工艺参数对凝胶注模成型不锈钢坯体强度和烧结密度的影响

为了制备高坯体强度和烧结密度的凝胶注模成型不锈钢制件,研究了凝胶注模工艺参数包括预混液单体含量和单体/交联剂比例、浆料固相含量及引发剂加入量等对坯体抗弯强度及烧结体密度的影响规律.结果表明,对于316L不锈钢的凝胶注模成型,可同时获得较好的坯体强度和烧结密度的工艺条件为:预混液单体质量分数18%～22%,单体/交联剂比例90∶1～240∶1;浆料固相体积分数52%～55%;引发剂用量约为单体质量的0.8%～1.4%.最终获得坯体强度高于30.0MPa、烧结密度高于97%的复杂形状烧结不锈钢零件,其烧结体力学性能略低于粉末注射成型时的性能,但远高于美国MPIF标准.     

Z值对凝胶注模成型SiC-Sialon材料烧结性能的影响

Z值对SiC-Sialon材料的结构和性能，如烧结性能有重要的影响。本实验对利用先进的凝胶注模成型工艺制备的形状复杂、性能优良的SiC-Sialon坯体，在氮气气氛，1570℃下烧结，制出抗折强度大于55MPa。体积密度大于3．08g／cm^3的SiC-SiMon制品。研究结果表明，在一定的实验条件下，Z值为2的Sialon的晶型发育的最好，此时SiC-Sialon材料的致密化也最好，强度最大。     

凝胶注模成型钛-生物玻璃多孔生物复合材料研究

采用凝胶注模成型工艺制备了钛-生物玻璃复合材料坯体,研究了pH值、分散剂、固相含量(钛和生物玻璃在料浆中的质量分数)等因素对料浆和复合材料坯体性能的影响,对坯体的力学性能进行了测试,借助扫描电镜分析了坯体的微观组织.试验结果表明,料浆的pH值应控制在8.5～9.5的范围内;聚丙烯酸铵的浓度为2vol%时,料浆的流动性最好;采用搅拌法制备的复相料浆固相含量达到50%,复合材料坯体的抗弯强度达到40MPa;由于生物玻璃的加入,使得多孔生物材料表面的生物活性提高.     

真空凝胶注模成型ZTA(含SiO2)陶瓷的烧结性能分析

采用一种新型的真空凝胶注模成型法,减少了在凝胶注模成型时坯体中形成的气泡。烧结曲线表明,真空凝胶注模制得的坯体的烧结温度比普通凝胶注模制得的坯体的低100℃左右。在1 550℃,真空坯体的收缩率比普通坯体的高78.7%。     

Z值对凝胶注模成型Sic-Sialon材料烧结性能的影响

Z值对SiC-Sialon材料的结构和性能,如烧结性能有重要的影响.本实验对利用先进的凝胶注模成型工艺制备的形状复杂、性能优良的SiC-Sialon坯体,在氮气气氛,1 570℃下烧结,制出抗折强度大于55MPa.体积密度大于3.08g/cm3的SiC-Sialon制品.研究结果表明,在一定的实验条件下,Z值为2的Sialon的晶型发育的最好,此时SiC-Sialon材料的致密化也最好,强度最大.     

锆钛酸铅压电陶瓷材料凝胶注模成型

为制备凝胶注模成型所需的高固相低粘度的锆钛酸铅陶瓷浆料,分别用分散剂聚甲基丙烯酸铵和柠檬酸三铵进行试验.研究了分散剂聚甲基丙烯酸铵、浆料pH值和固相含量对浆料粘度的影响,实验结果表明该分散剂最佳用量为陶瓷粉体质量分数0.30%~0.45%、浆料最佳pH值8.5~11.0,此时可制备体积分数50%、粘度小于1 Pa.s,适于凝胶注模的稳定锆钛酸铅浆料.其中当分散剂质量分数为0.30%时,烧结陶瓷有较好的微观结构.同时,对干压成型中不同粘合剂的作用效果进行了比较.     

SiC掺杂对中间相碳微球组织的影响

以Tween 80为分散剂,分别以丙烯酰胺和N,N′-亚甲基双丙烯酰胺为单体和交联剂,采用凝胶注模工艺,经过1000℃的埋碳烧结工艺,分别制备了掺杂SiC的中间相碳微球凝胶注模素坯和烧结体.研究SiC加入量对素坯和烧结体的影响.结果发现,当加入w(SiC)达到15%时,SiC具有明显的催化石墨化的效果.     

凝胶注模成型氧化锆陶瓷坯体的性能和显微结构分析

研究了通过添加2.6%(质量分数)水溶性高分子聚丙烯酰胺到氧化锆陶瓷悬浮体中能够消除在空气中凝胶注模成型的坯体的表面脱粉现象,成型出的形状复杂的氧化锆湿坯体性能良好,均匀致密.并研究了氧化锆粉体加入聚丙烯酰胺前后在水中的分散特性,同时对坯体的抗弯强度和显微结构进行了详细地测试和观察.     

