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1.
研究了金属酞菁化合物四(2,4-二甲基苯氧基)酞菁铜和四(2,4-二甲基苯氧基)酞菁镍在汽-液界面上的成膜特性,制备了相应的Langmuir-Blodgett(LB)膜。利用紫外可见吸收及偏振紫外可见吸收谱,表征了LB膜中的酞菁分子主要以二聚体的形式相对于基片水平排列。以酞菁LB膜为取向层制成液晶盒,取向向列型液晶E_7。通过偏光显微镜及锥光干涉系统,确定液晶分子在LB膜上的排列情况,并进行了电光测试,讨论了导致不同取向效果的机理。  相似文献   

2.
该文根据TN型液晶盒制作流程,采用不同的取向膜配置方式,分别制作出两组样品,并对其电光特性进行测试,测试结果表明,取向膜配置方式对液晶盒的电光特性存在一定的影响。分析认为,不同配置方式造成取向膜膜厚不同,是造成液晶盒电光特性不同的原因。  相似文献   

3.
用偏振FTIR-ATR方法研究1~9层花生酸铒LB膜结构,结果表明,在适当条件下花生酸铒可以形成稳定的LB膜。利用单轴及双轴取向模型分析了不同层数LB膜的结构与取向,1层与3层以上的花生酸铒LB膜的结构是不同的。单层LB膜内脂链的取向角为39°,并且是双轴分布,在xy轴投影的角度为41°,3层以上花生酸铒LB膜的结构为单轴取向,取向角为21°。  相似文献   

4.
液晶(EBBA)的光学多稳态的理论探讨马如康(漳州师范学院物理系363000)本文以置于F-P腔中的平行平面排列的向列型液晶膜在激光束以与液晶膜面法线方向成一定的夹角β入射,而产生光致重取向使其折射率随取向角发生变化为例,运用光线在F-P腔中的传播规...  相似文献   

5.
采用不摩擦技术制备了无序的混合排列型ECB液晶盒,研究了盘中液晶的微观织构,分析了它的电光特性和视角特性.结果表明,该液晶盒是多畴结构,具有很多向错,并具有三色峰值电压分离较好、工作电压低、视角在整个平面内具有方位角对称性的特点.  相似文献   

6.
应用偏光显微镜、扫描电子显微镜、DSC以及测定氧氮渗透性,对乙基纤维素液晶溶液和低分子液晶共混膜在电场下取向膜和非取膜的结构和性能进行研究,结果表明:高分子液晶和低分子液晶在电场下的均发生排列取向,渗透系数提高,渗透比稍微降低;各向同性溶液在电场下不发生取向;撤离电场后,发生部分分解取向,解取向程度与MBHpA的含量和实验温度有磋。  相似文献   

7.
利用电化学循环伏安法研究了沉积在ITO导电玻璃电极上液晶聚合物LB膜的屏蔽效应.通过测量各种成膜条件下循环伏安图的变化,结合X-射线衍射和紫外光谱的结果,对LB膜的微细结构进行了探讨.  相似文献   

8.
利用电化学循环伏安法研究了沉积在ITO导电玻璃电极上液晶聚合物LB膜的屏蔽效应,测量各种成膜条件下循环安图的变化,结合X-射线衍射和紫外光谱的结果,对LB膜的微细结构进行了探讨。  相似文献   

9.
该叙述液晶相与它的分子结构,液晶的各向异性,电光效应和液晶应用及电场和磁场对液晶分子取向的影响,并围绕这个问题进行讨论。  相似文献   

10.
制备条件对梯形聚硅氧烷取向层光取向行为的影响   总被引:1,自引:0,他引:1  
选用侧链含有双元光敏基团的梯形聚硅氧烷材料作为光取向材料,采用偏光显微镜(POM)及晶体旋转法,研究了梯形聚硅氧烷光取向层的制备条件,包括取向剂浓度、紫外光辐照度及光照时间对光取向层的取向行为的影响.结果表明,取向剂浓度越大,光敏基团更易于组装成垂直取向状态,进而诱导液晶分子形成垂直取向的分子排列方式.在一定的紫外光辐照度范围内可以有效地引起偶氮苯光敏基团的面内、面外异构化及再取向,有利于取向层诱导液晶分子形成平面取向的分子排列方式.紫外光光照时间的增加有利于取向层诱导液晶分子形成平面取向的分子排列方式.  相似文献   

11.
The discovery of the prolific Ordovician Red River reservoirs in 1995 in southeastern Saskatchewan was the catalyst for extensive exploration activity which resulted in the discovery of more than 15 new Red River pools. The best yields of Red River production to date have been from dolomite reservoirs. Understanding the processes of dolomitization is, therefore, crucial for the prediction of the connectivity, spatial distribution and heterogeneity of dolomite reservoirs.The Red River reservoirs in the Midale area consist of 3~4 thin dolomitized zones, with a total thickness of about 20 m, which occur at the top of the Yeoman Formation. Two types of replacement dolomite were recognized in the Red River reservoir: dolomitized burrow infills and dolomitized host matrix. The spatial distribution of dolomite suggests that burrowing organisms played an important role in facilitating the fluid flow in the backfilled sediments. This resulted in penecontemporaneous dolomitization of burrow infills by normal seawater. The dolomite in the host matrix is interpreted as having occurred at shallow burial by evaporitic seawater during precipitation of Lake Almar anhydrite that immediately overlies the Yeoman Formation. However, the low δ18O values of dolomited burrow infills (-5.9‰~ -7.8‰, PDB) and matrix dolomites (-6.6‰~ -8.1‰, avg. -7.4‰ PDB) compared to the estimated values for the late Ordovician marine dolomite could be attributed to modification and alteration of dolomite at higher temperatures during deeper burial, which could also be responsible for its 87Sr/86Sr ratios (0.7084~0.7088) that are higher than suggested for the late Ordovician seawaters (0.7078~0.7080). The trace amounts of saddle dolomite cement in the Red River carbonates are probably related to "cannibalization" of earlier replacement dolomite during the chemical compaction.  相似文献   

