变质重结晶锆石微量元地球化学与U-Pb年代学:以辽宁红透山铜锌矿床赋矿片麻岩为例

利用CL和LA-ICP-MS技术,对红透山铜锌矿床赋矿黑云母斜长片麻岩中的锆石开展了内部结构特征分析、原位微量元素组成分析和锆石微区定年.CL图像特征显示锆石具有核幔边结构,分析认为核部为岩浆锆石,幔部为变质重结晶锆石;原位微量元素组成分析的结果显示核部和幔部锆石稀土元素组成存在异同点,相同之处表现在两者的稀土配分模式相似,表明微量元素组成方面变质重结晶锆石对岩浆锆石的继承性;差别之处体现在稀土总量和轻稀土上,幔部变质重结晶锆石的稀土总量和轻稀土量都明显低于核部岩浆锆石,显示变质重结晶过程中锆石中稀土元素的地球化学行为.在此基础之上,对锆石U-Pb年龄进行合理解释,认为核部岩浆锆石年龄2 552Ma代表研究区海底火山岩的喷发时限,变质重结晶锆石较小年龄2 520 Ma代表区域变质事件的时限.既而限定红透山铜锌矿的成矿时代在2 552 Ma,变质变形时代2 520 Ma.     

准苏吉花斑岩型钼铜矿床岩体特征及成矿机制研究

通过对辉钼矿的Re-Os及锆石U-Pb同位素年代学研究, 得到辉钼矿的Re-Os等时线年龄为297.2±4.3 Ma, 赋矿花岗斑岩的锆石U-Pb年龄为 301.1±4.0 Ma, 确定准苏吉花斑岩型钼铜(Mo-Cu)矿床的成岩成矿时代为晚石炭世至早二叠世。准苏吉花矿区不含矿花岗闪长岩的锆石U-Pb 年龄为301.2±2.2 Ma, 与花岗斑岩成岩时代一致。发育角闪石和黑云母的矿物学特征以及高Rb, Th和Ba, 低P和Ti的岩石地球化学特征表明, 花岗斑岩和花岗闪长岩同属于I型花岗岩。较低的Re含量、Mg#值、Nb/Ta值和Zr/Hf值以及低ISr值和正ε_Nd(t)值的全岩Sr-Nd同位素特征表明, 准苏吉花花岗岩的源区为新生下地壳的部分熔融, 岩浆演化过程中, 花岗斑岩和花岗闪长岩均经历较强烈的分离结晶作用, 有利于Mo进一步在残余熔体中富集。通过锆石的Ce⁴⁺/Ce³⁺值计算获得岩浆结晶分异时的氧逸度, 发现花岗斑岩岩浆的氧逸度相对较高(ΔFMQ平均值为+4.8), 花岗闪长岩岩浆氧逸度相对较低(ΔFMQ平均值为+2.2), 表明高氧逸度的岩浆更有利于Mo和Cu富集成矿。     

内蒙古大苏计斑岩型钼矿赋矿岩体的锆石U-Pb年龄与地球化学特征研究

为研究内蒙古大苏计斑岩型钼矿床赋矿岩体的形成年龄、地球化学特征及构造背景, 对3种岩体(石英斑岩、花岗斑岩和正长花岗岩)的样品进行锆石U-Pb定年和主量元素、微量元素分析。结果显示, 石英斑岩、正长花岗岩和花岗斑岩分别形成于231, 227和225 Ma, 为印支期产物。3种岩体属于高钾钙碱性−钾玄质系列, 为高分异的I型花岗岩。岩石组合特征与区域地质背景揭示, 大苏计地区在印支期处于伸展环境, 软流圈上涌导致不同深度的地壳发生部分熔融作用, 产生与大苏计斑岩型钼矿成矿相关的母岩浆。这些母岩浆向上运移过程中萃取前中生代形成的矿源层中的成矿元素, 并在结晶分异过程中不断地富集钼元素, 当岩浆挥发分达到过饱和时发生流体相与熔体相的分离, 钼进入流体相。岩浆热液沿裂隙充填, 在演化过程中发生沸腾作用, 导致大量钼和石英沉淀, 形成大苏计钼矿床。     

