CO adsorption on electrode of Pt nanoparticles investigated by cyclic voltammetry and <Emphasis Type="Italic">in situ</Emphasis> FTIR spectroscopy

Pt nanoparticles were prepared by the chemical reduction method.The average diameter of Pt nanoparticles was determined to be 2.5nm by TEM.The electrochemical propertis of Pt nanoparticles were studied by cyclic voltammetry,In comparison with massive Pt,the oxidation current peak of CO adsorbed on Pt nanoparticles in broader.Twin adsorbates of CO on Pt nanoparticles were determined by in situ FTIRS for the first time.It has revealed that the linear and twin-bonded CO can be converted into bridge-bonded CO with the variation of electrode potential.A series of special properties of Pt nanoparticles,such as enhanced IR absorption of CO adsorbates,were also observed.     

单分散的硫化银纳米粒子的一步合成及性质表征

提出了一个简单的、温和的条件下合成高产量的、均匀的、单分散的硫化银纳米粒子的方法.该化学方法采用硫脲作硫源和稳定剂,室温下与硝酸银反应一步即可获得Ag2S纳米粒子,因而不需采用任何模板和基底.采用X-射线粉末衍射(XRD)、透射电子显微镜(TEM)、X-射线光电子能谱(XPS)以及紫外-可见光谱(UV-Vis)等手段对所合成的产物进行表征.XRD结果表明产物为单斜相的硫化银,TEM可以看出产物为直径约为50±10 nm左右的球状纳米粒子.XPS分析表明产物中Ag为 1价而S为-2价,它们的原子个数比为AgS = 10.489.UV-Vis观察到合成的硫化银纳米粒子在292 nm处有特征吸收峰.     

Functional Materials for Catalytic and Magnetic Applications

1 Introduction Metal, metal oxide and metal compound nanoparticles (NPs) received considerable attention due to their unique properties: catalytic, magnetic, optical, electronic, etc. We believe that for different applications, there are preferable morphologies of NP-stabilizing medium composites. For example, small (1-3 nm) nanoparticles formed in micro/mesoporous hypercrosslinked polystyrene demonstrate excellent catalytic properties in various hydrogenation and oxidation reactions due to high surface...     

攀枝花钒钛磁铁矿矿山遗迹资源特征及评价

攀枝花钒钛磁铁矿是我国西南地区最大的铁矿矿床之一,在生产过程中形成了类型丰富、数量众多的矿业遗迹景观。该矿业景观具有典型、系统及完整的特点,其科学价值和美学价值很高,与矿山遗迹相配套的自然与人文景观类型亦十分丰富。因此矿山遗迹资源具有十分巨大的开发价值,具备申报国家矿山公园的良好基础。     

生理盐水浸泡对Ti-6Al-4V钛合金超高周疲劳性能的影响

钛和钛合金可作为医用植入材料,有必要对其耐人体体液的侵蚀性能进行研究。用超声疲劳试验技术研究了室温下生理盐水中浸泡24 h后Ti-6A l-4V钛合金(TC4)的超高周疲劳性能,并与未经浸泡的同种材料的超声疲劳性能进行了对比分析。疲劳试验进行到109循环周次以上。结果显示,实验材料的S-N曲线均呈现缓慢下降趋势,材料不存在常规疲劳中的疲劳极限,经生理盐水浸泡24 h后对实验材料的超高周疲劳寿命无明显影响。用电子扫描电镜观测,实验材料表现为穿晶塑性断裂。     

TA6V钛合金疲劳断口形貌及断口分析

在进行TA6V钛合金疲劳小裂纹实验的基础上,使用KYKY2800B型扫描电镜(SEM)对TA6V钛合金疲劳断口形貌进行疲劳源区及其裂纹扩展形状、扩展区、瞬断区形貌的观察,分析TA6V钛合金疲劳断口形貌形成的原因,为其结构疲劳安全设计及可靠性分析提供科学依据,为今后TA6V钛合金在我国的使用提供参考。     

肼还原法制备镍纳米粒子及其机理

在乙二醇中用肼作还原剂还原Ni2 制备镍纳米粒子。用X射线衍射仪测定出产物的相结构,用扫描电子显微镜观察产物的微观结构。根据反应现象和产物的相结构,研究温度、pH值调节剂种类和pH值对镍纳米粒子形成的影响,并推断其形成机理。研究结果表明,用肼作还原剂还原Ni2 制备纳米Ni的最佳反应温度为60℃,用NaOH作pH值调节剂调pH值到10～11得到的镍纳米粒子为体心立方结构,平均粒径为25nm。在Ni纳米粒子的形成过程中,NaOH不仅起到调节pH值的作用,还起催化作用。     

溶剂对TS-1催化丙烯环氧化反应的影响

溶剂对钛硅分子筛TS-1催化丙烯环氧化反应具有重要影响,该文对甲醇、异丙醇和仲丁醇3种醇溶剂及丙酮、乙腈和四氢呋喃等有机溶剂中环氧化反应活性进行了研究,实验结果活性顺序为:甲醇>异丙醇>仲丁醇>乙腈>丙酮>四氢呋喃。以催化反应机理为基础,通过电子效应、空间位阻效应、溶剂极性、物理扩散和分配、溶剂氧化副反应、环氧丙烷(PO)醚化副反应、催化剂失活和丙烯溶解度等多种因素分析了溶剂对环氧化反应的影响。电子效应、空间位阻效应和溶剂极性是影响反应的重要因素,研究工作为今后同类反应溶剂的选取提供理论根据和指导,为PO清洁生产工艺的进一步工业化奠定基础。     

Characterization and Preparation of Bimetallic Nanoparticles

1 Results Bimetallic particles in the nanometer size range are of substantial interest due to their vast applications in catalysis[1].The synthesis of bimetallic nanoparticles with definite size with a well-control over their nanostructure remains a challenging problem.Thus there exists a great demand for both synthesis and atomic level characterization of nanostructure of bimetallic nanoparticles (NPs).With the recent advent of high-intensity tunable sources of X-rays,now available at synchrotron radia...     

Visible light photocatalytic decoloration of methylene blue on novel N-doped TiO2

Novel N-doped TiO2 (denoted as N-NTA600) was prepared by treating nanotube titanic acid (NTA) in NH3 flow. Its visible light photocatalytic activity,evaluated by decoloration reaction of methylene blue,is higher than that of N-P25(600) prepared by treatment of P25-TiO2 in the same condition. It is suggested that the origin of visible-light photocatalytic activity is single-electron-trapped oxygen vacancy (Vo·) modified by chemisorbed NO.