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1.
作者首次发现了Si3N4-MgO-CeO2系陶瓷在烧结过程中玻璃相自动析晶这一独特现象.对于Si3N4-MgO-CeO2系陶瓷在1450℃,MgO-CeO2就会与Si3N4颗粒表面的SiO2反应形成硅酸盐液相,冷却后则成为玻璃相保留在烧结体中;当烧结温度高于1550℃时,作者发现,CeO2仍留在玻璃相中,但MgO会自动析晶出来,其结果是大大减少了烧结体中严重影响其高温性能的玻璃相的含量,对于提高烧结氮化硅陶瓷的高温性能有重要作用  相似文献   

2.
综述了SiC颗粒弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp含量对材料显微结构和力学性能的影响,对SiCp弥散强化Si3N4基陶瓷材料的强化效果和强化机理进行了初步的分析  相似文献   

3.
超高压烧结Si3N4陶瓷断口形貌与韧性的研究   总被引:1,自引:1,他引:0  
研究不同制作条件下Si3N4陶瓷断口形貌与韧性的关系,当温度在1160~1340℃烧结时断口平面凹凸不平起伏很大,具有较好的韧性.当加入烧结助剂总量达质量百分数9%时,过多的烧结助剂会形成低熔点化合物存在于片层组织之间,降低了Si3N4陶瓷的强度与韧性.  相似文献   

4.
综述了SiC闰弥散强化Si3N4基陶瓷材料的研究近况,根据Si3N4和SiC的不同烧结机理对Si3N4/SiCp复相陶瓷材料烧结机理以及SiCp的掺入对材料可烧结性的影响进行了理论上的探讨。将SiCp粒子的尺寸对Si3N4/SiCp复相陶瓷材料显微结构和力学性能的影响与材料可烧结性之间的关系进行了分析,通过比较热压Si3N4/SiCp复相陶瓷材料和Si3N4/纳米SiCp复相陶瓷材料中SiCp一地  相似文献   

5.
ZrO2对Si3N4陶瓷烧结性能的影响   总被引:2,自引:0,他引:2  
对添加ZrO伯Si3N4陶瓷烧结性能的研究表明,一方面ZrO2可作为一种烧结助剂,促进液相烧结;另一方面它也以四方相形式弥散分布于Si3N4晶粒间,以提高材料的强韧性,试验结果表明:常压烧结下,ZrO2的质量分数为0.18时,材料强韧性最好。  相似文献   

6.
自韧化氮化硅陶瓷研究   总被引:4,自引:0,他引:4  
对热压烧结自韧化Si3N4陶瓷的工艺参数诸如助烧剂量,烧结时间和温度等与材料显微组织,相组成及力学性能间的关系进行了研究。在致密化前提下且烧剂量较少时,有利于材料显微组织的均匀化和力学性能的提高。  相似文献   

7.
Si3N4-MgO-CeO2陶瓷烧结过程中的致密化与相变   总被引:3,自引:0,他引:3  
氮化硅陶瓷有极大的应用潜力,但由于其强共价键,很难烧结致密化。采用了一种新的MgO-CeO2复合烧结助剂,利用X射线衍射、透射电镜等手段研究了MgO-CeO2复合烧结助剂对氮化硅陶瓷致密化和相变过程的影响,结果发现对Si3N4-MgO-CeO2陶瓷,在1450℃就会有大量液相出现,1500~1550℃为快速致密化阶段,而α-Si3N4→β-Si3N4相变主要发生在1550~1600℃,相变过程滞后于致密化过程。常压烧结Si3N4-MgO-CeO2陶瓷,强度达948MPa,因此,MgO-CeO2是一种非常有效的氮化硅的烧结助剂。  相似文献   

8.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的的摩擦系数及Si3N4销的磨损系数.对陶瓷销的磨损面进行了SEM显微形貌观察、X射线分析;并探讨了陶瓷销的磨损机理.研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理.  相似文献   

