溶剂萃取柠檬酸的传质研究

研究了用三辛胺溶剂分别从纯溶液和发酵液中萃取柠檬酸过程的传质规律与液滴粒径,无因次柱高及有机相配比对传质系数的影响,建立了液滴自由上升阶段的传质模型,并用以关联实验结果。     

一种改进的树形矢量量化编码算法

矢量量化中的一个最严重的问题是在一本码本中搜索最近码字的高计算复杂度。本文在研究树形矢量量化的基础上提出了一种改进的树形矢量量化编码算法。实验结果表明,本文提出的编码算法相对于树形矢量量化算法可大大改善峰值信噪比（ＰＳＮＲ）。     

L—统计量的非一致性收敛速度

本文研究了高阶矩条件下L—统计量的非一致性收敛速度,得到了与独立和类似的收敛速度。     

2-(1-萘甲基)-3(2-四氢呋喃基)丙酸N,N-二乙氨基乙酯草酸盐的新法合成

改进２－（１－萘甲基）－３－（２－四氢呋喃基）丙酸Ｎ,Ｎ－二乙氨基乙酯草酸盐（Ⅵ）合成方法．方法在１－氯甲基萘和四氢糠基丙二酸二乙酯（Ⅰ）的烷基化反应中使用ＮａＨ／ＤＭＦ为催化剂;在２－（１－萘甲基）－３－（２－四氢呋喃基）丙酸（Ⅳ）与２－氯乙基－Ｎ,Ｎ－二乙基胺的酯化反应中加入相转移催化剂;在２－（１－萘甲基）－３－（２－四氢呋基）丙酸Ｎ,Ｎ二乙氨基乙酯（Ⅴ）与草酸成盐中,直接使用二水合草酸替代脱水草酸．结果烷基化反应产率提高到７５％,反应时间缩短到２ｈ;酯化反应产率从文献报道的７２％提高到９２％;二水合草酸成盐效果与脱水草酸相同．结论该方法较已有的合成方法产率有较大提高且操作简便,有较好的工业化前景．     

静电像管均方根半径的计算及像质评价

探讨在电子光学成像系统中像评定的一种途径。方法,从静电这像差均方根理论出发,追迹计算大量空间轨迹的落点及系统均根半径,并由此衍算成弦财制传递函数。     

活菌制剂对雏鸡白痢沙门氏菌的体外拮抗及预防效果试验

从健康鸡的新鲜粪便中分离到乳酸杆菌和粪链球菌,佐以地衣芽孢杆菌,按不同比例制成活菌制剂。比较其对雏鸡白痢沙门氏菌的体外拮抗作用。结果表明,复合菌的组合适宜,对雏鸡白痢沙门氏菌的生长有很强的抑制作用。用此复合菌培养物预防人工感染的雏鸡白痢病,其预防保护率为８５％。     

谐振腔镜对高斯光束远场发散角的影响

利用变换矩阵和ＡＢＣＤ定律讨论了激光谐振空对高我束的变换,推导出高斯光束参数通过光腔输出镜的变换公式。并对热透镜腔,光束远场发散角等问题进行了讨论。     

盐胁迫下灰绿藜叶片光合特性与叶绿体离子调节的研究

ＮａＣｌ处理后,灰绿藜整个叶片内Ｎ＾＋ａ和Ｃｌ＆－积累,但叶绿体内仅少量增加。叶绿体与叶片的Ｋ＾＋浓度都降低。     

The v-v energy transfer of highly vibrationally excited states (I)

The relaxation of the highly vibrationally excited CO (v = 1–8) by CO₂ is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr₃ with O₂ generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO₂ molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (10¹⁴ cm³ · molecule⁻¹ · s⁻¹), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO². For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u³ mode of CO² For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u¹ mode of CO².     

The v-v energy transfer of highly vibrationally excited states (II)

The vibrational energy transfer from highly vibrationally excited CO to H₂O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser photolysis of CHBr₃ and O₂ the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H₂O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for CO(v)/H₂O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (10¹³cm³ · molecule^-1· s^-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H₂O is suggested.