单原子Co修饰TiO2(101)面的结构和析氢性能的第一性原理研究

通过基于密度泛函理论（DFT）+U的第一性原理方法研究了单原子Co在TiO₂（101）面的掺杂位置和方式、几何结构和整体能量以及掺杂后产物的制氢反应机制，得到了稳定且易出现的单原子修饰结构，即单原子Co吸附在4个O组成的表面空隙的中心位，记为Co/TiO₂（101）。进一步对Co/TiO₂（101）的析氢反应过程和性能进行研究，确定了当且仅当TiO₂（101）面完成表面羟基化反应后，H原子全覆盖的TiO₂（101）表面才能进行后续的析氢反应；此时单原子Co是唯一的反应位点，整体的制氢反应自由能ΔG_H*比Co（111）面更加趋近于0，显示出其具有远优于金属Co的催化性能。此外，Co和TiO₂间的电荷转移和相互作用使TiO₂带隙出现新的掺杂能级，可带来作为光催化基材的TiO₂光吸收性能的改善。     

粉末冶金法制备混杂增强铜基复合材料的增强体竞争析出行为研究

Copper matrix composites reinforced by in situ-formed hybrid titanium boride whiskers (TiB_w) and titanium diboride particles (TiB_2p) were fabricated by powder metallurgy. Microstructural observations showed competitive precipitation behavior between TiB_w and TiB_2p, where the relative contents of the two reinforcements varied with sintering temperature. Based on thermodynamic and kinetic assessments, the precipitation mechanisms of the hybrid reinforcements were discussed, and the formation of both TiB_w and TiB_2p from the local melting zone was thermodynamically favored. The precipitation kinetics were mainly controlled by a solid-state diffusion of B atoms. By forming a compact compound layer, in situ reactions were divided into two stages, where Zener growth and Dybkov growth prevailed, respectively. Accordingly, the competitive precipitation behavior was attributed to the transition of the growth model during the reaction process.     

贵州山核桃ISSR-PCR反应体系建立及优化

为建立贵州山核桃ISSR-PCR最佳反应体系,采用单因素试验的方法,对影响ISSR-PCR反应体系的模板DNA浓度、MgCl2浓度、d NTPs浓度、Taq酶用量、引物浓度等各因素进行了研究,确立了贵州山核桃ISSR-PCR的最佳反应体系。结果显示:最优反应体系的模板DNA浓度为40ng/u L、引物浓度为0.3umol/L、Mg2+的浓度2.9mmol/L、酶浓度0.3U、d NTPs浓度0.2mmol/L,退火温度为54℃。建立该反应体系可为贵州山核桃ISSR标记开发、物种分类鉴定、遗传图谱构建等后续分析奠定基础。     

气膜条件下车厢表面摩擦阻力计算理论研究

针对气膜条件下厢式运输车厢体表面摩擦阻力减小的实验结果,分别提出边界层加厚理论、混合降速理论、边界层加厚-混合降速理论3种理论来研究空气介质中空气膜的减阻机理,建立了气膜条件下厢式运输车厢体表面气流摩擦阻力计算模型,定性对比分析了厢体表面在有气膜和无气膜条件下各自所受到的气流摩擦阻力.结果表明,有气膜时摩擦阻力减小,这一结果与笔者前期的实验研究结果趋于一致,为气膜减阻在厢体表面减阻中的实际应用提供了理论基础.     

Synthesis of aluminum nitride in a coke-calcium reduction bed using nitrogen in air

An experimental study on the heating of a mixture of aluminum and lithium hydroxide (LiOH) powders in a reductive bed under air atmosphere is reported. The formation of aluminum nitride (AlN) during this process was the focus of this study. The formation of AlN was achieved using LiOH as an additive and heating the sample in a resistance furnace in a specially designed double crucible within a bed of a mixture of coke and filamentous calcium. The temperature range of the reaction was between 700°C and 1100°C. The optimum tem-perature of 1100°C and the optimum LiOH amount (5wt%) required to achieve maximum yield were determined by powder X-ray diffrac-tion (XRD) analysis. Scanning electron microscopy (SEM) micrographs clearly indicated the transformation of grain structures from rods (700°C) to cauliflower shapes (1100°C).     

