Film Morphology, Emulsification of Dodecyl/Carboxyl Modified Polysiloxane and Its Application Performance on Cotton Fabrics

The film morphology of dodecyl/carboxyl modified polysiioxane (RCAS) on cotton fabric or the silicon wafer was investigated and characterized by field emission scanning electron microscopy ( FESEM ),atomic force microscope ( AFM ),and Fourier transform infrared spectrometer (FTIR).Experimental results indicate that RCAS is a good film forming material on different substrates.Relatively smooth film was formed on cotton fabric surface,on which the grooves disappeared.In addition,RCAS formed a micromorphology inhomogeneous and unsmooth film on the silicon wafer.Many high or low bright peaks distributed randomly on the film surface,especially as the field was 2μm ×2 μmand the date scale was 5 nm in AFM observation.Then RCAS was emulsified with nonionic surfactant alkyl polyoxyethylene ether in order to achieve a transparent organosilicon emulsion-RCAS emulsion ( RCSE),which possessed good stability.The properties of RCSE and its application performance on cotton fabrics were investigated and characterized by transmission electron microscope (TEM),particle size analysis,and voltage test instrument.The results show that the average particle size of RCAS emulsion is 28.32 nm,while the ζ voltage is - 37.88 mV.Compared with untreatd cotton fabric,the.softness of treated fabric can be improved with RCSE to a certain extent.At the.same time,the fabric treated with RCSE acquires unique fluffy and soft handle.     

水立方薄膜(ETFE膜)导热系数的测定

大学生创新实验项目是我国高等教育培养当代大学生创新能力的一项重要举措,它旨在培养大学生的创新意识和动手能力。上海工程技术大学对申请到的大学生创新实验项目"水立方薄膜(ETFE膜)热传导特性的研究"做了深入探讨,利用稳态法测得了ETFE膜的导热系数,发现其值小于0.23W/m.℃,可以作为理想的绝热材料应用在建筑等领域,有效地节省电能,符合当前的绿色经济的要求。     

珠江口盆地白云凹陷珠海组碎屑岩储层特征及成因机制

通过岩石铸体薄片、粒度分析和压汞分析等手段,分析白云凹陷珠海组储层的岩石学特征和物性演化特征,研究沉积环境和成岩演化过程对储层特征的影响机制。研究结果表明:储层主要以长石质石英砂岩和长石岩屑质石英砂岩为主,颗粒支撑并以碳酸盐、自生石英和黏土矿物接触式胶结。储层物性总体具有中低孔中低渗特征,以粒间溶蚀扩大孔为主,其次为珠海组底部黏土膜保护的原生孔隙,分选好的中-粗喉型喉道使孔隙连通性良好;在凹陷西斜坡,珠海组上部和底部分别发育钙质砂岩夹层和铁泥质砂岩夹层。三角洲前缘环境是珠海组储层物性良好的先决条件;酸性流体的溶蚀溶解作用和绿泥石黏土膜保护是储层物性较好的根本原因,压实作用是粒间孔隙损失的主要原因,而部分储层渗透率较低是因为自生石英和黏土矿物充填喉道;钙质砂岩夹层物性差是胶结作用所致,而铁泥质砂岩夹层物性差是压实和胶结共同作用的结果。     

In-situ secondary growth of nanocube-based Prussian-blue film as an ultrasensitive biosensor

A regular nanostructure has been widely confirmed to result ina marked improvement in material performance in biosensing applications.In the present study,a regular nanostructured Prussian blue(PB) film with two heterogeneous crystal layers was synthesized in-situ using a secondary growth method.A PB seed layer was first controlled to form uniform cube-like crystal nuclei through an ultrasonic reaction with a single reactant.Then,well-defined 100 nm PB nanocubes were further crystallized on this seed layer using a self-assembly approach.In order to accelerate the electron transfer rate during the enzyme reaction for glucose detection,the graphene was used as the main cross-linker to immobilize glucose oxidase on the PB film.The as-prepared biosensor exhibited high electrocatalysis and electron conductivity for the detection of trace glucose with a sensitivity of141.5 μA mM~(-1) cm~(-2),as well as excellent anti-interference ability in the presence of ascorbic acid and uric acid under a low operation potential of-0.05 V.     

基于复合封装薄膜的水汽透过率测试系统研究

基于活泼金属(钙、镁)电学法设计研发了用于老化测试环境下的水汽透过率测试仪器,测试精度达到10-6 g·m~(-2)·d~(-1).利用本测试仪器测试了不同叠层次数的Al_2O_3/ZrO_2复合薄膜的水汽透过率,结果表明,多次叠层后的Al_2O_3/ZrO_2复合薄膜的水汽阻隔性能得到了较好提升.     

