Description of mechanism function about dehydration of cobalt oxalate dihydrate by multiple rates isotemperature method

0　IntroductionThetechnologyofthermalanalysishasbeenwidelyusedinthestudyofthermalbehaviorandthermalcharacterofsolidstatereaction ,theprimaryintentionofthermalanalysiskineticsistoestablishseparatevaluesofapparentactivationenergyE ,themostprobablemechanism g(α)andthepre exponentialfactorA ,meanwhilethedeterminationofg(α)hasgraduallybeenthefocusofthisfield .Inthisfield ,therearemostlygeneralkineticsmethodsused presently ,suchasCoats Redfern’s[1 ] integralmethod ,Achar’s[2 \〗differentialmet…     

Fast dating of Yongzheng copper coins in tsing empire by SEM-EDS

Twenty Yongzheng copper coins were fast dat-ing by X-ray energy dispersive spectrometer with scanning electron microscope (SEM-EDS) according to official ingredient. The 20 coins were classified in two groups according to the results. Group 1 represents the coins minted before AD 1 728 and group 2 represents the coins minted after AD 1 728. At concentration range (0.00%-5.13%), the distribution of lead is not homogeneous in the coins, and the largest diameter of lead inclusion is less than 15 μm. The official fineness degrade is supported.     

科学与艺术的结晶《Mandelbrot-Julia混沌分形图谱》——五大宇宙定律与时空谱

提出了一种具有Mandelbrot-Julia混沌分形图谱的曼德布罗特(Mandelbrot)混沌分形时空观,对经典的逃逸时间算法加以改进,提出了旋转逃逸时间算法,构造了一系列由复映射变换f1(z)=zm+c(m≥2,m∈N)和f3(z)=zω+c(ω=α+iβ)所确定的广义Mandelbrot集(简称M-集或M-分形图)及其对应的Julia集(简称J-集或J-分形图),提供了对其深入研究的新现象、新图形和新规律"图中嵌图、形中镶形、拉压与折叠、统计自相似、无限周期有稠性、混沌分形有新序".算法利用面向WEB的Java Applet技术实现,提供了一种基于Internet的分布式混沌分形理论研究机制.     

Dawson结构钨钛磷杂多配合物~(183)WNMR谱的研究

研究了Dawson结构取代原子数与相应的183 WNMR谱中“极位”W原子的化学位移值间的关系 .预测了α - 1 ,2 [P2 W16Ti2 O62 ]10 -,α - 1 ,2 - [P2 W16(TiO2 )2 O60 ]10 -“极位”W原子183 WNMR谱化学位移值 ,结果α - 1 ,2 - [P2 W16Ti2 O62 ]10 -和α - 1 ,2 - [P2 W16(TiO2 ) 2 O60 ]10 -中与取代Ti相连“极位”W原子的化学位移值分别为 :- 5 9.3ym ,- 66.5ym ;与取代Ti相对称“极位”W原子的化学位移值分别为 :- 1 49.3ym ,- 1 62 .6ym ;与取代Ti不对称“极位”W原子的化学位移值分别为 :- 1 2 5 .4ym ,-1 31 .4ym .     

隧道凿岩机器人的车体定位方法

讨论了国内自行研制的隧道凿岩机器人利用安装在隧道上的激光,使钻壁上的两个激光靶与激光过难,采集各关节传感器的值并做数据处理,能得到精确的车体到隧道断面的坐标变换矩阵,实现车体的精确定位,同时根据推导公式的特性,介绍了一种简单的定位方法。     

基于噪声小波包络谱的主轴承磨损故障诊断

传统的基于振动信号的内燃机主轴承磨损故障诊断中安装传感器以及提取故障特征频率很繁琐,为此,提出了基于噪声和正交小波监测往复式活塞发动机滑动主轴承磨损故障的一种新方法.利用Symlets小波分析将测得的机体噪声信号变换到时频域,得到含有内燃机主轴承间隙磨损状态的时频信息.主轴承磨损故障会使机体噪声信号的高频成分增加,而且高频滤波成分特征与内燃机的冲击过程相对应,所以,需选择合适的高频带加以提取并进行包络谱分析.通过声级计测取了代表主轴承4类间隙磨损程度的噪声信号,发现2个特征频率处的能量对间隙磨损状态比较敏感,均随着磨损量的增加而增加.通过该方法,可利用机体噪声信号监测主轴承的磨损状态.     

关于矩阵谱条件数的估计

提供了一个可选择的矩阵条件数的估计式,应用此方法,可以改进以往相应的用QR-方法计算矩阵特征值的相关条件数估计的结果．     

Observation of contrast variations of a copper (Ⅱ) complex by scanning tunneling microscopy

This report presents experimental observations of dramatic variations in STM images of bis [1,3-DI(p-n-tetradecyloxyphenyl)propane-1,3-dionato]copper( Ⅱ） (abbreviated to C14O-Cu)physisorbed on HOPG as the bias voltage is changed .Several representative image patterns were obtained for the rich changes of the internal contrast of the molecule .Submolecular features of the molecular cores and the interdigitated alkyl parts are clearly visible.     

2D self-assembling of 4, 5-didodecylthiolphthalonitrile on graphite surface

An important precursor 4,5-didodecylthiolphthalonitrile (DCP) for synthesis of phthalocyanines (Pcs) and subphthalocyanines (SubPcs) was synthesized and the assembling structure of this molecule on the basal plane of highly oriented pyrolytic graphite (HOPG) surface was characterized using the scanning tunneling microscopy (STM) in ambient conditions. In high-resolution images of the molecules, we found that the arrangement of the cyano groups forms a “head-to-head” configuration to keep the stability of the entire system. The mismatch of the DCP molecules with the substrate lattice has also been observed in the experiment.     

Pb(Mg1/3Nb2/3)O3-30%PbTiO3弛豫铁电单晶的异常压电响应行为

利用高真空度扫描力显微术(HV-SFM)的压电响应模式原位研究了Pb(Mg_1/3Nb_2/3)O₃-30%PbTiO₃ (PMN-PT)弛豫铁电单晶(111)晶面的压电响应行为. 观察到与单晶束缚电荷补偿机制密切关联的异常的压电响应行为. 高真空度条件下的压电响应退化行为与本征屏蔽电荷不足以补偿极化电荷所引起的极化状态的不稳定性有关. 而大气环境下相当强的压电响应信号源于表面吸附机制所致的表面束缚电荷对畴状态较强的稳定作用.