新型固体酸SO_4~(2-)MoO_3-TiO_2催化合成苹果酯

自制了一种新固体酸催化剂SO2 -4MoO3 -TiO2 ,FT -IR谱图表明 ,催化剂表面具有强酸中心 ,该催化剂对苹果酯合成的活性高 ,并得到该反应的优化条件如下 :乙酰乙酸乙酯 0 .3mol,乙二醇 0 .6mol,环己烷 30ml,催化剂 3g ,反应温度 110℃ ,反应时间 1.5h ,在此条件下 ,苹果酯产率达 90 % ,且催化剂易回收 ,具有较好的重复使用性能     

(E)-3-(3,4-二甲氧基苯基)-2-氰基丙烯酸乙酯的合成和晶体结构

标题化合物C14 H15O4N(3)是由 3,4 二甲氧基苯甲醛 (1) 与氰乙酸乙酯 (2 ) 在KF/蒙脱土催化下以N ,N 二甲基甲酰胺 (DMF)作溶剂反应而得 .结构通过单晶X射线衍射分析确定 ,其晶体属于单斜晶系 ,空间群P2 1/n ,a =1.310 1(3) ,b =0 .80 32 (2 ) ,c =1.385 4 (2 )nm ,β =114 .2 1(1)° ,Mr=2 6 1.2 7,V =1.32 96 (5 )nm3 ,Dc=1.30 5 g/cm3 ,Z =4 ,μ(MoKα) =0 .0 96mm-1,F(0 0 0 ) =5 5 2 .晶体结构用直接法解出 ,使用全矩阵最小二乘法对原子参数进行修正 ,最后的偏离因子R =0 .0 398,RW =0 .0 816 .单晶X衍射分析表明标题化合物为 (E)式异构体产物 ,说明该反应具有立体选择性 .     

Orthogonally linear polarized lasers(Ⅰ)--principle and devices

Two kinds of orthogonally polarized lasers, i.e. Zeeman dual-frequency lasers and four-frequency ring lasers (laser gyros) have been developed since the invention of lasers, in which circularly polarized lights oscillate. This paper summarizes recent progress of the study on orthogonally linear polarized lasers with the standing wave cavity. Firstly, the expression of producing orthogonally linear polarized lights in standing wave cavity, i.e. laser frequency splitting, is given. Almost all the birefringence effects made in laser cavity are used to produce orthogonally linear polarized lights. The effect includes quartz crystal birefringence effect, calcite birefringence effect,stress (photo-elastic) birefringence effect and electro-optical birefringence effect. Secondly, several physical phenomena of orthogonally linear polarized lasers are discovered such as aberrance of frequency splitting curves caused by optical activity of quartz crystal, order-passing of longitudinal modes with frequency splitting and strong modes competition. Finally, because the traditional Zeeman dual frequency laser cannot output frequency difference larger than 3 MHz, the approaches of obtaining larger frequency difference are studied. The sequential results, several kinds of orthogonally polarized lasers, are described, such as birefringence dual frequency lasers outputting a frequency difference from 40 MHz to hundreds of megahertz, birefringence-Zeeman dual frequency lasers outputting a frequency difference from 1 MHz to hundreds of megahertz, the LD pumped YAG birefringence dual frequency laser outputting frequency difference of several gigahertz, and the lasers whose longitudinal mode spacing is c/4L instead of c/2L.     

双势阱分子自发隧道效应的研究

用解析法对双势阱分子的自发隧道效应进行了研究,得到了粒子的自发隧道效应周期与能级裂距成反比关系,从而对隧道效应对双势阱分子激发态的稳定性贡献给予了积极的肯定.     

碳酸钕对AZ91合金组织的细化和腐蚀性能的影响

通过介绍实验条件实验方法及结果,并对其进行讨论,研究碳酸钕对A291合金组织的细化和腐蚀性能的影响。     

高职思想品德课案例教学效果的显现化

高职思想品德课的现代案例教学的效果显现化,可以帮助和指导学生思想品德的发展。对思想品德课效果显现化的内容应包括认知目标、情感目标、心因目标,其显现化的手段已不能用简单、传统的“考试”来测评,而应考虑用一些更综合的方式进行。     

用VBA实现Auto CAD2002参数化三维造型设计

对参数化绘图的基本原理进行分析,介绍AutoCAD2002环境下运用VBA(VisualBa sicApplication)编程实现参数绘图的方法,实现了对渐开线圆柱齿轮三维造型设计的参数化。     

谈高校改制对档案工作的影响及对策

知识经济的来临,推动了高等教育的迅猛发展,也给高校档案工作带来了新的机遇和挑战,面对高校改制出现的新情况、新问题,高校档案工作需要及时更新观念,积极变革运行机制,使其更好地为高校教学、科研、行政、后勤等部门服务,真正体现档案的价值.