全文获取类型
收费全文 | 6638篇 |
免费 | 59篇 |
国内免费 | 58篇 |
专业分类
系统科学 | 636篇 |
丛书文集 | 464篇 |
教育与普及 | 313篇 |
理论与方法论 | 22篇 |
现状及发展 | 413篇 |
研究方法 | 664篇 |
综合类 | 4237篇 |
自然研究 | 6篇 |
出版年
2017年 | 10篇 |
2016年 | 9篇 |
2015年 | 11篇 |
2014年 | 16篇 |
2013年 | 24篇 |
2012年 | 324篇 |
2011年 | 395篇 |
2010年 | 155篇 |
2009年 | 95篇 |
2008年 | 456篇 |
2007年 | 425篇 |
2006年 | 676篇 |
2005年 | 687篇 |
2004年 | 379篇 |
2003年 | 340篇 |
2002年 | 336篇 |
2001年 | 277篇 |
2000年 | 398篇 |
1999年 | 141篇 |
1998年 | 75篇 |
1997年 | 39篇 |
1996年 | 26篇 |
1995年 | 40篇 |
1994年 | 38篇 |
1993年 | 54篇 |
1992年 | 26篇 |
1991年 | 38篇 |
1990年 | 23篇 |
1989年 | 37篇 |
1988年 | 22篇 |
1987年 | 32篇 |
1986年 | 33篇 |
1985年 | 34篇 |
1984年 | 33篇 |
1983年 | 31篇 |
1982年 | 33篇 |
1981年 | 23篇 |
1980年 | 15篇 |
1979年 | 17篇 |
1972年 | 10篇 |
1971年 | 18篇 |
1970年 | 36篇 |
1966年 | 10篇 |
1959年 | 101篇 |
1958年 | 174篇 |
1957年 | 130篇 |
1956年 | 115篇 |
1955年 | 103篇 |
1954年 | 126篇 |
1948年 | 43篇 |
排序方式: 共有6755条查询结果,搜索用时 251 毫秒
1.
Cobalt (Co)-modified brownmillerite KBiFe2O5 (KBFO; [KBiFe2(1?x)Co2xO5 (x = 0, 0.05)]) polycrystalline is synthesized following the solid-state reaction route. Rietveld refinement of X-ray diffraction data confirmed the phase purity of KBFO and KBiFe1.9Co0.1O5 (KBFCO). The optical bandgap energy (Eg) of KBFO decreased from 1.59 to 1.51 eV because of Co substitution. The decrease in bandgap can be attributed to the tilting of the Fe–O tetrahedral structure of KBFCO. The observed room-temperature Raman peaks of KBFCO shifted by 3 cm?1 toward a lower wavenumber than that of KBFO. The shift in Raman active modes can be attributed to the change in the bond angles and bond lengths of the Fe–O tetrahedral structure and modification in response to oxygen deficiency in KBFO because of Co doping. Compared with that of KBFO, the frequency-dependent dielectric constant and dielectric loss of KBFCO decrease at room temperature, which is a con-sequence of the reduction in oxygen migration and modification in response to vibrational modes present in the sample. 相似文献
2.
C.D.Gómez-Esparza R.Peréz-Bustamante J.M.Alvarado-Orozco J.Mu?oz-Salda?a R.Martínez-Sánchez J.M.Olivares-Ramírez A.Duarte-Moller 《北京科技大学学报》2019,(5)
An AlCoCuCrFeNiTi high-entropy alloy(HEA) was prepared by mechanical alloying and sintering to study the effect of Ti addition to the widely studied AlCoCuCrFeNi system. The structural and microstructural characteristics were investigated by X-ray diffraction(XRD), scanning electron microscopy(SEM), and transmission electron microscopy(TEM). The formation of four micrometric phases was detected: a Cu-rich phase with a face-centered cubic(fcc) structure, a body-centered cubic(bcc) solid solution with Cu-rich plate-like precipitates(fcc), an ordered bcc phase, and a tetragonal structure. The XRD patterns corroborate the presence of a mixture of bcc-, fcc-, and tetragonal-structured phases. The Vickers hardness of the alloy under study was more than twice that of the AlCoCuCrFeNi alloy. Nanoindentation tests were performed to evaluate the mechanical response of the individual phases to elucidate the relationship between chemical composition, crystal structure, and mechanical performance of the multiphase microstructure of the AlCoCuCrFeNiTi HEA. 相似文献
3.
Effects of small additions of Zn on the microstructure,mechanical properties and corrosion resistance of WE43B Mg alloys 下载免费PDF全文
A. V. Koltygin V. E. Bazhenov R. S. Khasenova A. A. Komissarov A. I. Bazlov V. A. Bautin 《矿物冶金与材料学报》2019,26(7):858-868
Zn is a commonly used alloying element for Mg alloys owing to its beneficial effects on mechanical properties. To improve the mechanical and corrosion properties of WE43B Mg alloys, the effects of 0-0.7wt% Zn addition on the microstructure and properties of sample alloys were investigated. Addition of Zn to as-cast WE43B alloy promoted the formation of the Mg12Nd phase; by contrast, after T6 heat treatment, the phase composition of WE43B alloys with and without Zn addition remained mostly the same. A long-period stacking ordered phase was predicted by CALPHAD calculation, but this phase was not observed in either the as-cast or heat-treated Zn-containing WE43B alloys. The optimum temperature and duration of T6 heat treatment were obtained using CALPHAD calculations and hardness measurements. Addition of Zn resulted in a slight reduction in the average grain size of the as-cast and T6 heat-treated WE43B alloys and endowed them with increased corrosion resistance with little effect on their mechanical properties. 相似文献
4.
