Atmospheric heterogeneous reaction of acetone: Adsorption and desorption kinetics and mechanisms on SiO2 particles

Acetone plays an important role in photooxidation processes in the atmosphere. Up to date, little is known regarding the heterogeneous fate of acetone. In this study, the adsorption and desorption processes of acetone on SiO2 particles, which are the major constituent of mineral dust in the atmos-phere, have been investigated for the first time under the simulated atmospheric conditions, using in situ transmission Fourier transform infrared spectroscopy. It is found that acetone molecules are adsorbed on the surfaces of SiO2 particles by van der Waals forces and hydrogen bonding forces in a nonreactive and reversible state. The rates of initial adsorption and initial desorption, initial uptake coefficients and adsorption concentrations at equilibrium have been determined at different relative humidity. The presence of water vapor cannot result in the formation of new substances, but can decrease the adsorption ability by consuming or overlapping the isolated OH groups on the surfaces of SiO2 particles. In the desorption process, a considerable amount of acetone molecules will remain on SiO2 particles in dry air, whereas acetone molecules are almost completely desorbed at a high relative humidity. In order to evaluate the role of heterogeneous reactions of acetone and other carbonyl compounds in the atmosphere, a new model fitting the atmospheric conditions is needed.     

Progress and prospect for high temperature single-phased magnetic ferroelectrics

Magnetic ferroelectrics are one of the most important functional materials. The present bottleneck limiting applications of them is lacking of high-temperature single-phased ferromagnetic-ferroelectric multiferroics with strong magnetoelectric coupling effect. Here, those progresses of the mechanism for coexistence of ferroelectric and magnetic order, experimental and theoretical studies on single-phased magnetic ferroelectrics, and the relationship between magnetic structure and crystal symmetry are summarized. With examples of BiFeO3, BiMnO3 and Bi2FeCrO6, the difficulties encountered in this field are analyzed. At last, some prospects to develop high-temperature single-phased ferromagnetic-ferroelectric multiferroics are also presented.     

个体保单在两种分布模型下的平均索赔额

本文在索赔次数服从混合Poisson分布与复合Poisson—Geometric分布的基础上,当个体保单索赔额服从指数分布时,给出了累计索赔额服从的分布及个体保单的平均索赔额表达式．     

铁氧化合物对多孔陶瓷滤料表面改性的研究

通过液相沉积、多次涂层法研究了陶瓷滤料的改性.用均匀试验设计方法优化了改性工艺,并对改性滤料的铁覆盖量、抗酸碱和抗机械耐磨性能、比表面积、表面形貌和铁氧粉末的物相组成进行了表征分析.结果表明,2号样品改性工艺为最佳,其比表面积、铁覆盖量、抗酸碱和抗机械耐磨铁脱落率最大或最少,分别为4.987 m2/g、12.181 2 mg/g、0.016 22%、0.015 09%、0.230 7%,铁涂层的主晶相为α-Fe2O3,为多孔结构.改性滤料的这些特性为增强其除污能力奠定了基础.图5,表1,参8.     

复合型英语人才的培养模式研究

伴随着国际化、市场化进程的加速,我国高等教育改革和发展面临着前所未有的机遇,同时也面临着空前的考验。在这种形势下,针对我国英语教育存在的实际问题,必须加大英语专业复合型人才的培养力度,使学生的综合素质进一步提高,使之适应社会发展的需要。     

邯郸某商务楼CFG桩复合地基的设计与施工

以邯郸文化广场商住楼CFG桩工程为例,介绍了CFG桩复合地基的设计计算和施工方法.通过静荷载试验和对建筑物沉降的观测,复合地基承载力和沉降变形均满足要求.     

建立在复合环境下的服务网络模式研究

从机构概念上的服务网络更新和技术网络层面的服务更新两个层面探讨了图书馆未来发展。     

广义复合马尔可夫二项模型的破产概率

将复合马尔可夫二项模型推广为保费收取过程而得到广义复合马尔可夫二项模型并研究其破产概率.给出该模型破产概率的递推公式及其Lundberg型指数的上界.     

涉及一类全纯函数复合的正规定则

研究了一类全纯函数族的正规性。证明了结论：设F是区域D内的一族全纯函数,p（z）=an^z^n＋an-1z^n-1＋…＋a0/bm^z^m＋bm-1z^m-1＋…b0是一个满足m＋1〈n,an≠0,bm≠0的有理函数。若对F中的任意函数f,复合函数p（f（z））≠h（z）,h（z）为非常数全纯函数或者当h（z）为常数函数时p（z）－h（z）至少有两个判别的零点,则F在D内正规。这一结果对文献[1]中P（z）是次数≥2的多项式的结果进行了改进。     

基于鲁棒PID-模糊复合控制的随动系统研究

某型导弹随动系统动力学模型的复杂性及客观环境中的干扰因素,使传统单一模式的控制难以达到预定的要求,有必要寻求鲁棒性强且大误差可控的控制策略.针对模型参数及外界干扰的不确定性,在对该型导弹随动系统的控制方式进行分析研究的基础上,设计一种基于模拟退火算法(SA)优化的模糊控制和鲁棒PID控制的复合控制方法,并用MATLAB软件进行数值仿真.仿真结果表明,复合控制系统的各项性能都比原系统有显著提高.