长江、黄河沉积物中碳酸盐组成及差异

利用显微镜观察、X射线物相分析、容量法等方法分析了长江、黄河沉积物中碳酸盐组分，结果表明长江沉积物碳酸盐含量在4%～8%之间，碳酸盐含量随粒级呈衰变型分布，在<0.125mm的粒级中碳酸盐含量稳定于3%～5%左右；黄河沉积物中碳酸盐含量在8%～18%之间，碳酸盐含量随粒级呈不对称鞍型分布，在<0.045mm的粒级中碳酸盐含量明显增高，达12%以上．长江、黄河中的碳酸盐含生物碎屑和碎屑碳酸盐两种成因类型，生物碎屑多属文石质，主要分布于>0.125mm的粒级之中；碎屑碳酸盐以低镁方解石占优势，长江以单晶方解石为主，黄河以隐晶质方解石集合体为主．长江、黄河沉积物中碳酸盐组成及差别主要受流域的风化条件、物源及生态环境的制约．     

基于计算流体力学的熔盐燃料电池电堆的仿真

基于计算流体力学技术，建立并仿真了10kW级顺流型熔融碳酸盐燃料电池（MCFC）电堆的三维模型，对电堆内部的物质、动量和能量守恒过程进行了理论分析，模型考虑了MCFC电堆的一个重要组成部分-波状板，并讨论了波状板尺寸对电堆性能的影响，结果表明，在采用较大尺寸波状板的电堆中，电化学反应进行得更加充分，所建模型对电堆内部流场的设计有一定意义。     

硫铁矿中铊的相态分析

分析了云浮硫铁矿中微量铊的相态分布，包括可交换相，碳酸盐结合相，铁锰氧化物结合相，有机质及硫化物结合相，硅酸盐结合相等相态。实验表明，对云浮硫铁矿中微量铊的相态研究，为资源开发利用中的铊污染提供了基础科学数据。     

鄂尔多斯盆地早奥陶世沉积特征及其演化

鄂尔多斯盆地的早奥陶世沉积可划分为西缘末端变陡的碳酸盐岩缓坡、东缘蒸发-局限台地和南缘镶边碳酸盐岩台地3个沉积区。岩相古地理的发展可划分为3个阶段,即冶理—亮甲山期为稳定的发展阶段,早、晚马家沟期为岩相分异阶段,峰峰期为中奥陶世陆源浊积盆地这一新的发展阶段的前奏。其演化具有东升西降的特点,东部沉积区的沉积相演化为一个向上变浅的沉积序列,而西部为一个向上变深的沉积序列。     

广西泥盆系弗拉阶-法门阶之交分子地层研究

运用GC-MS分析仪对23件样品的检测结果显示:广西泥盆系弗拉阶-法门阶(F/F)之交分子化石主要由正构烷烃、类异戊二烯烃、萜类、甾类构成,其先体主要为海源浮游植物、浮游动物、底栖非光合作用的菌类和陆源高等植物,其中浮游植物和浮游动物是构成F/F事件期台盆碳酸盐相生物量的主体;n Pr /n Ph <1(Ph为植烷,Pr为姥鲛烷)或♂1、n ph /n C 18 值较高、C 16 ～C24 具有明显的偶碳优势表明,F/F之交广西为蒸发量、盐度和缺氧程度较高的海相碳酸盐环境.F/F之交生物集群绝灭是中泥盆世晚期以来环境不断恶化的结果,多次天体撞击对晚泥盆世不断恶化的生态系无异于雪上加霜;高温导致的高蒸发量、较高盐度和水柱底层缺氧是低纬度礁生态系、浅水海相生物集群绝灭的最直接杀手.     

Diet control on carbon isotopic composition of land snail shell carbonate

Carbon isotope compositions for both the carbonate shells and soft bodies (organic tissue) of living land snails collected mostly from the Loess Plateau, China have been measured. The result shows that δ 13C values range from -13.1‰ to -4.3‰ for the aragonite shell samples and from -26.8‰ to -18.0‰ for the soft body samples. Although the shells are enriched in 13C relative to the bodies averagely by 14.2(±0.8)‰, the shell δ 13Ca values are closely correlated to the body δ 13Corg values, expressed as δ 13Ca = 1.021 δ 13Corg 14.38 (R = 0.965; N = 31). This relationship indicates that δ 13Ca is primarily a function of the isotopic composition of the snail diets since previous studies have proved that the snail body is the same as their food in carbon isotope composition. In other words, carbon isotope compo-sition of the carbonate shell can be used as a proxy to estimate the dietary 13C abundance of the land snails. The data also support that the 13C enrichment of the carbonate shells results mainly from the equilibrium fractionations between the metabolic CO2, HCO3-in the hemolymph and shell aragonite, and partially from kinetic fractionations when snail shells form during their activity.     

掺镱硼酸盐和磷酸盐玻璃光谱性质的成分依赖性

了玻璃成分对掺镱硼酸盐和磷酸盐玻璃光谱性质的影响。结果表明，其变化规律与Ｎｄ＾３＋离子在相应基质中的变化规律相似，即在网络骨架结构为主的硼卤玻璃中，随着饰体阳离子场强增加或高价阳离子的引入，吸收截面和发射截面升高。与此相反，磷酸盐玻璃由于链状结构的特点，随着修饰体阳离子场强升高，吸收截面和发射截面降低。两种玻璃中，硼酸盐玻璃有较高的发射截面，其发射截面高于目前发展中的掺Ｙｂ＾３＋激光玻璃，磷酸盐玻     

氯化铵溶液碳化过程中的萃取平衡

研究了氯化镓溶液碳化过程中叔胺对ＨＣｌ的萃取平衡，测算出了不同配比下的萃取平衡常数。实验证明，当有机相中叔胺的相对用量减少时，萃取平衡常数增大；在相比机的情况下的实验所测的三种配比中以配比为１：１时的萃取率为最高。     

Fundamental geological elements for the occurrence of Chinese marine oil and gas accumulations

The Paleozoic strata in the Tarim Basin, Sichuan Basin and Ordos Basin are the major targets for marine petroleum exploration, with developed high quality hydrocarbon, mainly argillite. The deep burial of these source rocks suggests that they mainly develop gas instead of oil. But different maturities of organic matter may lead to different hydrocarbon facies. Through thermochemical sulfate reduction （TSR）, the hydrocarbon in the carbonate rocks may undergo a process of pyrolytic cracking and be catalyzed into gases. The marine reservoirs mainly consist of carbonate and clastic rocks, and the former is controlled by sedimentary facies, dolomitization, solution, TSR and cracking. The multiphase tectonic cycling develops multiple source-reservoir-cap combinations and diversified types of traps and reservoirs, featuring multiphase reservoir formation, mainly late-phase formation or consolidation. Palaeo-uplifts play a controlling role in hydrocarbon accumulation. Differences in major source rocks in the three basins lead to different locations of oil-gas accumulation layers, different types and patterns of reservoirs and different features of reservoir formation.