Al2O3陶瓷凝胶注模成型工艺的研究

凝胶注模成型是一种原位成型工艺 ,该工艺是制备形状复杂、成分均匀和可靠性高的陶瓷材料的理想成型工艺。以降低Al2 O3陶瓷浆料的黏度和提高固相含量为重点 ,分别研究了pH值、分散剂、固相含量对浆料黏度的影响 ,以及固相含量对坯体抗弯强度的影响 ,并制备出固相含量 5 5 %、黏度 0 .69Pa·s的Al2 O3浆料 ,其坯体抗弯强度 3 1MPa .     

琼脂凝胶注模成形不锈钢粉末浆料与生坯的性能

研究温度、琼脂质量分数、分散剂质量分数、固相体积分数等因素对浆料流变性质和生坯力学性能的影响规律,获得最优的凝胶注模工艺参数.在此实验研究基础上,对金属浆料的混合、分散、凝胶机理和生坯的烧结过程进行初步分析和探索.研究结果表明:粒径分布为2～30 μm的316L不锈钢粉末,应用聚乙烯醇为分散剂,控制溶液pH值为8.5～...     

An Index mechanism for multi-scale view in spatial databases

There are numerous geometric objects stored in the spatial databases. An importance function in a spatial database is that users can browse the geometric objects as a map efficiently. Thus the spatial database should display the geometric objects users concern about swiftly onto the display window. This process includes two operations:retrieve data from database and then draw them onto screen. Accordingly, to improve the efficiency, we should try to reduce time of both retrieving object and displaying them. The former can be achieved with the aid of spatial index such as R-tree, the latter require to simplify the objects. Simplification means that objects are shown with sufficient but not with unnecessary detail which depend on the scale of browse. So the major problem is how to retrieve data at different detail level efficiently. This paper introduces the implementation of a multi-scale index in the spatial database SISP (Spatial Information Shared Platform) which is generalized from R-tree. The difference between the generalization and the R-tree lies on two facets: One is that every node and geometric object in the generalization is assigned with a importance value which denote the importance of them, and every vertex in the objects are assigned with a importance value,too. The importance value can be use to decide which data should be retrieve from disk in a query. The other difference is that geometric objects in the generalization are divided into one or more sub-blocks, and vertexes are total ordered by their importance value. With the help of the generalized R-tree, one can easily retrieve data at different detail levels.Some experiments are performed on real-life data to evaluate the performance of solutions that separately use normal spatial index and multi-scale spatial index. The results show that the solution using multi-scale index in SISP is satisfying.     

Characterization of Ordovician carbonate reservoirs, southeastern Saskatchewan, Canada

The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3～4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰～ -7.8‰, PDB) and matrix dolomites (-6.6‰～ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084～0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078～0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.     

A computer generator for randomly layered structures

AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…     

Perspherical Approaches for Electrons in Atoms and Charged Excitons in Quantum Wells

Instead of following Fock’s expansion,we solve the Schrodinger equation for some quantum mechanical manybody systems such as electrons in atoms and charged excitons in quantum wells in a similar way in hyperspherical coordinates by expanding the wave functions into orthonormal complete basis sets of the hyperspherical hannonics(HHs)of hyperangles and generalized Laguerre polynomials(GLPs)of the hyperradius.This leads the equation to     

Advances in broadband wireless communications under high-mobility scenarios

Future mobile communication systems aim at providing very high data transmission rates, even in high-mobility scenarios such as high-speed wheel-track trains, maglev trains, highway vehicles, airplanes, guided missiles or spacecraft. A particularly important commercial application is the strong and increasing worldwide demand for high- speed broadband wireless communications （up to 574.8 km/ h test speeds or 380 km/h commercial speeds） in railways, providing data, voice and video services for applications such as onboard entertainment services to passengers, train control, train dispatch, train sensor status handling and sur- veillance. In such high-mobility scenarios, there are a number of communication challenges, including fast hand- over, location updating, high-speed channel modeling, estimation and equalization, anti-Doppler spreading tech- niques, fast power control, and dedicated network architec- ture. Because signal transmission in very high-speed scenarios will inevitably experience serious deterioration, it is imperative to develop key broadband mobile communi- cation techniques for such high-speed vehicles.     

Wuhan University Journal of Natural Sciences TOTAL CONTENTS

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海南岛地体及其毗邻陆缘晚中生代—新生代古地磁研究和构造演化

本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。     

Scale-based spatial data model for GIS

Being the primary media of geographical information and the elementary objects manipulated, almost all of maps adopt the layer-based model to represent geographic information in the existent GIS. However, it is difficult to extend the map represented in layer-based model. Furthermore, in Web-Based GIS, It is slow to transmit the spatial data for map viewing. In this paper, for solving the questions above, we have proposed a new method for representing the spatial data. That is scale-based model. In this model we represent maps in three levels: scale-view, block, and spatial object, and organize the maps in a set of map layers, named Scale-View, which associates some given scales.Lastly, a prototype Web-Based GIS using the proposed spatial data representation is described briefly.     

Exciton Seebeck in Molecular Systems

Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with     

Achieving Unusual States of Matter Under High Pressure

The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to