Cs_2NaYX_6（X＝Cl，Br）中Cr~（3＋）的d－d电子光谱和EPRg因子的研究

用双自旋－轨道耦合模型研究了Ｃｓ＿２ＮａＹＸ＿６（Ｘ＝Ｃｌ，Ｂｒ）：Ｃｒ￣３＋的ＥＰＲｇ因子。计算表明，配体Ｂｒ４ｐ轨道对络离子（ＣｒＢｒ＿６）￣３－ＰＲｇ因子的贡献不应忽略。解释了Ｃｓ＿２ＮａＹＢｒ＿６：Ｃｒ￣３＋的ｇ因子移动为正值的疑惑。     

Spectroscopy of aqueous solutions: protein and DNA interactions with water

This review emphasises the need to use spectroscopy in order to understand the behaviour of water, and summarises the background of the subject. The various forms of spectroscopy that are especially informative are described, with particular reference to near-infrared (NIR) spectrophotometry. The key results are outlined, first those obtained with small molecules and ions, and second those involving proteins, DNA and cell membranes. Finally, some interpretations are offered which include the novel but possibly controversial concept of free OH and free lone-pair groups.     

生态产业共生网络运营成本及其优化模型开发研究

从构成生态产业共生网络的微观要素———企业环境责任入手,开发了基于企业环境责任市场化机制的生态产业共生网络运营成本模型,并对模型假设做了改进研究.模型研究结果表明,环境责任代理企业的环境责任履行成本是影响生态产业共生网络运营总成本大小的关键要素,而环境责任委托企业和中间物流企业的各种参数对生态产业共生网络运行总费用的影响相对较小.基于这种认识,最后又探讨了影响代理企业运营成本的主要因子,并对费用优化模型做了应用研究.     

以EPR纠缠为基础的量子密钥分配

提出了一种以EPR纠缠为基础的新的量子密钥分配方案.不需要密钥双方Alice,Bob进行测量基的选择,提高了传输产生的密钥效率.同时,检测偷听者需要对比更少的量子位.     

The first observation of Mo5+ in the passivation layer of Mo2N

Molybdenum nitride powder with S_g of 115 m² · g¹ (passivated) has been prepared by a temperature programmed reaction of MoO₃in H₂/N₂ mixture. It exhibited high catalytic activity in CO oxidation at low temperature. XPS, EPR and LRS studies have shown the existence of mixed valence states of Mo ions, especially Mo⁵⁺ ion (g(tT=1.932,g||=1.892) observed for the first time, in the passivation layer of molybdenum nitride. A surface Superoxide species, O₂ (g = 2.001, Raman band 1 124 cm¹), was found to be produced accompanying the transformation of Mo⁵⁺/Mo⁴⁺ redox pair. Evidence has been given to suggest that this surface superoxide might be responsible for CO oxidation over Mo₂N catalyst.     

A Review of Quantum Cryptography Communication for Wireless Networks

We analyze the development of quantum cryptography communication,including analyze the problems lie in the existent literatures and give the resolve methods according to these problems.Then discuss the quantum cryptography communication for wireless networks and also point out the shortcoming of current research and the future of quantum wireless networks.     

Engineering Entanglement,Conceptualizing Quantum Information

Proposed by Einstein, Podolsky, and Rosen (EPR) in 1935, the entangled state has played a central part in exploring the foundation of quantum mechanics. At the end of the twentieth century, however, some physicists and mathematicians set aside the epistemological debates associated with EPR and turned it from a philosophical puzzle into practical resources for information processing. This paper examines the origin of what is known as quantum information. Scientists had considered making quantum computers and employing entanglement in communications for a long time. But the real breakthrough only occurred in the 1980s when they shifted focus from general-purpose systems such as Turing machines to algorithms and protocols that solved particular problems, including quantum factorization, quantum search, superdense code, and teleportation. Key to their development was two groups of mathematical manipulations and deformations of entanglement—quantum parallelism and ‘feedback EPR’—that served as conceptual templates. The early success of quantum parallelism and feedback EPR was owed to the idealized formalism of entanglement researchers had prepared for philosophical discussions. Yet, such idealization is difficult to hold when the physical implementation of quantum information processors is at stake. A major challenge for today's quantum information scientists and engineers is thus to move from Einstein et al.'s well-defined scenarios into realistic models.     

基于EPR粒子对的信息签名协议

研究了利用Einstein-Podolsky-Rosen (EPR)对的纠缠特性进行量子数字签名的方案,提出了一个基于测量结果比较的签名协议以及一个基于隐形传态的签名协议. 在基于测量结果比较的签名协议中,通信双方测量各自的EPR并将测量结果与消息M进行比较可以实现M的签名和验证,同时通过量子单向函数来保证协议的安全. 在基于隐形传态的签名协议中,消息发送者将M通过隐形传态传递给接收者来实现对M签名并验证,其安全性由量子隐形传态的物理特性来保证. 这两种协议均可以脱离可信赖的第三方,且通信过程中不需要密钥,具有无条件安全性.     

CuGeO_3的电子顺磁共振研究

本文借助于Ｃｕ２＋离子的近似自洽扬ｄ轨道理论，对ＧｕＧｅＯ３中Ｃｕ２＋离子ｄ轨道混合基态波函数和ｇ因子进行了计算．     

The composition and distribution of metal clusters in the MoFe protein from a nifZ deletion strain （DJ 194） of Azotobacter vinelandii

Through the anaerobic chromatography on the columns of DEAE 52, Q-Sepharose and Sephacryl S-200, a nitrogenase MoFe protein (△nifZ Av1) was obtained from a nifZ deleted mutant of Azotobacter vinelandii (stain DJ194).The results of Western blotting after anoxic native electrophoresis and SDS-PAGE showed that △nifZ Av1 was similar to wild type MoFe protein (OP Av1) at the electrophoretic mobility, molecular weight and subunit composition. Furthermore, △nifZ Avl was also similar to OP Av1 at the molybdenum content, EPR signal (g≈4.3, 3.65 and 2.01), and the molar extinction coefficient (△ε) of circular dichroism (CD)at 660 nm region. All of these indicated that, besides having the same α2β2 composition as OP Av1, the △nifZ Av1 also contained equal amount of reductive FeMoco in the spin state of S=3/2 to OP Av1. However, the iron content and substrate (C2H2, H^ and N2)-reduction activity of △nifZ Av1 were 74% and 46%-50% of those of OP Av1, respectively. Furthermore, the △ε at around 450 nm, which reflects P-cluster in Av1, was obviously lower than that of OP Av1. It suggested that the difference between △nifZ Avl and OP Av1 resulted from P-cluster rather than FeMoco, and from the half number of P-cluster in △nifZ Av1, but the composition or redoxstate of P-cluster in △nifZ Av1 were not changed. Thus it could propose that △nifZ Av1 is composed of two different αβsubunit pairs. One is a FeMoco-and P-cluster-containing pair, and the other is a P-cluster-deficient but FeMoco-containing pair. Since the deletion of nifZ gene leads to the deficiency of only one of two P-clusters in a α2β2 tetramer, the assembly of P-cluster may not simply depend on one gene product, and so a possible mechanism of NifZ is supposed here.