12.
AcomputergeneratorforrandomlylayeredstructuresYUJia shun1,2,HEZhen hua2(1.TheInstituteofGeologicalandNuclearSciences,NewZealand;2.StateKeyLaboratoryofOilandGasReservoirGeologyandExploitation,ChengduUniversityofTechnology,China)Abstract:Analgorithmisintrod…  相似文献   

13.
本文叙述了对海南岛及其毗邻大陆边缘白垩纪到第四纪地层岩石进行古地磁研究的全部工作过程。通过分析岩石中剩余磁矢量的磁偏角及磁倾角的变化,提出海南岛白垩纪以来经历的构造演化模式如下:早期伴随顺时针旋转而向南迁移,后期伴随逆时针转动并向北运移。联系该地区及邻区的地质、地球物理资料,对海南岛上述的构造地体运动提出以下认识:北部湾内早期有一拉张作用,主要是该作用使湾内地壳显著伸长减薄,形成北部湾盆地。从而导致了海南岛的早期构造运动,而海南岛后期的构造运动则主要是受南海海底扩张的影响。海南地体运动规律的阐明对于了解北部湾油气盆地的形成演化有重要的理论和实际意义。  相似文献   

14.
Various applications relevant to the exciton dynamics,such as the organic solar cell,the large-area organic light-emitting diodes and the thermoelectricity,are operating under temperature gradient.The potential abnormal behavior of the exicton dynamics driven by the temperature difference may affect the efficiency and performance of the corresponding devices.In the above situations,the exciton dynamics under temperature difference is mixed with  相似文献   

15.
The elongation method,originally proposed by Imamura was further developed for many years in our group.As a method towards O(N)with high efficiency and high accuracy for any dimensional systems.This treatment designed for one-dimensional(ID)polymers is now available for three-dimensional(3D)systems,but geometry optimization is now possible only for 1D-systems.As an approach toward post-Hartree-Fock,it was also extended to  相似文献   

16.
17.
The explosive growth of the Internet and database applications has driven database to be more scalable and available, and able to support on-line scaling without interrupting service. To support more client's queries without downtime and degrading the response time, more nodes have to be scaled up while the database is running. This paper presents the overview of scalable and available database that satisfies the above characteristics. And we propose a novel on-line scaling method. Our method improves the existing on-line scaling method for fast response time and higher throughputs. Our proposed method reduces unnecessary network use, i.e. , we decrease the number of data copy by reusing the backup data. Also, our on-line scaling operation can be processed parallel by selecting adequate nodes as new node. Our performance study shows that our method results in significant reduction in data copy time.  相似文献   

18.
R-Tree is a good structure for spatial searching. But in this indexing structure,either the sequence of nodes in the same level or sequence of traveling these nodes when queries are made is random. Since the possibility that the object appears in different MBR which have the same parents node is different, if we make the subnode who has the most possibility be traveled first, the time cost will be decreased in most of the cases. In some case, the possibility of a point belong to a rectangle will shows direct proportion with the size of the rectangle. But this conclusion is based on an assumption that the objects are symmetrically distributing in the area and this assumption is not always coming into existence. Now we found a more direct parameter to scale the possibility and made a little change on the structure of R-tree, to increase the possibility of founding the satisfying answer in the front sub trees. We names this structure probability based arranged R-tree (PBAR-tree).  相似文献   

19.
The geographic information service is enabled by the advancements in general Web service technology and the focused efforts of the OGC in defining XML-based Web GIS service. Based on these models, this paper addresses the issue of services chaining,the process of combining or pipelining results from several interoperable GIS Web Services to create a customized solution. This paper presents a mediated chaining architecture in which a specific service takes responsibility for performing the process that describes a service chain. We designed the Spatial Information Process Language (SIPL) for dynamic modeling and describing the service chain, also a prototype of the Spatial Information Process Execution Engine (SIPEE) is implemented for executing processes written in SIPL. Discussion of measures to improve the functionality and performance of such system will be included.  相似文献   

20.
Advances in wireless technologies and positioning technologies and spread of wireless devices, an interest in LBS (Location Based Service) is arising. To provide location based service, tracking data should have been stored in moving object database management system (called MODBMS) with proper policies and managed efficiently. So the methods which acquire the location information at regular time intervals then, store and manage have been studied. In this paper, we suggest tracking data management techniques using topology that is corresponding to the moving path of moving object. In our techniques, we update the MODBMS when moving object arrived at a street intersection or a curved road which is represented as the node in topology and predict the location at past and future with attribute of topology and linear function. In this technique, location data that are corresponding to the node in topology are stored, thus reduce the number of update and amount of data. Also in case predicting the location,because topology are used as well as existing location information, accuracy for prediction is increased than applying linear function or spline function.  相似文献   

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