高锰酸钾热分解历程研究

本文用DTA技术结合常规分析得出高锰酸钾的热分解历程为:生成的MnO_2可和K_2O·3MnO_2形成新的亚锰酸盐。本文还找出了一种鉴别+6、+5价可溶性锰酸盐的方法。     

合成结构纤维对混凝土力学性能的影响

采用长度分别为4.7,5.6和6.5cm的合成结构纤维,均以5kg·m-3的掺量配制C40混凝土,通过维勃稠度、抗压强度、方板和圆板弯曲韧性、混凝土梁和切口梁弯曲韧性等试验,分析了其对混凝土工作性能和力学性能的作用规律与特征,同时与素混凝土以及同体积掺量(40kg·m-3)的钢纤维混凝土进行对比.结果显示,合成纤维的加入降低了混凝土的流动性、抗压强度和混凝土梁的抗弯强度,其长度越长则降低抗压强度及抗弯强度的程度越高;合成纤维对混凝土方板或圆板的初始断裂强度影响不大,但可明显提高断裂能,其作用高于同体积掺量的钢纤维,并且中等长度(5.6cm)的合成纤维增加混凝土断裂能的作用最大;合成结构纤维混凝土的应力-挠度曲线在其下降过程中呈现一个"平台段",虽然平台高度不及钢纤维混凝土的,但其长度明显更长,这是由合成结构纤维的材质特征决定的.     

不同钝化介质层对AlGaN/GaN异质结二维电子气密度的影响

试验用高分辨率X射线衍射仪(HRXRD)测定了不同介质层钝化后异质结势垒层AlGaN的附加应变,用范德堡霍尔效应测量法测定了不同介质层钝化后异质结二维电子气密度,发现AlN钝化层尽管给势垒层带来附加的压应变.但依然使二维电子气密度增大,借此讨论了钝化对势垒层表面态产生的影响,分析了钝化机制.     

过渡元素价态共价半径及其新价态电负性的计算和应用(Ⅳ)

提出了计算过渡元素价态共价半径的公式;提出了计算过渡元素新价态电负性和化学键的离子性的方法。     

苯并色烯类化合物合成方法的探讨

 以取代苯甲醛、丙二腈和2-萘酚（或2,7-萘二酚）为原料合成出了3-氨基-2-氰基-1-(4-取代苯基)-1H-苯并［f］色烯类物质,后者在冰醋酸或者醋酸钠催化作用下,乙酸酐中回流,合成出苯并色烯并嘧啶类化合物。这类化合物的关环反应条件易于实施,后处理简单,易于纯化,属于首次报道。     

微电机噪声信号的小波包分析与故障检测

电机运转噪声中包含了电机状态的信息,分析了微电机的噪声源及噪声信号特征,基于最优小波包基和Donoho软阈值消噪方法对一组微电机标准信号和故障信号进行了消噪处理,比较低频信号成分的功率谱得出故障特征频率,从而确定电机故障,结果表明该方法能有效实现对电机的故障检测.     

Grafting of 2-Hydroxyethyl Methacrylate onto Silk by Atom Transfer Radical Polymerization

Silk was grafted using 2-hydroxyethyl methacrylate(HEMA)by atom transfer radical polymerization(ATRP)method.The amino groups and hydroxyl groups on the side chains of the silk fibroin was reacted with 2-bromoisobutyryl bromide(BriB-Br)to obtain efficient macroinitiator for ATRP.And the macroinitiator was grafted with HEMA in water aqueous using CuBr/N,N,N',N,N-pentamethyldiethylenetriamine(PMDETA)as catalyst system.The effects of monomer concentration,the proportion of CuBr and PMDETA,grafting temperature a...     

Influence of Thermal Treatment on the Structure and Thermal Properties of Kaolin Modified Polyester Fibers

Modified polyester fibers were obtained using 2% and 6% of kaolin blends through melt spinning.The influences of two thermal treatments maintaining the original tension(180 ℃×2 min and 200 ℃×1 min)on the structure and properties of fiber were compared.The changes of grain size and crystallinity of fiber were investigated by X-ray diffraction(XRD).The changes of thermal properties of fibers were analyzed using dynamic mechanical analyzer(DMA).The results show that the crystalline structure of kaolin modified polyester fiber doesn't change with the thermal treatment.With the kaolin content increasing,the grain size of fiber changed.The higher the thermal treatment temperature is,the higher the crystallinity of fiber is.There are two glass-transition temperatures for kaolin modified:the lower one is the glass-transition temperature of polyester fiber matrix,and the higher one is derived from the heterogeneous blend of polyester matrix and nano kaolin.The higher the kaolin content is,the higher the glass-transition temperature is.Thermal treatment could increase the compatibility of polyester matrix and nano kaolin.There was only one glass-transition temperature for the thermal treatment fiber,and the heat resistance of fiber was improved.Thermogravimetric analysis-differential scanning calorimetry(TGA-DSC)results of kaolin modified polyethylene terephthalate(PET)matrix indicate that the decomposition temperature of PET fibers,kaolin modified PET fibers,and thermal treated fibers were little different within 40%-60% of weight loss rate range.     

基于测量机器人的工业机器人校准方法研究

在对高精度测量机器人、激光跟踪测量系统进行全面分析与系统研究的基础上,提出运用工业机器人与测量机器人对接,工业机器人带动测量机器人在整个工业机器人工作空间进行自动测量的方法.给出了工业机器人带动测量机器人联动测量的结构图和工业机器人空问误差的检测与补偿的流程图,为研究工业机器人末端误差测量提供新的理论与技术支持.