Hydrothermal synthesis,structures and properties of metal phosphonates based on m-xylylenediphosphonic acid

In this work, a series of new metal phosphonates were hydrothermally synthesized and structurally characterized based on m-xylylenediphosphonic acids （H4L）, including [M（H2L）（bpy）] （M = Mn 1, Co 2）, [MH2L）（phen）] （M = Co 3, Cu 4）, and [Cu2（H2L）2（bpy＂）2] 5 （bpy = 2,2＇-bipyfidine, phen = 1,10-phenanthroline, bpy＂ = 4,4＇-dimethyl-2,2＇- bipyridine）. X-ray diffraction indicated that compounds 1 and 2 were isomorphic. Complexes 3 and 4 were shown to crystallize in different space groups but had similar crystallographic units. In the complexes, H4L was seen to partially deprotonate to afford H2L^2-. The H2L^2- ligands in 1-4 functioned as tetradentate ligands with each phosphonate group adopting bidentate coordination mode with two M centers to generate a 2D layer. In addition, the H2L^2- anions in 5 functioned as tfidentate ligands with one phosphonate group adopting the bidentate mode and another phosphonate group adopting the monodentate mode, thus linking three Cu atoms to provide a 1D chain. The IR and thermal stabilities of these compounds were subsequently examined.     

Progress in the research of radical anion ligands and their complexes

Recent progress in the research of radical anion ligands and their complexes with metals were summarized in this review. Radical anions were sorted into several types including iminosemiquinonate and iminoquinonate radical, nitroxide radical, heterocycle radical etc. Structural characteristics and properties of the corresponding complexes were introduced. The complexes exhibited novel properties and possibility for applications in organic magnetic materials and transition metal catalysis.     

多糖金属配合物的研究进展

多糖金属配合物由于其结构和生物活性的特殊性已成为当今天然产物研究领域的热门课题,研究的热点主要集中在植物类多糖铁复合物和壳聚糖与钙、铁、铜、稀土元素离子形成的配合物上。该文对多糖金属复合物的制备工艺、理化性质和药理作用、工业用途等方面进行了综述。     

耦合双桩共振子MDM波导结构中光学性质的研究

采用时域有限差分方法研究了同侧和异侧耦合双桩共振子的MDM波导结构中的光学性质．发现同侧耦合双桩共振子的MDM波导中桩间距改变时对透射谱影响很大,当间距较小时,出现两个很尖锐的透射峰,当间距较大时,其中一个峰消失,另一个峰增强．异侧耦合双桩共振子的MDM波导结构中桩长度不一样时,能导致Fano共振而产生新的尖锐的峰．     

全膜润滑金属成形工艺的有限元仿真分析

全膜润滑的金属成形的数值分析非常少,这主要是由于求解润滑模型的方法只适用于轴对称和平面应变情况.因此,本文中提出了全润滑膜润滑和金属成形有限元法相结合的统一方法,适用于稳态和非稳态的三维成形工艺,也适用于轴对称和平面应变情况.而一个轴对称拉深成形被用来做一个样板实验.该法大幅度增加了仿真的精度.而理论计算的润滑膜厚与实测值相一致,这也证明本文的方法优于其它方法.     

Solvent-free selective hydrogenation of o-chloronitrobenzene to o-chloroaniline over alumina supported Pt nanoparticles

A supported Pt/Al2O3 catalyst was prepared by immobilizing preformed colloidal Pt nanoparticles on Al2O3. The particle size and size distribution of Pt particles on Al2O3 remained the same as the colloidal nanoparticles. Selective hydrogenation of o-chloronitrobenzene to ochloroaniline was performed on the as-prepared Pt/Al2O3 nanocatalyst without using any solvent and 88.5% selectivity to o-chloroaniline at 98.2% conversion of o-chloronitrobenzene was achieved. Further catalytic experiments with metal cation modification showed that some metal cations could improve the activity in various degrees while maintaining the high selectivity. Especially, 99.8% selectivity to o-chloroaniline at ~100% conversion was attained with Sn4t.     

工程管路中波纹管膨胀节的选型与应用

分析了管路系统主固定支架的受力情况,指出了波纹管膨胀节选型的注意事项.在剖析1个工程实例后,提出了合理的处理方法.     

金属羰基化合物氧原子转移反应动力学和机理研究的信息与进展(二)

续上饶《上饶师专学报》１９９８年第６期）２．５信息之五氧转移试剂（ＲＡ－Ｏ）的Ａ－Ｏ键能及其取代基的性质是影响其反应活性的重要因素。２．５．１取代基的推电子性能增大胺类Ｎ－氧化物反应活性氧转移反应研究中最为吸引人的问题之一，是试图了解转移试剂的什么性...     

建筑钢结构构件加工过程的质量控制

建筑钢结构有着单重轻、可预制、结构细长、易运输等特点,所以在质量控制方面表现出了与常规钢结构不同的一些质量要点,结合近些年国内外在建筑钢结构质量控制方面的发展及部分项目质量控制实例,简要介绍建筑钢结构构件加工过程的质量控制。     

环境污染原生动物监测的研究进展

简要概述了原生动物在监测环境污染方面的优势,论述了以草履虫为典型代表的原生动物在监测重金属离子和化学农药造成的环境污染方面的研究进展,并且提出了原生动物在环境污染监测中存在的问题,还对其应用前景做出了展望.