Structure design,controllable synthesis,and application of metalsemiconductor heterostructure nanoparticles

Metal-semiconductor heterostructure nanoparticles(NPs) have attracted much interest and extensively been investigated due to their promising potentials in the fields of catalysis,energy conversion and storage.Due to the synergistic effect and coupling effect between metal and semiconductor,designing and controlling the interface structure of metal-semiconductor NPs and understanding the structure-property relationship have great significance for optimizing their physicochemical performances.Metal NPs coupled with semiconductors forming several kinds of interface structures,including core-shell,yolk-shell,Janus and oligomer-like structures are summarized in this review.The controllable synthesis methods to obtain metal-semiconductor heterostructure NPs with fantastic properties are presented in detail.Moreover,the structure-property relationship and their applications in the fields of catalysis,energy conversion and storage are also exhibited.A brief outlook is given on the challenges and possible solutions in future development of metal-semiconductor NPs.     

有界复形的 Modi ed Ringel Hall 代数的结构常数

设k是有限域.A是k上的满足一定有限性条件的本质小的遗传阿贝尔范畴.本文研究了有界复形范畴的modified Ringel—Hall 代数MH(A)中零微分复形乘积的结构常数，给出了它们与A的Ringel-Hall 代数H(A)的Hall数之间的关系.     

Curcin和curcin C与腺嘌呤互作位点的比较分析

麻疯树核糖体失活蛋白curcin和curcin C均具有抗肿瘤活性，但后者的活性水平显著高于前者，为了探索造成这一差异的结构基础，本文采用在线的同源建模预测软件SWISSMODEL，对两种麻疯树核糖体失活蛋白curcin、curcin C的三维结构模型进行预测，采用SYBYL对预测模型进行能量最小化优化，采用PROCHECK、VERIFY 3D和ERRAT软件对优化前后的模型进行质量评估，随后采用AutoDock软件将预测的模型与腺嘌呤进行分子对接分析.结果显示，两种蛋白采用与Ricin A类似的方式与腺嘌呤相互作用，但在相互作用的氨基酸残基种类、数量以及形成的氢键和疏水相互作用上还是存在差异，其中，curcin C与腺嘌呤具有最强的结合能力，curcin则最低.     

Structure,scale and emergence

In this paper I consider the structures that chemists and physicists attribute at the molecular scale to substances and materials of various kinds, and how they relate to structures and processes at other scales. I argue that the structure of a substance is the set of properties and relations which are preserved across all the conditions in which it can be said to exist. In short, structure is abstraction. On the basis of this view, and using concrete examples, I argue that structures, and therefore the chemical substances and other materials to which they are essential, are emergent. Firstly, structures themselves are scale-dependent because they can only exist within certain physical conditions, and a single substance may have different structures at different scales (of length, time and energy). Secondly, the distinctness of both substances and structures is a scale-dependent relationship: above a certain point, two distinct possibilities may become one. Thirdly, the necessary conditions for composition, for both substances and molecular species, are scale-dependent. To know whether a group of nuclei and electrons form a molecule it is not enough to consider energy alone: one also has to know about their environment and the lifetime over which the group robustly hangs together.     

钢板-砼组合加固钢筋砼梁的研究及应用进展

钢板-混凝土组合加固技术是钢筋混凝土梁加固的一种的新方法.简介了目前关于钢板-混凝土组合加固梁抗弯和抗剪承载力研究的成果,分析考虑界面滑移、二次受力等因素对于承载能力影响的研究现状,探讨了该加固技术试验研究方法及工程应用情况.通过对现有研究成果的归纳和总结,分析了该技术的主要特点与不足,并指出了有关钢板-混凝土组合加固方面值得进一步研究的问题.     

圆柱正弦活齿传动接触力影响因素分析

基于弹性小变形和变形协调方程假设建立了理论状态下的啮合副接触力分析模型,利用牛顿法求解了力学方程。对圆柱正弦活齿传动结构分析,发现了4个主要结构参数,分析了这4个参数单独变化时,啮合副接触力大小和周期的变化规律;总结这些变化规律,归纳出在一定传动比的条件下,圆柱正弦活齿传动结构设计的一般设计准则。利用分析结果可以设计出结构比较优化的圆柱正弦活齿传动机构。     

通辽市开发区行道树的结构特征分析

行道树作为城市园林绿化的骨干,在创造优美的城市景观和改善城市生态环境中发挥着十分重要的作用.通过对通辽市开发区主要路段行道树进行调查,结果表明：通辽市开发区行道树共有园林树木9种,隶属6科7属.其中国槐重要值是37.98,其他树种重要值均不超过15.胸径20—30cm的树木最多,占总数的48.13%,处于10—20cm的树木占47.31%.平均树高为6.88m,高度处于4—7m之间的树木最多,占总数的49.02%.根据以上调查结果可知开发区行道树存在种类单一,常绿树种,观花、观果树种较少的问题.据此,提出了对策与建议.     

某通用小型汽油机箱体有限元分析及结构优化

该文运用有限元法对某通用小型汽油机箱体进行了结构强度与刚度分析，结果表明右箱体主轴承位置最大变形量过大，刚度较差。为此对右箱体主轴承区域进行拓扑优化。优化方式为：增加右箱体主轴承处加强筋数量、增加壁面厚度以及在壁面上添加加强条。通过计算表明，该优化方式能使箱体的最大应力与应变大大下降，使其强度刚度有了较大提升，箱体的结构更趋合理。     

Mechanisms functional underlying the characteristics structural and of acupoints

Acupoints are particular areas on the surface of the body through which the Qi and blood of the Zang-fu organs and meridians flow. Acupoints can respond to stimuli and reflect syndromes. Research on the essential morphology of acupoints has two key focuses： anatomical structure and physiological func- tion. The structure is the material and anatomical basis for the function, while the function is the manifes- tation of the structure. The two factors not only have profound significance for our understanding of the essence of acupoints, but also have great value for clinical acupuncture and moxibustion practice. Based on the structural and functional characteristics of meridians under different physiological and pathological con- ditions, this paper illustrates the essence of acupoints and explores the rules and biological basis of the acu- point functions induced by acupuncture and moxibustion.     

综放孤岛工作面顺槽超前支护选型研究

针对东山煤矿煤层赋存和开采条件,介绍了15号煤层51519综放孤岛工作面顺槽超前支护选型研究,确定采用传统的超前支护方式:即采用单体液压支柱加金属顶梁(或工字钢)进行超前支护,论述了不采用超前液压支架的原因,为孤岛工作面综放开采超前支护提出一些有益的建议。