CNX薄膜的PCVD制备及研究

ＣＮＸ薄膜是一种新型的超硬膜。我们用等离子增强化学气相淀积法，制备了含氮量的２１ａｔ％的ＣＮＸ膜，并用俄歇电子探针，红外谱仪和拉曼光谱仪及Ｘ光衍射仪对其结构进行了研究。结果表明膜听屡元素主要以Ｃ≡Ｎ，Ｃ＝Ｂ，Ｃ－Ｎ键的形成与碳结合。     

用平均连续模给出渐近Fejér点组上插值算子的平均逼近阶

本文在对区域D的边界Γ作了较弱的光滑性假设下,得到了用平均连续模来刻划D内有界解析,在Γ上Riemann可积函数在渐近Fej(?)r点组上的Lagrange及Hermite-Fej(?)r插值算子在L~P(Γ),P>1意义下逼近函数的平均逼近阶,在得到这些估计式时,我们首先在一般区域上,对渐近Fej(?)r点组,导出了Marcinkiewicz-Zygmund型不等式。     

（淮）共晶系相变材料融点及融解热的理论预测

本对（准）共晶系的融点和融解进行了分析预测，得到了共晶混合物融点，融解热与组分物性间的关系及两个推论。所得结果对按应用需要选配合适融点、融解热的相变混合介质具有指导意义。     

变质量三体问题

本文研究了变质量圆型限制性三体问题的运动方程,Jacobi积分,给出了拉格朗日特解,并对零速度面和平动点附近的稳定性做了讨论。     

球状碳——碳的第三种同素异形体

本文综述了球状碳（富勒烯）的发现、制备、结构、化学性质及芳香性，以及配合物等方面的最新研究进展     

关于台风路径转折的研究

本文研究台风的运动，得到了下列方程 本文还研究台风路径的转析与５00bm变高场的关系，并给山了预报台风路径转析的一种新方法．     

点空间分析--分维与均匀度

对有限空问内的点集定义了独占圆、独占线和独占球。通过对有限点集均匀性的研究,抽象出了均匀度的定义。对分形集定义了度量映射,度量映射产生的点集的均匀度与分维之间有换算关系,可以说均匀性与复杂性是密不可分的。均匀度是对点集格局的一种测度,它描述的是点集的空间关系,而不是点的“多少”,有限点集的均匀度可以取到[01]区间的任何实数,这是它与测度和分维的区别。本文得到两个有趣的常数：一位无限循环小数产生的点集的均匀度为0．1,随机格局的均匀度的数学期望为1／x=0．318。可见,均匀度将空间复杂性转移到了点集均匀性上,它为复杂性的研究打开了新的窗口。     

Concentrations of “elemental carbon” in samples from the Peking Man Site at Zhoukoudian and the possibility of their application in the development of evidence for the use of fire by humans

Elemental carbon?EC) is a C-rich, O-H-S-N-depleted substance that is necessarily produced in the process of combustion. Due to the logn-term use of fire by cave-inhabiting ape-men, considerable amounts of 揺lemen-tal carbon?would be necessarily left behind in the corre-sponding strata inside the cave. The sepaation of EC was effected by the chemical method and the contents of carbon were determined on an element analyser and a self-made measuring system. The concentration of Ec in the hearth,the exhibited ash samples collected from near the hearth un-earthed in the 1930s, and the three samples of accumulated material collected from the tenth bed are 43.74%, 1.77%,3.88%,1.87% and 1.11%,respectively; those of the equivalent samples from the tenth bed outside the cave and samples from the fourth and seventh beds are at least one order of magnitude lower than the former抯. The above re-sults show that the sampling location of the tenth bed may be close to the hearth. Sampling over a wider range may lead to the finding of a location where the concentrations of EC are corresponding to the maximum values of EC in the hearth. The determination and study of EC may provide new evi-dence for the use of fire by Peking Man.     

A study on nano-sized NiO electrodes doping with C and Co prepared by electrochemical deposition-sintering processes and their capacitance performance

In the present work, it was studied that nanoosized NiO electrodes doping with C and Co were prepared by electrochemical deposition in an ethanol solution containing nickel nitrate and cobalt nitrate and sintering processes. The capacitance performance of such electrodes was also studied. The results reveal that samples obtained by electrochemical deposition first on a porous nickel cathode in an ethanol solution contain 0.5 mol/L nitrates, in which Ni(NO3)2 and Co(NO3)2 were mixed in a molar proportion of 8 : 2. After sintering at 300℃ for 2 h, they exhibited the best performance. XRD analysis illustrates that the essential phase of the product is NiO doping with certain content of C and Co. The particles of product imaged a spherical morphology with sizes of 20---30 nm in diameter, and with an average crystal size of 4--5 nm. The capacitance measurement of the simulating C/NiO capacitors indicates that a single electrode can reach as high as 410.0 F/g, and still maintain the value of 323 F/g after 30 recycles showed as a stabilized value with increasing recycles, when it was discharged at a current of 5 mA.     

Progress in the synthesis and reactivity studies of metallabenzenes

Metallabenzenes are metallacyclohexatriene complexes that are derived by replacement of one of the CH groups in benzene with a transition-metal fragment. Their synthesis and aromatic properties have recently attracted considerable attention. This paper summarizes the progress in the synthesis, aromatic property, and reactivity studies of metallabenzenes. We will describe the synthesis and reactivity of typical metallabenzenes with various metals (e.g. osmium, iridium, and ruthenium, etc.), the synthesis and structure of a recent reported example of metallanaphthalene and several rare examples of novel and stable metallabenzynes. Finally, the possible future developments in this field have also been suggested.