基于图像欧氏距离流形降维的端元提取算法

由于多重反射和散射,高光谱图像中的混合像元实际上是非线性光谱混合传统的端元提取算法是以线性光谱混合模型为基础,因此提取精度不高针对高光谱图像的非线性结构.本文提出了基于图像欧氏距离非线性降维的高光谱遥感图像端元提取方法该方法结合高光谱数据的物理特性,将图像欧氏距离引入局部切空间排列进行非线性降维以更好的去除高光谱数据集中冗余的空间信息和光谱维度信息,然后对降维后的数据利用寻找最大单形体体积的方法提取端元.真实高光谱数据实验表明,提出方法对高光谱图像端元提取具有良好的效果,性能优于线性降维的主成分分析算法和原始的局部切空间排列算法.     

不同主导力量下供应商减排投资的谎报与协调策略

在碳交易政策下的两级低碳供应链中，针对供应商可能利用私有成本信息增加自身利润损害零售商和供应链绩效的问题，探讨供应商投资减排后不同主导力量下供应商的成本信息谎报行为和供应链协调策略。研究发现，供应链主导力量对供应链利润在供应链成员间的分配、供应链的整体绩效和供应商的最优成本谎报策略均有影响。供应商主导型供应链中，供应商不会谎报其成本信息；零售商主导型供应链中，供应商在一定条件下会采取相应的谎报策略以使自身利润最大化，影响减排量、低碳产品零售价格以及零售商和供应链的绩效等。因此，设计一种固定减排量下依赖于批发价格的线性补贴惩罚机制进行协调。在合适的契约参数设置下，此机制在激励供应商反馈真实成本信息的同时能够实现低碳供应链的完美协调，且能将供应链利润在零售商和供应商之间进行自由划分。最后，通过数值分析对结论进行验证并探讨了谎报因子与零售商和供应商利润的关系。     

‘Revolutions,philosophical as well as civil’: French chemistry and American science in Samuel Latham Mitchill’s Medical Repository

ABSTRACT

From 1797 to 1801 a controversy played out on the pages of the Medical Repository, the first scientific journal published in the United States. At its centre was the well-known feud between the followers of Antoine Lavoisier and Joseph Priestley, the lone supporter of the phlogiston model. The American debate, however, had more than two sides. The Americans chemists, Samuel Latham Mitchill and Benjamin Woodhouse, who rushed to support Priestley did not defend his scientific views. Rather, as citizens of a republic, they defended his right to have them. They also castigated the assertions of the “French chemists,” whose claims that the new chemistry obviated debate seemed unsettlingly similar to the dictatorial ambitions of the French state. Using the Medical Repository, Mitchill and Woodhouse sought a compromise that validated the new chemistry, but united it with a more egalitarian form of discourse. The desired balance eluded them. Priestley proved too stubborn, and as the French Revolution descended into dictatorship and war, Mitchill and Woodhouse came more to realize that truly prising French chemistry from the culture of the revolutionary era. The episode left Mitchill and Woodhouse disillusioned with chemistry and hoping to redirect scientific enthusiasm to more pious ends.     

振动引起的界面切向相对运动对摩擦的影响

为了研究接触界面振动对摩擦的影响, 自主设计实验装置, 以在振动台上匀速滑动的滑块为对象, 采用理论与实验相结合的方法, 分析法向振动和切向振动引起界面切向运动减摩的机理。实验结果表明, 振动台的法向振动和切向振动经常同时存在。当界面振动, 且滑块与振动台之间的切向相对速度方向不变时, 滑块受到的平均滑动摩擦力与无振动时相同, 没有减摩作用; 当滑块与振动台之间切向相对速度的方向发生周期性变化或存在stick-slip (黏滑)时, 与无振动时相比, 滑块的平均滑动摩擦力有明显的减摩作用。根据Coulomb摩擦定律建立动力学模型进行仿真, 仿真结果与实验结果非常吻合, 说明在界面运动为已知的条件下, Coulomb摩擦模型能够反映界面间的摩擦作用。实验和仿真结果表明, 当法向振动和切向振动同时存在时, 振动引起的界面切向相对运动造成摩擦力方向的周期性变化或stick-slip是减摩的主要原因。     

现阶段我国工业产能过剩及去产能的形势分析

本文考察了现阶段我国工业产能过剩以及去产能的形势,指出产能利用率持续偏低、生产者价格指数持续为负和行业盈利持续下降是现阶段产能过剩的主要表现,然而当前通过减产量、去产能来化解产能过剩的政策效果并不明显,这主要是因为受地方政府干预过多、企业陷入"囚徒困境"和威胁经济社会稳定等因素的制约。政府应深化和落实地方官员政绩考核体制、生产要素定价机制等的改革,减少地方政府对经济的不当干预,发挥市场在资源配置中的决定性作用,实现企业优胜劣汰,同时应建立产能退出补偿机制,避免引发社会动荡。