改进的节点电路分析法

在节点分析法的基础上,用标准支路和纯电流源相结合,对大规模电路的计算方法进行了分析。     

油气雾化技术在钛合金加工中应用研究

为了提高金刚石刀具切削钛合金零件的表面加工质量,减轻金刚石刀具的磨损,提出一种以二氧化碳、水及植物油雾化后的雾状混合物作为冷却介质的加工技术.冷却介质经研制的油气雾化装置喷淋到切削区,达到冷却、润滑及保护金刚石刀具的目的.对比实验表明,利用油气雾化技术,二氧化碳气体能够更充分地接触加工表面,使工件加工表面中微量铁原子直...     

纳米YAG粉体的制备与表征

以Y(NO3)3·6H2O、Al( NO3)3·9H2O、Nd(NO3)3·6H2O、NH4HCO3为原料,以乙醇为分散剂,采用共沉淀法制备Nd:YAG前躯体,将前躯体在不同温度下煅烧得到Nd:YAG粉体.分别采用红外光谱仪(FT-IR)、热重/差热分析仪(TG/DSC)、X射线衍射仪(XRD)、透射电子显微镜(TEM...     

锌掺杂二氧化钛对含酚废水的降解作用的研究

以钛酸四丁酯为主要原料,氯化锌溶液为掺杂剂,采用超声分散法制备了含锌的二氧化钛光催化剂.并采用X射线衍射(XRD),透射电镜(TEM)对产品进行了表征.同时研究了不同影响因素对苯酚去除率的影响.结果表明,焙烧温度为500℃,锌掺杂量r(Zn∶Ti)=0.01,催化剂的最佳投加量为2 g/L光催化性最好.     

低价钛试剂促进下苯并咪唑并[1,2-c]喹唑啉衍生物的合成

在低价钛试剂促进下,以2-（2-硝基苯基）苯并咪唑和碳酸二三氯甲酯为原料,经过串联还原偶联反应,一步合成了一系列苯并咪唑并[1,2-c]喹唑啉-6（5 H）-酮衍生物.产物结构通过红外光谱、核磁共振氢谱和元素分析确证.     

Preparation, structure, and properties of polyurethane foams modified by nanoscale titanium dioxide with three different dimensions

TiO2-based nanosheets (TiNSs), TiO2-based nanotubes (TiNTs) were prepared by hydrothermal processing, and polyurethane foams with TiO2 nanopowders (P25), TiNSs and TiNTs were synthesized by free-rising foaming method. The Fourier-transform infrared (FT-IR) spectra show that the addition of titanium dioxide does not affect the chemical structure of polyurethane foam. However, microscope observations show that PU/TiNSs composite foams have more uniform cells and the average aperture smaller than that of pure poly-urethane foams. According to the results of thermal analysis, the PU/TiNSs composite foams have better thermal stability, the temperature of decompostion occurring with a maximum weight loss rate is about 30 ℃ higher than that of pure PU foams. The decompostion temperatures are 167 ℃ and 148 ℃ for the PU/P25 composite foams and the PU/TiNTs composite foams respectively, which are lower than that of pure PU foams. Moreover, with the addition of the fillers, the sound absorption property also has changed; the addition of TiNSs improved the sound absorbing property efficiently. The better thermal stability and sound absorption of PU/TiNSs composite foams are mainly due to the uniform cells diffuse and smaller aperture.     

铁素体基Ti-Mo微合金钢超细碳化物析出规律

利用光学显微镜、透射电镜和能谱分析等方法对两种不同Ti含量的铁素体基Ti--Mo微合金钢中析出相的尺寸、分布特征、析出规律和成分进行了研究.结果表明:钢中绝大多数析出相为超细碳化物,尺寸小于10 nm,析出相尺寸呈正态分布.随着Ti质量分数由0.072%增到0.092%,析出粒子平均尺寸增大,分布峰值向粒子尺寸增大的方向移动.Ti--Mo微合金钢具有栅格状的相间析出方式,栅格间距受冷速的影响较大,晶内和靠近晶界处的栅格间距不同.能谱分析发现,不同尺寸的粒子Mo含量不同,较大颗粒(50 nm左右)析出相中不含Mo,小颗粒(20 nm)中碳化物是Ti和Mo的复合析出相,且随着粒子尺寸的减小,成分中Mo所占比重增大.     

Density and structure of undercooled liquid titanium

For liquid Ti, it is difficult to achieve high undercooling because of its chemical reactivity; as a result, there is little information available on its properties and structure in the undercooled state. In this study, we investigate the density and structure, using molecular dynamics method, for the undercooling and superheating ranges 0-743 K and 0-457 K. The density increases quadratically for undercooling. At the melting temperature, the density is 4.14 g/cm3, and first and second temperature coefficients are obtained. The pair correlation functions and coordination numbers indicate that the short range degree of order becomes increasingly significant with increasing undercooling.     

烷氧基钛水解制备TiO_2超细粒子 Ⅱ.水解反应动力学及粒子形成

测定了烷氧基钛水解成核的诱导时间,研究了水解反应形成TiO_2超细粒子的机理,及溶剂和反应底物对水解反应机理的影响规律。导出了丁氧基钛在醇溶剂中的水解反应速率方程与对应的水解和聚结反应历程该机理同实验结果相吻合。     

金属有机化合物化学气相淀积含钛硬质涂层的过程研究

在垂直冷壁CVD反应器中进行了文题的探索性研究。以二乙胺基钛(Ti(NEt_2)_4)为源,在不锈钢或硬质合金基体上完成了氮化钛(TiN)和碳氮化钛(Ti(C,N))硬质薄膜低温下的淀积。发现(TiN)和(Ti(C,N))分别在773K和973K下形成;在操作范围内整个反应器流场由自由对流控制;反应过程由表面过程控制;反应活化能为235 kJ/mol;二乙胺基钛反应级数为1级。进行了热力学计算,提出了反应历程假设。结果表明:用二乙胺基钛进行MOCVD淀积含钛硬质薄膜可以降低温度,以扩大基体的选用范围,为获得硬质薄膜提供了一条新的途径。