9.
测定了销-盘式热压Si3N4/3Cr2W8V钢摩擦副在室温干摩擦磨损条件下的摩擦系数及Si3N4销的磨损系数,对陶瓷销的磨损面进行了SEM显微形貌观察,X射线分析;并探讨了陶瓷销的磨损机理。研究结果表明:Si3N4陶瓷的磨损以微区脆性断裂为主要机理。  相似文献   

10.
重点研究了Al2O3 /ZrSiO4 富铝体系反应烧结制备过程中的晶相变化,以及Al2O3/SiO2 比对反应烧结的影响,进而研究了添加Cr2O3 对反应烧结的影响.研究表明,在反应烧结过程中,莫来石的生成明显滞后于ZrSiO4 的分解;在相同温度下,ZrSiO4 的分解程度随Al2O3 的加入量的增加而提高.添加Cr2O3 使莫来石的稳定生成温度提高,此外,Cr2O3 的引入有助于Al2O3 向莫来石中的固溶  相似文献   

11.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

12.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

13.
本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。  相似文献   

14.
Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with  相似文献   

15.
The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to  相似文献   

16.
17.
The explosive growth of the Internet and database applications has driven database to be more scalable and available, and able to support on-line scaling without interrupting service. To support more client's queries without downtime and degrading the response time, more nodes have to be scaled up while the database is running. This paper presents the overview of scalable and available database that satisfies the above characteristics. And we propose a novel on-line scaling method. Our method improves the existing on-line scaling method for fast response time and higher throughputs. Our proposed method reduces unnecessary network use, i.e. , we decrease the number of data copy by reusing the backup data. Also, our on-line scaling operation can be processed parallel by selecting adequate nodes as new node. Our performance study shows that our method results in significant reduction in data copy time.  相似文献   

18.
R-Tree is a good structure for spatial searching. But in this indexing structure,either the sequence of nodes in the same level or sequence of traveling these nodes when queries are made is random. Since the possibility that the object appears in different MBR which have the same parents node is different, if we make the subnode who has the most possibility be traveled first, the time cost will be decreased in most of the cases. In some case, the possibility of a point belong to a rectangle will shows direct proportion with the size of the rectangle. But this conclusion is based on an assumption that the objects are symmetrically distributing in the area and this assumption is not always coming into existence. Now we found a more direct parameter to scale the possibility and made a little change on the structure of R-tree, to increase the possibility of founding the satisfying answer in the front sub trees. We names this structure probability based arranged R-tree (PBAR-tree).  相似文献   

19.
The geographic information service is enabled by the advancements in general Web service technology and the focused efforts of the OGC in defining XML-based Web GIS service. Based on these models, this paper addresses the issue of services chaining,the process of combining or pipelining results from several interoperable GIS Web Services to create a customized solution. This paper presents a mediated chaining architecture in which a specific service takes responsibility for performing the process that describes a service chain. We designed the Spatial Information Process Language (SIPL) for dynamic modeling and describing the service chain, also a prototype of the Spatial Information Process Execution Engine (SIPEE) is implemented for executing processes written in SIPL. Discussion of measures to improve the functionality and performance of such system will be included.  相似文献   

20.
Advances in wireless technologies and positioning technologies and spread of wireless devices, an interest in LBS (Location Based Service) is arising. To provide location based service, tracking data should have been stored in moving object database management system (called MODBMS) with proper policies and managed efficiently. So the methods which acquire the location information at regular time intervals then, store and manage have been studied. In this paper, we suggest tracking data management techniques using topology that is corresponding to the moving path of moving object. In our techniques, we update the MODBMS when moving object arrived at a street intersection or a curved road which is represented as the node in topology and predict the location at past and future with attribute of topology and linear function. In this technique, location data that are corresponding to the node in topology are stored, thus reduce the number of update and amount of data. Also in case predicting the location,because topology are used as well as existing location information, accuracy for prediction is increased than applying linear function or spline function.  相似文献   

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