关于上海股市指数日收益尾部的实证研究

基于极值理论（EVT）方法,利用平均超出量函数,结合判断阈值u改变引起参数估计量的变化,找出合适的阈值,建立了上海股市综合指数极端日收益率的广义帕累托模型（GPD）。     

A multiple-labelling method for cells using Au nanoparticles with different shapes

An important and difficult issue is simultaneously identifying the detailed locations of various molecules on the cell surface, as this identification requires a synergistic effect between more than one molecule in a living cell. Au nanoparticles (NPs) with different shapes can be readily recognised under low vacuum scanning electron microscopy (lvSEM). Anisotropic Au nanorods (NRs) possess unique surface plasmon resonance (SPR) properties, which can be further utilised for two photon luminescence (TPL) and other optical imaging techniques. In this paper, Au NRs and Au nanooctahedra (Au NOs) are introduced as biomarkers for ICAM-1 and Integrin β1. Combined with the advantages of lvSEM, this multiple-labelling method is a new method for studying the interactions between specific, functional molecules.     

Ionic liquids as green reaction media for synthesis of poly(aryl ether ketone)s

Poly(aryl ether ketone)s (PAEKs) were successfully synthesized via nucleophilic aromatic substitution (SNAR) mechanism, using ionic liquids as green reaction media. The influence of various reaction parameters including monomer concentration, dehydration time, polymerization temperature and duration, IL’s cations and anions nature, upon PAEKs molecular weight was investigated. In addition, the peculiarities of hydrogen-bonding ability of ILs were investigated. The interaction of 2,2-bis(4-hydroxyphenyl) propane (bisphenol A) with ILs has a strong influence on PAEKs synthesis. Various moderate molecular weight PAEKs have been obtained in high yields with molecular weights ranging from 10000 to 18000g mol-1.     

The radiolytic behavior and mechanism of calixarene crown ether under γ-irradiation

Bis(2-propyloxy)calix[4]crown-6 (BPC6) is an effective separation agent for cesium removing from spent nuclear fuel. The study on radiolytic behavior of BPC6 itself under γ-irradiation was required for evaluating its feasibility of practical application. It was found that BPC6 exhibited excellent radiation stability at dose less than 100 kGy. However, the isopropyl groups in BPC6 under- went oxidation and dealkylation to form carbonyl groups and phenolic hydroxyl groups at dose above 300 kGy, respectively. When the dose was more than 1000 kGy, the ring opening of crown ether structure of BPC6 resulted in the formation of phenolic hydroxyl groups as well. The formation of radiolytic products containing phenolic hydroxyl groups during the irradiation of BPC was confirmed by using FeCl 3 as a probe. Combining with the radiolytic behavior of two model chemicals (1-isopropoxybenzene and benzo-18-crown-6 ether), the radiolytic behavior and mechanism of BPC6 under -irradiation was testified further.     

Hierarchical power control for OFDM based LTE system

3 GPP LTE has approved uplink intra-cell power control and defined overload indicator （OI） for uplink inter-cell power contrQ1 to mitigate the inter-cell interference （ICI）, respectively. In this pa- per, we propose a hierarchical power control （ HPC ） scheme where intra-eell and inter-cell power controls interact with each other. The inter-cell power control eommand is generated by radio re- source management （RRM） entity according to the ICI-load model together with the current ICI and served load information. This ICI-load model is proposed as a guideline for coordination among cells to enable the system to approach its system specific interference over thermal noise （IoT） work area. Simulation results show that for HPC scheme, the system＇ s IoT is well controlled to fit its pre-de- fined work area and the power efficiency is improved significantly. Our proposed scheme is also ro- bust to different settings of its inter-cell power control period.     

Comparison between PCA and KPCA methods in comprehensive evaluation of robotic kinematic dexterity

Due to the correlation and diversity of robotic kinematic dexterity indexes, the principal component analysis （PCA） and kernel principal component analysis （KPCA） based on linear dimension reduction and nonlinear dimension reduction principle could be respectively introduced into comprehensive kinematic dexterity performance evaluation of space 3R robot of different tasks. By comparing different dimension reduction effects, the KPCA method could deal more effectively with the nonlinear relationship among different single kinematic dexterity indexes, and its calculation result is more reasonable for containing more comprehensive information. KPCA＇ s calculation provides scientific basis for optimum order of robotic tasks, and furthermore a new optimization method for robotic task selection is proposed based on various performance indexes.     

Development of emergency water quality standard for Cr6+ and Hg2+ in Liao River basin

The acute toxicity data of Cr＋ and Hg2＋ to the aquatic organisms in Liao River basin was collected and screened. Calculated results of criteria values using popular species sensitivity distribution （SSD） methods were evaluated through data analysis. The comprehensive methodology of emergency water quality standards （EWQSs） was established on the basis of the SSD method of Australia and New Zealand according to the evalu- ation results. The affected fractions of the aquatic organisms were set to be 5 %, 15 %, 30 % and 50 %, corre- sponding to the risk grades of Ⅰ,Ⅱ,Ⅲ and IV, and four-grade EWQSs, respectively. The EWQSs for Cr6＋ and Hg2. in the Liao River were derived and the corresponding risk indicators were also proposed. The results showed that the four-grade EWQSs for Cr6＋ were 2.85 μg/L, 21.0 μg/L, 161 μg/L and 797 μ/L, respec- tively, and the risk indicators were daphnia （grade Ⅱ ）, shrimp （grade Ⅲ）, and the bighead fish or tadpole （grade IV）. The four-grade EWQSs for Hg2＋ were 0.59 μg/L, 2.32 μg/L, 6.25 μg/L and 15.6 μg/L, respective- ly, and the risk indicators were crucian carp or daphnia （grade Ⅱ）, shrimp （grade Ⅲ）, and worm or crab （grade IV）. The results provided valuable information for the risk analysis of sudden ambient water environmen- tal pollution accident.     

基于ADAMS.LifeMOD的人体头颈部动力学仿真与验证

基于多刚体动力学软件ADAMS和生物力学仿真软件LifeMOD,建立了一个人体头颈部三维多刚体动力学模型。该模型包括颅骨、颈椎骨、肩胛骨、躯干上段以及体现粘弹性性质的肌肉组织。采用美国海军力学实验室的前碰撞志愿者实验数据对模型进行了验证。验证结果表明,该模型具有很好的可信度,可以用来研究在碰撞条件下头颈部的动力学响应特性。     

统计不相关最佳鉴别矢量集的本质研究

Until recently the hydrogen molecule structural parameters are calculated with the methods of quantum mechanics. To achieve results close to experimental values, the wave function used is complicated and has no clear physical meaning. Because the distribution of the electron probability density is a statistical rule, the macro-time has actually been used in the concept on a electron cloud graph. Here are obtained three formulas with a classical mechanics method on the bond-length re , bond-energy De and force constant k of the ground state hydrogen molecule, which have a clear physical meaning but no artificial parameters, and compared with experimental values, the relative errors are respectively less than 1% , 2% and 4% .