5.
穆肯德·R·帕特尔美 《科技咨询导报》2014,(30):17-19
近地空间环境(如热层、电离层)对空间系统的危害很大。航天器电源系统必须在从发射到寿命终结的整个任务阶段经受住空间环境的考验,达到各项性能指标要求。为达到此目的,空间研究机构如NASA等已对通用设计准则进行研究并形成了文件。太阳电池阵直接暴露在空间环境中,故极易损坏。事实上,多数情况下,太阳电池阵的损坏情况决定了航天器的寿命。 相似文献
6.
Biodiesel fuel is found to be a promising alter- native for the petroleum diesel based on the results published by the researchers for a decade. Biodiesel fuel is renewable and non degradable fuel. Many countries use biodiesel fuel for automotives to meet the crisis due to the depletion of the petroleum fuel and to meet the stringent emission norms. Various researches have been carried out with different bio- diesel fuels with vegetable oil as the source and appreciable results were reported. Few biodiesel fuels which have been already tested are Jatropha, Pongamia, Mahua, neem, cotton seed, etc. In this experimental work, Adelfa biodiesel blend is used as the test fuel. The emission and performance charac- teristics were compared with three other different biodiesel fuel blends. Appreciable results imply that Adelfa biodiesel (Nerium oil methyl ester) can be a futuristic biodiesel fuel, which has a good compatibility with the direct injection (DI) diesel engine without any major modification. Moreover, Adelfa can be cultivated in a non agricultural land with fewer sources of water. It is widely spread over all major countries of Asia. Experimental investigations have been carried out on a single cylinder DI diesel engine with standard engine speci- fications. In this experimental work, various Adelfa biodiesel blends is compared with reference fuel (diesel) to choose the best blend which gives a closer performance to diesel. The comparative analysis with other biodiesel fuels has also been done and results have been discussed. 相似文献
7.
Bjrn Winkler Alexandra Friedrich Wolfgang Morgenroth Eiken Hausshl Victor Milman Chris R. Stanek Kenneth J. Mc Clellan 《科学通报(英文版)》2014,(36):5278-5282
Single-crystal X-ray diffraction at pressures up to 50 GPa has been employed to study the compression behavior of Sm2Ti2O7-pyrochlore. In contrast to earlier reports, we observed no pressure-induced amorphization or pressure-induced anion disorder up to 50 GPa. The experimental study has been complemented by density functional theory-based calculations. A combination of the theoretical and experimental data yields a bulk modulus of 185 GPa, significantly higher than a value which had been reported earlier. In comparison to earlier work, the current study provides more reliable data due to the use of neon as a pressure medium, which provides a more hydrostatic pressure than the aluminum, which had been employed as a pressure medium in the earlier studies. An analysis of the compressibility of Al2B2O7 pyrochlores shows an approximately linear dependence of the bulk modulus on the unit cell volume. 相似文献
8.
梁学磊 李伟 CHENG GuangJun CALIZO Irene HACKER Christina A HIGHT WALKER Angela R RICHTER Curt A 彭练矛 《科学通报》2014,(33)
利用化学气象沉淀法(CVD)在金属衬底上生长的石墨烯制备电子器件需要先把石墨烯转移到绝缘基底上,转移过程对器件制备的成功率和性能的均匀性有重要影响.转移过程中导致的石墨烯破损和金属生长基底残余颗粒污染受到普遍重视,然而由金属基底腐蚀液导致的石墨烯表面污染还没有引起足够的重视.本文利用拉曼光谱和X射线光电子能谱(XPS)证明了转移过程中金属基底腐蚀液会在石墨烯表面引入污染,利用我们发展的"改良的RCA(radio corporation of America)清洗(modified RCA clean)"转移工艺能够有效地去除这种污染.这对提高后续制备的电子器件的性能有重要意义. 相似文献
9.
10.
采用超临界CO2气溶胶溶剂萃取法(ASES)制备了尤特奇S100(Eudragit S100)纳米粒,考察了有机溶剂的选择、压力、温度、溶液浓度及流速等主要工艺参数对Eudragit S100纳米粒形貌及粒径大小的影响,并采用扫描电镜、傅立叶红外光谱分析对结果进行了表征。结果表明,在以丙酮作为溶剂、压力为16 MPa、温度为45℃、溶液浓度为1 mg/m L的工艺条件下,可制备出有机溶剂残留少、分布均匀、平均粒径为30~60 nm的Eudragit S100纳米颗粒。纳米粒子的平均粒径随温度、压力的升高而减小,随溶液浓度的减小而减小。 相似文献