滇西新生代赋矿斑岩及花岗岩包体的锆石年代和稀土特征的地质意义

滇西地区沿金沙江—哀牢山断裂带广泛发育新生代富碱斑岩及相关多金属矿床.以六合正长斑岩中与暗色深源包体共存花岗岩包体和马厂箐赋矿斑状花岗岩为研究对象,开展岩相学和LA-ICP-MS锆石U-Pb年代学研究及锆石稀土元素分析.研究表明,六合花岗岩浆活动起始时间约为(42.8士1.6)Ma B.P.,包体结晶成岩时间与主岩(正长斑岩)年龄一致(38.63 Ma B.P.±0.52 MaB.P.);马厂箐含矿富碱岩浆起始活动时间约为(38.51士0.52)MaB.P.,结晶成岩时间为(35.80士0.20)Ma B.P..结合花岗岩包体的液态不混溶现象和锆石稀土元素特征分析,初步揭示研究区富碱岩浆起源、演化及成岩成矿作用过程为:来自交代富集地幔源区的硅不饱和富碱岩浆伴随互不混溶含矿地幔流体同步上升运移;该富碱岩浆以其底劈作用和地幔流体交代作用引发地壳深熔形成长英质岩浆.此后的2类岩浆过程分为2部分:一是富碱岩浆直接捕获少量长英质岩浆以不混溶方式继续同步运移至地壳结晶成岩,形成含花岗岩包体的硅不饱和富碱斑岩;二是富碱岩浆与长英质岩浆发生同化混染形成混合岩浆运移至地壳,其中所含不混溶含矿地幔流体伴随其结晶成岩进行自交代蚀变,形成硅过饱和的赋矿斑状花岗岩.     

黔西南贞丰水银洞基性岩锆石U-Pb测年及金矿成矿

基性岩与金矿成矿关系密切。而针对滇黔桂地区卡林型金矿成矿年龄一直缺乏年代学证据。测得黔西南贞丰水银洞基性岩锆石U-Pb年龄为218±3.2 Ma,与前人对水银洞卡林型金矿年龄的测定一致,说明该区金矿化与基性岩岩浆活动密切相关。该年龄对应印支晚期,并在此基础上提出一种印支期成矿的动力学模型:古特提斯洋封闭导致印支板块与扬子板块碰撞,强大的区域构造事件为矿化提供了动力,形成了贞丰地区218±3.2 Ma的基性岩。另外该地区可能存在一些埋藏的印支期花岗岩侵入体,这些入侵的岩体可作为热源,驱动主要为大气降水成因的流体浸出成矿元素,形成了贞丰水银洞地区卡林型金矿床。     

富钾碱性岩体形成演化对铜矿成矿制约--以马厂箐铜矿为例

马厂箐赋铜斑岩体主要由早期角闪正长岩及晚期花岗斑岩组成,早期角闪正长岩锆石U-Th-Pb年龄(35.6±0.3)Ma,晚期花岗斑岩锆石U-Th-Pb年龄(35.0±0.2)Ma,岩浆活动期限0.6Ma;早期角闪正长岩氧逸度低,锆石Ce4 /Ce3 平均102,晚期花岗斑岩氧逸度高,锆石Ce4 /Ce3 平均264.马厂箐赋铜斑岩体由早到晚氧化性增强表明和铜矿化有关氧化性岩浆不是直接来自强氧化性地幔源区,而是在形成上升过程中和顶部富水及斜长石氧化性盖层反应,形成富水氧化性岩浆.富水氧化性岩浆结晶分异出的富铜成矿流体有利于斑岩型铜矿床形成.     