鄂尔多斯盆地东南部上古生界储集砂岩的成岩作用

研究鄂尔多斯盆地东南部上古生界砂岩储层特征,以及不同的成岩作用类型与储集性能的关系。通过分析取芯井的岩石薄片、铸体薄片、扫描电镜、能谱分析数据,发现储集砂岩中发育有粒内溶孔、粒间孔、粒间溶孔、晶间孔、溶缝等多种孔缝类型,其中最主要的是粒内溶孔和粒间溶孔;主要成岩作用类型有压实作用、溶蚀作用、碳酸盐矿物、硅质矿物和黏土矿物的形成作用。结合不同砂岩组分与孔隙面孔率的相关性,得到如下结论:(1)压实作用是导致砂岩孔隙度较差的重要原因;(2)增加砂岩整体孔隙度最重要的是溶蚀作用;(3)碳酸盐矿物的形成会导致砂岩孔隙度减小;(4)硅质矿物会一定程度减少砂岩粒间孔;(5)高岭石的形成对增加岩石整体孔隙作用有限,水云母和绿泥石对溶孔和晶间孔的形成不利。     

不同热解终温和保留时间下污泥生物质炭 孔隙结构特征

通过低温(77 K)氮气吸附/脱附等温实验,结合分形维数的概念,分析生活污水污泥在不同热解终温和保留时间下经热解获得的生物质炭孔隙结构变化特征。实验结果表明,随着热解终温的提高,污泥生物质炭BET的比表面积呈先升高后降低的趋势,在600oC时达到最大,为92.3 m~2/g。在低温(不超过500oC)下,污泥生物质炭中的孔以介孔为主,无微孔出现;在高温(超过500oC)下,则以微孔和介孔为主。随热解终温的升高,孔的形状由狭缝型向开放性和平行板式转变,保留时间的延长不改变孔的形状,但改变孔的容积。污泥生物质炭表面分形维数随热解终温升高呈增大趋势;而保留时间的延长,在中高温(600~700oC)下使污泥生物质炭表面分形维数降低,高温(超过700oC)下又使其提高。     

3,5-二甲基-4-羟基苯基五唑合成及性质理论研究

以3,5-二甲基-4-羟基苯基五唑为研究对象,借助文献报道的合成路线,采用密度泛函理论的M06L/6-311g(d,p)方法,进行了反应机理分析.在3,5-二甲基-4-羟基苯基五唑分子结构全优化的基础上,对其红外光谱(IR)、核磁共振谱(NMR)、紫外-可见吸收光谱(UVVis)进行了量子力学计算.根据反应机理的计算结果,讨论了各反应步骤的特点;根据红外光谱(IR)、核磁共振谱(NMR)、紫外-可见吸收光谱(UV-Vis)的计算结果,对谱图数据进行了简要分析及讨论.     

ZnO/WO_3纳米片薄膜的光电催化性能研究

采用水热法在不锈钢基底上制备WO3纳米片阵列,然后将其浸渍于不同浓度Zn(NO_3)_2溶液中以负载ZnO纳米颗粒,从而制备出ZnO/WO_3纳米片薄膜。采用场发射扫描电镜(FESEM)、X射线衍射(XRD)、X射线光电子能谱(XPS)、紫外-可见吸收光谱(UV-Vis)和电化学阻抗图谱(EIS)等方法对ZnO/WO_3复合薄膜的形貌、结构、物相组成和光电性能等进行分析,重点考察了薄膜电极对亚甲基蓝(MB)的光电催化降解性能。结果表明,WO_3纳米片均匀垂直于基底生长,Zn元素以ZnO颗粒的形式分布在WO_3表面;ZnO的引入促进了WO_3中产生的光生电子-空穴对的分离,从而使ZnO/WO_3复合薄膜表现出比纯WO_3薄膜更优异的光电性能和光电催化活性;在Zn(NO_3)_2浸渍液浓度为20mmol/L时,所制ZnO/WO_3复合薄膜具有最佳的光电催化性能,在MB溶液初始浓度为10mg/L、外加偏压为0.8V、光照1h的条件下,采用该样品对MB的降解率达96.5%,并且复合薄膜具有良好的循环稳定性,在重复使用5次后,对MB的光电催化降解效率没有明显降低,有望在实际污水处理中得到应用。     

Use of high-resolution X-ray computed tomography and 3D image analysis to quantify mineral dissemination and pore space in oxide copper ore particles

Mineral dissemination and pore space distribution in ore particles are important features that influence heap leaching performance. To quantify the mineral dissemination and pore space distribution of an ore particle, a cylindrical copper oxide ore sample (φ4.6 mm×5.6 mm) was scanned using high-resolution X-ray computed tomography (HRXCT), a nondestructive imaging technology, at a spatial resolution of 4.85 μm. Combined with three-dimensional (3D) image analysis techniques, the main mineral phases and pore space were segmented and the volume fraction of each phase was calculated. In addition, the mass fraction of each mineral phase was estimated and the result was validated with that obtained using traditional techniques. Furthermore, the pore phase features, including the pore size distribution, pore surface area, pore fractal dimension, pore centerline, and the pore connectivity, were investigated quantitatively. The pore space analysis results indicate that the pore size distribution closely fits a log-normal distribution and that the pore space morphology is complicated, with a large surface area and low connectivity. This study demonstrates that the combination of HRXCT and 3D image analysis is an effective tool for acquiring 3D mineralogical and pore structural data.