| 2-（甲硫基）苯并[d]噁唑-5-羧酸的合成及电致化学发光性能 |
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| 引用本文： | 姜国民,詹文毅,颜瑞,路毛凤,江国庆.2-（甲硫基）苯并[d]噁唑-5-羧酸的合成及电致化学发光性能[J].南通工学院学报(自然科学版),2013(3):48-52. |
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| 作者姓名： | 姜国民 詹文毅 颜瑞 路毛凤 江国庆 |
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| 作者单位： | 南通大学化学化工学院,江苏南通226019 |
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| 基金项目： | 国家自然科学基金项目（21173122） |
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| 摘 要： | 以对羟基苯甲酸甲酯为原料，通过硝化，还原，关环，甲基化合成2-（甲硫基）苯并d]噁唑5-羧酸，过程的总收率为49．17％．利用红外光谱（FTIR）、核磁共振谱（^1HNMR）、质谱（HPLC—MS）和元素分析等分析手段对中间产物及目标化合物进行了表征．通过分子自组装膜法将其负载在金电极上，分别在四丁基六氟膦酸胺-乙腈电解液、磷酸盐缓冲水溶液中检测其电化学发光性能，结果表明，在水相中电致化学发光强度明显高于有机相．
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| 关 键 词： | 对羟基苯甲酸甲酯 2-（甲硫基）苯并[d]噁唑-5-羧酸 合成 电化学发光 |
Synthesis and Electrogenerated Chemiluminescence Property of 2-（Methylthio）Benzo[d]Oxazole-5-Carboxylic Acid |
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| Authors: | JIANG Guo-min ZHAN Wen-yi YAN Rui LU Mao-feng JIANG Guo-qing |
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| Institution: | (School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China) |
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| Abstract: | In this paper, with methyl 4-hydroxybenzoate as raw material, 2-（methylthio）benzo d]oxazole -5- carboxylic acid was synthesized by nitration , reduction, cyclization, methylation. The structures of the intermediates and 2-（methylthio）benzo d]oxazole-5-carboxylic acid were characterized by FFIR, 1HNMR, HPLC-MS and element analysis. The product was loaded on the surface of gold elctrode by self-assembly, and the electrochemiluminesoence was measured in tetrabutylammonium hexafluorophosphate-acetonitrile electrolyte and phosphate buffer solution. The results reveal that electrochemiluminesoence intensity is higher in aqueous phase than it is in organic phase. |
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| Keywords: | methyl 4-hydroxybenzoate 2-（methylthio）benzo[d]oxazole-5-carboxylic acid synthesis electrochemiluminesoence |
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