西秦岭中生代花岗岩锆石U-Pb-Lu-Hf同位素特征及地质意义

对西秦岭地区中川岩体、柏家庄岩体和教场坝花岗岩体进行LA-ICP-MS锆石U-Pb同位素年代学分析, 获得其岩浆侵位年龄分别为220±1, 216±6和222±3 Ma, 表明3个岩体均形成于中?晚三叠世。样品的全岩地球化学分析结果表明, 3个岩体具有相似的稀土及微量元素特征, 均表现为显著亏损高场强元素Nb, Ti和P等, 具有明显的右倾式球粒陨石标准化稀土元素配分模式。锆石Lu-Hf同位素分析结果表明, 3个岩体锆石测年样品的ε_Hf(t)值介于?3.31~+1.68之间, 二阶段模式年龄介于1151~1456 Ma之间。岩石成因分析表明, 这些印支期花岗岩体的母岩浆主要来源于新元古代地壳物质的部分熔融。结合岩体形成时代、岩石成因和区域岩浆作用, 认为这些岩体形成于南秦岭与华南板块沿勉略缝合带相碰撞的造山动力学背景, 可能与华南板块的俯冲板片断离有关。     

伊春花岗质片麻岩锆石 U-Pb 年代学特征

通过1∶5万朱拉比拉河等图幅区域地质调查工作,在伊春地区发现了新元古代花岗质片麻岩。应用锆石 U-Pb 测龄方法对花岗质片麻岩进行了年代学研究,23个点的206 Pb／238 U表面谐和年龄均在850 Ma 左右,加权平均为850．2±2．1 Ma。该年龄代表花岗质片麻岩体的侵位时间为新元古代;而较新的499 Ma 年龄可能是后期构造事件改造的新生锆石,反映后期构造热事件的年龄;1518 Ma 的年龄应是本次岩浆作用过程中捕获的早期锆石的年龄,该锆石年龄可能代表本区花岗岩的继承性锆石年龄。伊春花岗质片麻岩所在的地区存在前寒武纪的古老微陆块。     

长乐-诏安断裂带形成时代的锆石U-Pb年代学约束及其地质意义

为厘定长乐-诏安断裂带的形成时代及活动峰期,运用激光剥蚀电感耦合等离子体质谱(LA-ICP-MS)锆石U-Pb测年法对平潭辉绿岩墙、二长花岗岩围岩及南日岛动力变质花岗闪长岩开展了测年工作,结果表明带内大规模花岗质岩石的形成与大型走滑活动是同期的,辉绿岩墙结晶年龄代表断裂带走滑剪切形成深切地壳张性破裂时间,辉绿岩中捕获的继承岩浆锆石年龄较老,最新结晶锆石年龄为131 Ma,围岩的锆石年龄加权平均值为(133. 4±0. 8) Ma,动力变质花岗岩锆石的年龄加权平均值为(130. 3±1. 0) Ma。首次发现的假玄武玻璃是对早白垩世断裂带强烈活动形成的古地震事件的记录,该带的基底可能为华夏古陆的一部分,其初始形成时代主要为侏罗纪-早白垩纪。     

吉林省石头口门地区早二叠世砂岩碎屑锆石U-Pb年龄及其地质意义

通过对吉林省石头口门地区早二叠世砂岩进行野外地质考察、薄片镜下观察和碎屑锆石U-Pb年代学研究,探讨其形成时代、物源及构造环境。长石岩屑杂砂岩的碎屑颗粒具有分选和磨圆度差以及成分复杂的特征,表明为近源快速堆积的产物。获得114颗碎屑锆石U-Pb年龄介于480～276 Ma,可划分出晚石炭世—早二叠世(322～276 Ma)和早石炭世(349～323 Ma) 2个主要年龄组,另有4个早古生代和中泥盆世年龄。通过区域岩浆事件对比,推测石头口门地区早二叠世砂岩的物源主要来自华北板块北缘晚石炭世—早二叠世活动陆缘型岩浆岩,少量来自研究区附近的早石炭世岩浆岩、早古生代岩浆弧、晚志留世—中泥盆世弧-陆碰撞岩浆岩以及华北板块前寒武纪变质基底。综合碎屑锆石年龄频谱、沉积以及构造背景资料分析,认为石头口门早二叠世砂岩应是活动大陆边缘环境下海底扇沉积序列的组成部分,并在古亚洲洋闭合过程中作为基质与一系列成分、规模和时代复杂的构造岩块或岩片共同构成了蛇绿混杂岩。     

Geochronolosic constraints on masmatic intrusions and mineralization of the Zhunuo porphyry copper deposit in Gansdese, Tibet

