FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

Acyl-chloride functionalized graphene oxide chemically grafted with hindered phenol and its application in anti-degradation of polypropylene

In this study,graphene oxide (GO) nanosheets were first functionalized by the acyl-chloride reaction and then reacted with hindered phenol (HP) to obtain HP grafted GO (GO-g-HP).The GO-g-HP prepared under the optimized condition exhibited a high efficiency against both thermal and photo oxidation of isotactic polypropylene (iPP).GO-g-HP exhibited a much better anti-aging efficiency than that of HP and GO used individually or that of their physical mixture.The outstanding anti-aging effect of GO-g-HP was attributed to the excellent synergistic effect produced between the chemically bonded GO and HP,which resulted in an improved oxygen barrier property of GO and excellent utilization of the free radical scavenging capability of GO and HP.Also,thanks to the grafting of HP on GO,the physical loss of HP,which was one of the main shortcomings for traditional small molecular antioxidants,was largely suppressed.It is expected that the GO-g-HP prepared can well meet the requirement of long-term applications of polymers in some harsh service conditions.     

丙酸盐对厌氧氨氧化除氮性能及群落结构的影响

为了探究有机碳对厌氧氨氧化的长期影响, 向厌氧氨氧化膜生物反应器中添加不同浓度的丙酸钠, 研究对反应器的除氮效能以及微生物的种群结构和功能变化。结果表明: 反应器主要的脱氮过程由CandidatusBrocadia完成, 当丙酸钠浓度为100 mg/L时, 反应器中由于异养细菌的生长, 可实现碳氮的同步去除, 平均总氮去除率可达91.9%。当丙酸钠浓度为200 mg/L 时, 对Candidatus Brocadia的抑制作用导致反应器除氮性能下降, Candidatus Brocadia的丰度降至41.2%, 总氮去除率降至 78.8%。在有机碳抑制作用解除后, 反应器的除氮性能恢复为86.8%, Candidatus Brocadia丰度增加到54.0%, 但群落多样性下降, 属水平的微生物组成有较大的改变。     

正交试验优化手性镍催化不对称反应条件研究

用正交试验法优化手性镍催化二乙基锌对α，β不饱和酮的不对称麦克尔加成反应条件，优化后的不对称麦克尔加成反应的一般条件为：低温(近反应溶剂冰点)，常压，非质子非极性溶剂(环己烷)．     

Modulation of protein biophysical properties by chemical glycosylation: biochemical insights and biomedical implications

Glycosylation constitutes one of the most important posttranslational modifications employed by biological systems to modulate protein biophysical properties. Due to the direct biochemical and biomedical implications of achieving control over protein stability and function by chemical means, there has been great interest in recent years towards the development of chemical strategies for protein glycosylation. Since current knowledge about glycoprotein biophysics has been mainly derived from the study of naturally glycosylated proteins, chemical glycosylation provides novel insights into its mechanistic understanding by affording control over glycosylation parameters. This review presents a survey of the effects that natural and chemical glycosylation have on the fundamental biophysical properties of proteins (structure, dynamics, stability, and function). This is complemented by a mechanistic discussion of how glycans achieve such effects and discussion of the implications of employing chemical glycosylation as a tool to exert control over protein biophysical properties within biochemical and biomedical applications. Received 15 December 2006; received after revision 28 March 2007; accepted 25 April 2007     

溶胶-凝胶法制备SiO2-P2O5-TiO2粉体

采用溶胶-凝胶工艺制备出平均尺寸为0.109μm的SiO2-P2O5-TiO2细小均匀的粉体。通过XRD、SEM、热重分析发现,粉体中存在着包裹在颗粒周围的无定形二氧化硅膜,能有效的抑制水解时磷和钛的副反应发生,改善了粉体的化学稳定性,并且该粉体具有良好的吸湿性,适合于制备电解质薄膜。     

工程中常用的几种氧化沟及其发展

简要介绍了当今工程中常用的几种氧化沟技术的特点及其发展历程,主要包括Carrousel氧化沟、Orbal氧化沟、交替式氧化沟以及一体化氧化沟。     

pH、温度和浓度对苯酚在V掺杂MoOx-C/Ti电极上的电催化氧化的影响

采用溶胶-凝胶法合成MoOx、MoOx-V5 (x%)胶体,通过Vulcan XC-72炭黑负载制备炭载钼系氧化物电催化剂.利用循环伏安法(CV)测试手段研究苯酚在电极上的氧化降解,考察了掺杂元素、溶液pH值、苯酚浓度、扫描速率、温度对苯酚氧化性能的影响.测试结果表明:苯酚在电极上的氧化是受扩散和电子转移联合控制的复杂过程;掺杂过渡金属元素V可以降低苯酚氧化的表观活化能,提高电化学性能;溶液的pH值越低,MoOx-C/Ti电极对苯酚的催化氧化活性越高;pH在0～6,苯酚的氧化经历了相似的历程,包含了相同的电子数和质子数;苯酚氧化峰电流随着浓度、温度的增加而增加,到一定程度后趋于稳定.     

选择性催化氧化H2S的催化剂研究

在考察了几种单组分氧化物把硫化氢催化氧化为单质硫的基础上，采用共沉淀法合成了3种复合氧化物催化剂A，B，C，并考察了它们的催化活性和选择性．结果表明，在一定条件下，催化剂B的转化率和选择性分别在90％和97％以上，在40h的催化性能稳定性测试中，其转化率和选择性均能保持稳定，具有良好的催化性能．