-qi XIA Dao-cheng DU Xi-guang DU Guo-tong |
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| Institution: | 1. School of Physics and Optoelectronic Technology of DUT, Dalian University of Technology, Dalian 116023, Liaoning Province, China; 2. State Key Laboratory of Integrated Optoelectronics, Jilin University, Changchun 130012, China; 3. School of Chemistry, Northeast Normal University, Changchun 130024, China |
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| Abstract: | Copper tetra-(2-isopropyl-5-methylphenoxy) phthalocyanine was prepared and characterized by MS and elemental analysis. Its photoluminescence (PL) spectra show a peak centered at about 1 180 nm, which indicates that it can be used as a near infrared functional material. Electrochemistry shows the redox of this complex is one electron processes which include two ring based reductions and one ring based oxidation. The identities of these electrode processes were further revealed by performing spectroelectrochemical experiments. |
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| Keywords: | copper phthalocyanine phenoxy photoluminescence electrochemistry spectroelectrochemistry |
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