In situ zircon U-Pb ages for the recently discovered Zhunuo porphyry copper deposit in the western part of the Gangdese metallogenic belt in Tibet were determined by sensitive high-resolution ion microprobe （SHRIMP）. The ages can be divided into two separate groups, reflecting more than four major tectono-magmatic events in the area. The 62.5±2.5 Ma age of inherited zircons may be related to the volcanic eruption of the Linzizong Group formed shortly after the India-Asia continental collision. The 50.1±3.6 Ma age most likely corresponds to the time of underplating of mantle-derived mafic magma in Gangdese. The 15.6±0.6 Ma age obtained from magmatic zircons is interpreted as the age of crystallization of the Zhunuo ore-forming porphyry. Finally, a molybdenite Re-Os isochron age of 13.72±0.62 Ma is consistent with another zircon U-Pb age of 13.3±0.2 Ma, representing the time of copper mineralization. These ages, in combination with available literature data, indicate that magmatic crystallization and copper mineralization in the Gangdese metallogenic belt became gradually younger westward, and further suggest that the Zhunuo porphyry copper deposit was formed in the same tectonic stage as other porphyry copper deposits in the eastern and central Gangdese belt. This conclusion provides critical information for future exploration of porphyry copper deposits in western Gangdese.     

Zircon SHRIMP dating of sodium alkaline rocks from Maomaogou area of Huili County in Panxi, SW China and its geological implications

Alkalinerocksareoftenassociatedwithextensionaltectonicsandregardedasthecharacteristicproductsoc-curringincontinentalmarginsorriftzones[1].Theywereusuallygeneratedindeep-large-faultzoneandcloselyconnectedwithbasic/ultrabasicrocksinspace.Therefore,alkalinerocksareofsignificanceintectonicpetrology.Atthebeginningofthe1980s,geologicalandgeophysicalstudieswereperformedinPanzhihua-Xichangpaleo-riftzone(Panxiriftzone).However,thesestudiesonlyin-volvedgeologyandpetrochemistryoftheMaomaogouringalkalic…     

西藏洞中拉铅锌矿床石英斑岩锆石U-Pb年代学研究

探讨西藏洞中拉铅锌矿区的石英斑岩岩体归属.通过详细的地质填图,并采用LAICPMS锆石U-Pb法年龄测定技术,对石英斑岩进行年代学研究.通过石英斑岩样品中单颗粒锆石22个样品点的分析,得到其206 Pb/238U的加权平均年龄为126.9±1.1 Ma,MSWD=0.96.这一结果否认了这套岩石单元属于始新世林子宗群帕...     

滇西小龙潭矿区始新世岩浆岩的成因及其地质意义

云南省宾川县小龙潭矿区是一个大型斑岩型铜多金属矿床,铜矿体主要产于斑岩体及其外围接触带,矿化与斑岩体密切相关。对矿区主要侵入岩开展全岩地球化学、锆石LA-ICPMS U-Pb年代学和Hf同位素研究,获得含矿二长斑岩的~(206)Pb/~(238)U加权平均年龄为(35.98±0.16)Ma,属于始新世岩浆活动的产物。斑岩体SiO_2质量分数变化较大(64.81%~69.6%),高钾(4.36%~10.95%)和碱(Na_2O+K_2O8%),A/CNK为0.99~1.36,属高钾的碱性—过碱性、准铝质—过铝质斑岩;富集大离子亲石元素(K、Rb、Ba、Sr等)、亏损高场强元素(Ta、Nb、P、Ti等),富集轻稀土元素、亏损重稀土元素;虽被划入富碱侵入岩及A型花岗岩,但具C型埃达克岩地球化学特征。斑岩体锆石ε_(Hf)(t)值为-26.93~1.66,地壳模式年龄为1 009~4141 Ma,显示斑岩体来源于下地壳物质的部分熔融,并有幔源物质的加入。结合区域演化特征,认为小龙潭斑岩体形成于造山期后的拉张环境,陆陆碰撞挤压后应力松弛,岩浆沿断裂及次级断裂上侵,进而形成铜多金属矿床。     

Porphyry Cu-Mo deposits in the eastern Xing’an-Mongolian Orogenic Belt: Mineralization ages and their geodynamic implications

The eastern Xing’an-Mongolian (Xing-Meng) Orogenic Belt (XMOB) is one of the important areas of porphyry copper (Cu)-molybdenum (Mo) deposits in China. However, studies on the exact ages of mineralization and their geodynamic significance are very limited. In this study, granodioritic rocks from the Duobaoshan Cu deposit and Daheishan Mo deposit were selected to make zircon SHRIMP U-Pb analyses in order to constrain their mineralization ages. Geochronological data indicate that two episodes of mineralization took place in the Duobaoshan Cu deposits. The granodiorite related to the Duobaoshan porphyry Cu deposit was formed in the Early Paleozoic with zircon U-Pb age of 485±8 Ma, whereas the granodiorites related to the Sankuanggou skarn-type Cu deposit were emplaced in the Jurassic with zircon U-Pb ages of 176±3 and 177±3 Ma. In the Daheishan area of Jilin Province, the emplacement age of the granodiorite porphyry related to the porphyry Mo deposit was dated at 170±3 Ma, and the unmineralized monzogranite at 178±3 Ma. Therefore, two episodes of Cu-Mo mineralization were developed in the eastern XMOB, at ~485 Ma and ~175 Ma, respectively. Based on the geological history and spatial-temporal distribution of the granitoids in northeastern (NE) China, it is proposed that the Duobaoshan Cu deposit was related to the collision of the Xing’an and Erguna blocks in the Early Paleozoic, and the Sankuanggou Cu and Daheishan Mo deposits were related to subduction of the Paleo-Pacific plate during the Jurassic.     

Chronological record of the Early Mesozoic underplating in the northern margin of North China─U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Formation in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma, which is consistent with the age of the Early Mesozoic underplating granulites, and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma, which is highly consistent with the Ar-Ar dating of the host volcanic rocks. Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites, indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.     

Chronological record of the Early Mesozoic underplating in the northern margin of North China─U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Formation in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma, which is consistent with the age of the Early Mesozoic underplating granulites, and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma, which is highly consistent with the Ar-Ar dating of the host volcanic rocks. Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites, indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.     

Chronological record of the Early Mesozoic underplating in the northern margin of North China—U-Pb chronometry of zircons in the Late Mesozoic andesite from Western Liaoning

Cathodoluminescence spectroscopic analysis of zircons in the uppermost sanukites of the early Cretaceous Yixian Forma- tion in Western Liaoning reveals zoning structures of the zircons in the volcanic rocks. LA-ICP-MS chronometry shows that the central part of the zircons is remnant zircon with a U-Pb dating of 254 Ma,which is consistent with the age of the Early Mesozoic underplating granulites,and that the periphery is zircon crystallizing out of the host magma with a U-Pb dating of 116 Ma,which is highly consistent with the Ar-Ar dating of the host volcanic rocks.Compositions of the clinopyroxenes xenocrystals in the sanukites are similar to those of the clinopyroxenes in the underplating granulites,indicating that the granulites accreted to the lower crust in the Early Mesozoic have been reformed and disrupted by the upwelling diapers of the asthenosphere and taken part in formation of the sanukites in the Late Mesozoic.     

江西乐平塔前钼(钨)矿床成岩成矿时代及意义

探讨江西省乐平市塔前钼(钨)矿床成矿岩体的形成时代。通过对塔前钼(钨)矿床进行野外地质调查和SIMS锆石U-Pb测龄,结果表明其成矿母岩为花岗闪长斑岩,其加权平均年龄为160.9±2.5 Ma(MSWD=0.69),代表矿区花岗闪长斑岩的结晶时间。这与矿区矽卡岩矿石中辉钼矿Re-Os同位素年龄(162±2 Ma)在误差范围内一致,说明此矿床形成于中侏罗世晚期。将其与钦杭成矿带东段塔前-赋春成矿带与乐华—德兴成矿带中同类矿床进行对比发现,前者成矿年龄集中于161 Ma±,控岩控矿构造皆以北东向为主;而后者成矿年龄集中于170 Ma±,控岩控矿构造以北西向为主,预示钦杭成矿带东段2个成矿阶段(170~161 Ma B.P.)区域构造应力方向可能发生了重大转变。